Petrology of Al- and Cr-rich ophiolitic chromitites from the Muğla,SW Turkey: implications from composition of chromite,solid inclusions of platinum-group mineral,silicate, and base-metal mineral,and Os-isotope geochemistry

Ultramafic rocks around the city of Muğla in SW Turkey are represented by mantle peridotites depleted to various degrees, ranging from cpx-rich harzburgites to depleted harzburgite and dunite. Cpx-rich harzburgites are thought to be the residua left after extraction of MORB-type basalt, from which high-Al chromitite [49.2 < Cr# = 100 × Cr/(Cr + Al) < 53.5] crystallised with a higher proportion of ¹⁸⁷Os/¹⁸⁸Os (average of 0.1361). However, depleted harzburgites are assumed to be the residua left after extraction of hydrous boninitic melt produced by second stage partial melting of already depleted mantle due to a subducting slab, from which high-Cr chromitites (64.2 < Cr# < 85.9) with lower and heterogeneous ¹⁸⁷Os/¹⁸⁸Os ratio (average of 0.1324) were crystallised as a result of melt–rock interaction in a supra-subduction environment. Dunites around the chromite deposits are considered to be the product of melt–peridotite interaction. Most of the chromitites contain high-Cr chromite and display enrichment in IPGE (Os, Ir, Ru) over PPGE (Rh, Pt, Pd), with PGE concentrations between 61 and 1,305 ppb. Consistently, laurite-erlichmanite series minerals with various Os concentrations are found to be the most abundant PGM inclusions in chromite. Os–Ir–Ru alloy, irarsite, and kashinite, as well as Pt–Fe alloy and Pt-oxide, which are not common in ophiolitic chromitites, were also detected as magmatic PGM inclusions. Pentlandite, millerite, and, rarely heazlewoodite form the magmatic inclusions of base-metal sulphide. The presence of olivine and clinopyroxene, as well as hydrous silicate inclusions such as amphibole and phlogopite, in high-Cr chromitite supports the idea that high-Cr chromitites were formed in a supra-subduction environment.     

Heavy minerals of the Barakar Formation,Talchir Gondwana Basin,Orissa

Heavy mineral analysis has been carried out in the Barakar Formation of the Talchir Gondwana Bbasin, Orissa. The characteristic heavy minerals are garnet, zircon, tourmaline, rutile, biotite, chlorite, pyroxenes, hornblende, staurolite, sillimanite, apatite, epidote, sphene, spinel and siderite including opaques and leucoxene. These heavy minerals are divisible into four groups on the basis of principal component analysis and suggest derivation of Barakar sediments from pegmatite, acid and basic igneous as well as low- and high-rank metamorphic rocks lying to the south of the Talchir Gondwana Basin. Though the heavy mineral suites of all the sandstone samples are by and large similar, differences have been noticed in the frequencies of many heavy minerals in vertical succession. Cyclic nature and vertical fluctuation of heavy mineral frequencies can be ascribed to variation of the relief of the source area, sudden release of some of the minerals in the source region and/or existence of favourable geochemical condition to escape partial dissolution.     

Stable Isotopes Reveal Complex Changes in Trophic Relationships Following Nutrient Addition in a Coastal Marine Ecosystem

Complex links between the top-down and bottom-up forces that structure communities can be disrupted by anthropogenic alterations of natural habitats. We used relative abundance and stable isotopes to examine changes in epifaunal food webs in seagrass (Thalassia testudinum) beds following 6 months of experimental nutrient addition at two sites in Florida Bay (USA) with different ambient fertility. At a eutrophic site, nutrient addition did not strongly affect food web structure, but at a nutrient-poor site, enrichment increased the abundances of crustacean epiphyte grazers, and the diets of these grazers became more varied. Benthic grazers did not change in abundance but shifted their diet away from green macroalgae + associated epiphytes and towards an opportunistic seagrass (Halodule wrightii) that occurred only in nutrient addition treatments. Benthic predators did not change in abundance, but their diets were more varied in enriched plots. Food chain length was short and unaffected by site or nutrient treatment, but increased food web complexity in enriched plots was suggested by increasingly mixed diets. Strong bottom-up modifications of food web structure in the nutrient-limited site and the limited top-down influences of grazers on seagrass epiphyte biomass suggest that, in this system, the bottom-up role of nutrient enrichment can have substantial impacts on community structure, trophic relationships, and, ultimately, the productivity values of the ecosystem.     

