Event monitoring of herbicides with naked and membrane-covered Empore disk integrative passive sampling devices

Subsequent to an initial wet season flood event in the Brisbane River, Australia, both fast (naked disk) and slow (membrane-covered) variants of SDB-RPS Empore disk passive sampling devices were deployed with an automated grab sampling program. A trend increase in the aquatic dissolved concentrations of diuron and simazine was observed over a 10-day period. Kinetic and equilibrium parameters for each sampler were calculated based on the dynamic concentration. Absolute percent difference for duplicate passive samples was <10% in the fast and <25% in the slow samplers. For kinetic sampling, significantly shortened integrative periods are available with the fast compared with the slow variant, with higher sampling rates offering improved detection limits. The study demonstrates a method for determining kinetic parameters of passive samplers in a variable concentration field deployment, and illustrates the differences in quality between active and passive data, in terms of capturing changes in concentration associated with rainfall events.     

A retrospective analysis of contamination and periphyton PICT patterns for the antifoulant irgarol 1051, around a small marina on the Swedish west coast

Irgarol is a triazine photosystem II (PSII) inhibitor that has been used in Sweden as an antifouling ingredient since the 1990s. Early microcosm studies indicated that periphyton was sensitive to irgarol at concentrations regularly found in harbours and marinas. However, field studies of irgarol effects on the Swedish west coast in 1994, using the pollution-induced community tolerance (PICT) approach, failed to detect any effects of the toxicant in the field. A PICT study involves sampling of replicate communities in a gradient of contamination, and a comparison of their community tolerance levels, with an increase being an indication that sensitive species have been eliminated and replaced by more tolerant ones. Typically, short-term assays are used to quantify the community tolerance levels. Later PICT studies in the same area over a 10 year period demonstrate that irgarol tolerance levels have increased, although the contamination pattern has been stable. Our results support the hypothesis that that the PICT potential was low initially, due to a small differential sensitivity between the community members, and that a persistent selection pressure was required to favour and enrich irgarol-tolerant species or genotypes.     

Analysis of Signals from an Unique Ground-Truth Infrasound Source Observed at IMS Station IS26 in Southern Germany

Quantitative modeling of infrasound signals and development and verification of the corresponding atmospheric propagation models requires the use of well-calibrated sources. Numerous sources have been detected by the currently installed network of about 40 of the final 60 IMS infrasound stations. Besides non-nuclear explosions such as mining and quarry blasts and atmospheric phenomena like auroras, these sources include meteorites, volcanic eruptions and supersonic aircraft including re-entering spacecraft and rocket launches. All these sources of infrasound have one feature in common, in that their source parameters are not precisely known and the quantitative interpretation of the corresponding signals is therefore somewhat ambiguous. A source considered well-calibrated has been identified producing repeated infrasound signals at the IMS infrasound station IS26 in the Bavarian forest. The source results from propulsion tests of the ARIANE-5 rocket’s main engine at a testing facility near Heilbronn, southern Germany. The test facility is at a range of 320 km and a backazimuth of ~280° from IS26. Ground-truth information was obtained for nearly 100 tests conducted in a 5-year period. Review of the available data for IS26 revealed that at least 28 of these tests show signals above the background noise level. These signals are verified based on the consistency of various signal parameters, e.g., arrival times, durations, and estimates of propagation characteristics (backazimuth, apparent velocity). Signal levels observed are a factor of 2–8 above the noise and reach values of up to 250 mPa for peak amplitudes, and a factor of 2–3 less for RMS measurements. Furthermore, only tests conducted during the months from October to April produce observable signals, indicating a significant change in infrasound propagation conditions between summer and winter months.     

Low‐frequency passive seismic experiments in Abu Dhabi,United Arab Emirates: implications for hydrocarbon detection

Low‐frequency passive seismic experiments utilizing arrays of 3‐component broadband seismometers were conducted over two sites in the emirate of Abu Dhabi in the United Arab Emirates. The experiments were conducted in the vicinity of a producing oilfield and around a dry exploration well to better understand the characteristics and origins of microtremor signals (1–6 Hz), which had been reported as occurring exclusively above several hydrocarbon reservoirs in the region. The results of the experiments revealed that a strong correlation exists between the recorded ambient noise and observed meteorological and anthropogenic noises. In the frequency range of 0.15–0.4 Hz, the dominant feature is a double‐frequency microseism peak generated by the non‐linear interactions of storm induced surface waves in the Arabian Sea. We observed that the double‐frequency microseism displays a high variability in spectral amplitude, with the strongest amplitude occurring when Cyclone Gonu was battering the eastern coast of Oman; this noise was present at both sites and so is not a hydrocarbon indicator. Moreover, this study found that very strong microtremor signals in the frequency range of 2–3 Hz were present in all of the locations surveyed, both within and outside of the reservoir boundary and surrounding the dry exploration well. This microtremor signal has no clear correlation with the microseism signals but significant variations in the characteristics of the signals were observed between daytime and nighttime recording periods that clearly correlate with human activity. High‐resolution frequency‐wavenumber (f‐k) spectral analyses were performed on the recorded data to determine apparent velocities and azimuths of the wavefronts for the microseism and microtremor events. The f‐k analyses confirmed that the double‐frequency microseism originates from wave activity in the Arabian Sea, while the microtremor events have an azimuth pointing towards the nearest motorways, indicating that they are probably being excited by traffic noise. Results drawn from particle motion studies confirm these observations. The vertical‐to‐horizontal spectral ratios of the data acquired in both experiments show peaks around 2.5–3 Hz with no dependence on the presence or absence of subsurface hydrocarbons. Therefore, this method should not be used as a direct hydrocarbon indicator in these environments. Furthermore, the analyses provide no direct evidence to indicate that earthquakes are capable of stimulating the hydrocarbon reservoir in a way that could modify the spectral amplitude of the microtremor signal.     

Morphometric comparisons between automated and manual karst depression inventories in Apalachicola National Forest,Florida, and Mammoth Cave National Park,Kentucky, USA

Karst depression catalogs are critical to assessing the hydrology and geohazards of an area; yet, the delineation of these features within a landscape can be a difficult, time-consuming and subjective task. This study evaluates the efficacy of karst depression inventorying using an automated fill-difference method operating on high-resolution lidar-derived digital elevation models (DEMs). The resulting catalog is compared with existing karst depression inventories for two low-development areas of the USA, Mammoth Cave National Park (MACA) and Apalachicola National Forest (ANF), where karst depressions have been mapped previously using a manual closed-contour approach. The automated fill method captures 93 and 85 % of these previously mapped karst depressions at MACA and ANF, respectively. Field observations and topographic analysis suggest that the omitted features were likely misclassified within the existing catalogs. The automated routine returns 797 and 3377 additional topographic depressions, at MACA and ANF, respectively, which are not included in the existing catalogs. While the geology of ANF is mostly homogenous Quaternary deposits, the newly identified, typically smaller-scale depressions found within MACA tend to be disproportionally located in non-carbonate-dominated formations, where the development of karst may be restricted by geologic heterogeneity. Within both areas, the size distributions of the two inventories are statistically identical for features larger than ~10³ m² in area or ~3 m in depth. For individual depressions captured by both methods at MACA, the automated fill-difference routine tends to return a slightly larger estimate of depression size and aggregate small depressions into larger ones. Conversely, at ANF, some low-relief depressions may be disaggregated by the fill-difference technique, with a trend toward smaller estimated depression areas when the automated method is employed. The automated fill-difference method, operating on high-resolution lidar-derived DEMs, can reproduce and expand the existing inventories of karst depressions, while minimizing false detections that may be inherent within pre-existing catalogs.     

THE MARBLE BEACHES OF TUSCANY*

ABSTRACT. Beach‐nourishment operations designed to replace sediment lost through erosion change the identity and meaning of coastal landscapes. Seven beaches in Tuscany, nourished with marble‐quarry waste, reveal how an industrial byproduct is naturalized by particle rounding and sorting and can become a positive symbol of human‐altered nature. The marble was placed on formerly sandy beaches, resulting in different grain size and color of sediments, beach morphology, and value for human use. The abrasion rate of marble makes the nourished beaches unsatisfactory when viewed solely as protection structures, but the rapid particle rounding and aesthetic appeal of marble increase the acceptability of the beaches for recreation.     

Ein Vergleich der Ergebnisse von A. Bianchi und F. Karl über die granitischen Gesteine des Zillertales und des Großvenedigers (Hohe Tauern)

Zusammenfassung Es wurde in einem Vergleichsreferat zwischen den Untersuchungsergebnissen vonA. Bianchi (1934) undF. Karl (1959) an den granitischen Gesteinen des Zillertal- und Großvenedigerbereiches (Hohe Tauern) und dem Tonalitmassiv des Rieserferner gezeigt, daß sich die Beobachtungen und Teilergebnisse vonBianchi trotz unterschiedlicher genetischer Auswertung gut in das Gesamtbild vonKarl einordnen lassen. Wichtig ist dafür, daß die Mehraktigkeit der alpidischen Orogenese für die Beurteilung des Verhältnisses zwischen Kristallisation und Deformation berücksichtigt wird und daß aus der zusammengefaßten Gesteinsgruppe der granodioritischen, schichtigen oder massigen Orthogneise mit normaler Biotit-reicher Facies tonalitisierte Paragneise (nachKarl Tonalitische Gneise) abgetrennt werden. Für die petrochemischen Vergleiche wurden alle interessierenden AnalysenBianchis auf Kationoxydprozente (Eskola) verrechnet und in vergleichbaren Verhältniszahlen gegenübergestellt.Mit 4 Textabbildungen