Risk assessment of land subsidence at Tianjin coastal area in China

Risk assessment and zoning are very important to risk management. In this study, a land subsidence risk assessment index was proposed based on the Disaster Risk Index. The cumulative subsidence volume, the land subsidence velocity, and the groundwater exploitation intensity were collected, analyzed, and put together to create a land subsidence hazard evaluation map in Tianjin coastal area. The population density, Gross Domestic Product per square kilometer, and construction land proportion were adopted as indexes to create the vulnerability map. In addition, the capability of land subsidence prevention and reduction was also assessed. Finally, the land subsidence risk map was created by combing the hazard, vulnerability, and the capability of land subsidence prevention and reduction map. Specifically, the land subsidence risk was classified into five levels, i.e., very high, high, medium, low, and very low. The result of this research could provide a solid basis for the sustainable development as well as disaster prevention policy-making of Tianjin city.     

Soil erosion prediction using the Revised Universal Soil Loss Equation (RUSLE) in a GIS framework,Chania, Northwestern Crete,Greece

Soil erosion is a growing problem in southern Greece and particularly in the island of Crete, the biggest Greek island with great agricultural activity. Soil erosion not only decreases agricultural productivity, but also reduces the water availability. In the current study, an effort to predict potential annual soil loss has been conducted. For the prediction, the Revised Universal Soil Loss Equation (RUSLE) has been adopted in a Geographical Information System framework. The RUSLE factors were calculated (in the form of raster layers) for the nine major watersheds which cover the northern part of the Chania Prefecture. The R-factor was calculated from monthly and annual precipitation data. The K-factor was estimated using soil maps available from the Soil Geographical Data Base of Europe at a scale of 1:1,000,000. The LS-factor was calculated from a 30-m digital elevation model. The C-factor was calculated using Remote Sensing techniques. The P-factor in absence of data was set to 1. The results show that an extended part of the area is undergoing severe erosion. The mean annual soil loss is predicted up to ∼200 (t/ha year⁻¹) for some watersheds showing extended erosion and demanding the attention of local administrators.     

Dissolution,transport, and fate of lead on a shooting range in the Jefferson National Forest near Blacksburg,VA, USA

Samples taken from a shooting range near Blacksburg, VA, USA provide information about the reservoirs and pathways of lead at shooting ranges in an upland setting and humid environment. The metallic lead shot corrodes rapidly and develops a coating of hydrocerussite (Pb₃(CO₃)₂(OH)₂). Hydrocerussite dissolution releases soluble lead at concentrations ranging from 2 ppb to 2 ppm depending the soil pH values at this site. This soluble lead is captured by the Fe and Mn oxides and carbonates soil fractions. The highest concentration of extractable lead contained in the soil was directly correlated with the highest concentration of lead shot and bullets measured on the shotgun range surface. Eh-pH and hydrolysis diagrams provide a useful geochemical framework for understanding the corrosion process, recognizing the corrosion product(s), understanding their solubility, and identifying the geochemical barriers to lead migration that provides a basis for selecting best management practices for this and other shooting range.     

Study of subsurface geology in locating arsenic-free groundwater in Bengal delta,West Bengal,India

Over a large area of the Bengal delta in West Bengal, India, arsenic distribution patterns in groundwater were studied. One hundred and ten boreholes at different target locations were made, subsurface sediments were logged and analysed, and arsenic values in sediments vis-à-vis groundwater were compared. The study elucidates the subsurface geology of the western part of Bengal delta and characterises the sediments that were intersected in different boreholes with contrasting values of arsenic in groundwater. It reveals an existence of multiple aquifers stacked over each other. Depending on the color and nature of aquifer-sands and their overlying clay beds six aquifer types (Type-1 to Type-6) are classified and described. Sediment-arsenic for all the varieties of aquifer sands are near similar but the groundwater-arsenic of these six aquifers varies widely. Type-2 and Type-5 aquifers host arsenic-contaminated groundwater whereas the other four aquifers are arsenic-free. Type-2 and Type-5 aquifers are capped by a grey to dark grey soft organic matter-rich clay unit which makes these aquifers semi-confined to leaky-confined. These contribute in releasing arsenic from the sediments. The results of this study are employed in a proposed georemedial measure against this hazardous toxic element.     

Nutrient chemistry and salinity mapping of the Delhi aquifer,India: source identification perspective

Present study is an effort to distinguish between the contributions of natural weathering and anthropogenic inputs towards high salinity and nutrient concentrations in the groundwater of National Capital Territory (NCT) Delhi, India. Apart from the source identification, the aquifer of entire territory has been characterized and mapped on the basis of salinity in space and water suitability with its depth. Major element chemistry, conventional graphical plots and specific ionic ratio of Na⁺/Cl⁻, SO₄ ²⁻/Cl⁻, Mg²⁺/Ca²⁺ and Ca²⁺/(HCO₃ ⁻ + SO₄ ²⁻) are conjointly used to distinguish different salinization sources. Results suggest that leaching from the various unlined landfill sites and drains is the prime cause of NO₃ ⁻ contamination while study area is highly affected with inland salinity which is geogenic in origin. The seasonal water level fluctuation and rising water level increases nutrients concentration in groundwater. Mixing with old saline sub-surface groundwater and dissolution of surface salts in the salt affected soil areas were identified as the principle processes controlling groundwater salinity through comparison of ionic ratio. Only minor increase of salinity is the result of evaporation effect and pollution inflows. The entire territory has characterized into four groups as fresh, freshening, near freshening and saline with respect to salinity in groundwater. The salinity mapping suggests that in general, for drinking needs, groundwater in the fresh, freshening and near freshening zone is suitable up to a depth of 45, 20 and 12 m, respectively, while the saline zones are unsuitable for any domestic use. In the consideration of increasing demand of drinking water in the area; present study is vital and recommends further isotopic investigations and highlights the need of immediate management action for landfill sites and unlined drains.     

Hydrochemical variation in the springs water between Jerusalem–Ramallah Mountains and Jericho Fault,Palestine

The spatial and temporal changes of the composition of the groundwater from the springs along the Wadi Qilt stream running from the Jerusalem–Ramallah Mountains towards the Jericho Plain is studied during the hydrological year 2006/2007. The residence time and the intensity of recharge play an important role in controlling the chemical composition of spring water which mainly depends on distance from the main recharge area. A very important factor is the oxidation of organics derived from sewage and garbage resulting in variable dissolved CO₂ and associated HCO₃ ⁻ concentration. High CO₂ yields lower pH values and thus under-saturation with respect to calcite and dolomite. Low CO₂ concentrations result in over-saturation. Only at the beginning and at the end of the rainy season calcite saturation is achieved. The degradation of dissolved organic matter is a major source for increasing water hardness. Besides dissolution of carbonates dissolved species such as nitrate, chloride, and sulfate are leached from soil and aquifer rocks together with only small amounts of Mg. Mg not only originates from carbonates but also from Mg–Cl waters are leached from aquifer rocks. Leaching of Mg–Cl brines is particularly high at the beginning of the winter season and lowest at its end. Two zones of recharge are distinguishable. Zone 1 represented by Ein Fara and Ein Qilt is fed directly through the infiltration of meteoric water and surface runoff from the mountains along the eastern mountain slopes with little groundwater residence time and high flow rate. The second zone is near the western border of Jericho at the foothills, which is mainly fed by the under-groundwater flow from the eastern slopes with low surface infiltration rate. This zone shows higher groundwater residence time and slower flow rate than zone 1. Groundwater residence time and the flow rate within the aquifer systems are controlled by the geological structure of the aquifer, the amount of active recharge to the aquifer, and the recharge mechanism. The results of this study may be useful in increasing the efficiency of freshwater exploitation in the region. Some precautions, however, should be taken in future plans of artificial recharge of the aquifers or surface-water harvesting in the Wadi. Because of evaporation and associated groundwater deterioration, the runoff water should be artificially infiltrated in zones of Wadis with high storage capacity of aquifers. Natural infiltration along the Wadis lead to evaporation losses and less quality of groundwater.     

Scale of pluton/wall rock interaction near May Lake,Yosemite National Park,CA, USA

Interaction of magma with wall rock is an important process in igneous petrology, but the mechanisms by which interactions occur are poorly known. The western outer granodiorite of the Cretaceous Tuolumne Intrusive Suite of Yosemite National Park, California, intruded a variety of metasedimentary and igneous wall rocks at 93.1 Ma. The May Lake metamorphic screen is a metasedimentary remnant whose contact zone exhibits a variety of interaction phenomena including xenolith incorporation, disaggregation, and partial melting. The chemical contrast of these metasedimentary rocks with the invading pluton provides an excellent measure of pluton/wall rock interactions. Wall rock xenoliths (mostly pelitic quartzite) are predominantly located in an elongate horizon surrounded by a hybridized fine-grained granodiorite. Initial Sr and Nd isotopic ratios of the hybridized granodiorite indicate significant local incorporation of crustal material. Major- and trace-element geochemical data indicate that contamination of the granodiorite occurred via selective assimilation of both high-K and low-K, high-silica partial melts derived from pelitic quartzite. Although the hybridized granodiorite shows significant amounts of contamination, adjacent to xenoliths the proportion of contamination is undetectable more than a meter away. These results indicate that the chemical and isotopic variability of the Tuolumne Intrusive Suite is not caused by magma contamination via in situ wall rock assimilation.