Environmental Monitoring and Peat Assessment Using Multivariate Analysis of Regional-Scale Geochemical Data

A compositional multivariate approach was used to analyse regional-scale soil geochemical data obtained as part of the Tellus Project generated by the Geological Survey of Northern Ireland. The multi-element total concentration data presented comprise X-ray fluorescence (XRF) analyses of 6862 rural soil samples collected at 20-cm depth on a non-aligned grid at one site per \(2\,\hbox {km}^{2}\). Censored data were imputed using published detection limits. Each soil sample site was assigned to the regional geology map, resulting in spatial data for one categorical variable and 35 continuous variables comprised of individual and amalgamated elements. This paper examines the extent to which soil geochemistry reflects the underlying geology or superficial deposits. Since the soil geochemistry is compositional, log-ratios were computed to adequately evaluate the data using multivariate statistical methods. Principal component analysis (PCA) and minimum/maximum autocorrelation factors (MAF) were used to carry out linear discriminant analysis (LDA) as a means to discover and validate processes related to the geologic assemblages coded as age bracket. Peat cover was introduced as an additional category to measure the ability to predict and monitor fragile ecosystems. Overall prediction accuracies for the age bracket categories were 68.4 % using PCA and 74.7 % using MAF. With inclusion of peat, the accuracy for LDA classification decreased to 65.0 and 69.9 %, respectively. The increase in misclassification due to the presence of peat may reflect degradation of peat-covered areas since the creation of superficial deposit classification.     

Modeling and Fitting of Three-Dimensional Mineral Microstructures by Multinary Random Fields

Mathematical Geosciences - Modeling a mineral microstructure accurately in three dimensions can render realistic mineralogical patterns which can be used for three-dimensional processing...     

Sea level induced variations in clay mineral composition in the southwestern South China Sea over the past 17,000 yr

Variations in clay mineral composition of sediment cores from the margin and continental slope of the Sunda Shelf (southern South China Sea, SE Asia) covering the past 17,000 yr reflect changing influences of sediment sources together with clay mineral partitioning processes in shallow waters. We identify the deglacial sea level rise as the principal factor driving these changes. During the late glacial, high values of kaolinite are interpreted to reflect a higher contribution of clays from soils that have formed on the exposed Sunda Shelf and in the southern archipelagos of Indonesia. At this time core sites were located in close proximity to the mouths of the Sunda Shelf palaeo-drainage systems on the emerged shelf (“Sundaland”). The progressive landward displacement of the coastline and breakdown of these vast drainage systems during deglaciation led to a decrease in influence of the kaolinite-rich southern sources. When the coastline had retreated closely to its present-day position in mid-Holocene times, the former dominance of southern sources was replaced by a stronger influence of illite-rich sources (e.g. Borneo). The overriding control of sea level changes on the clay mineral distribution patterns precludes a definite climatic interpretation of clay mineral data in terms of climatic/monsoonal changes in such highly dynamic sedimentary environment.     

Swedish coastal fisheries—From conflict mitigation to participatory management

Several research projects have studied Swedish coastal fishery to investigate the conflict between seals and fishery. In recent years, a strategy of participation by means of co-management has been unfolding. Realising that maintaining the coastal fishery requires societal support and knowledge integration, attempts have been made to introduce the principle of participatory management into the centralised Swedish fisheries management system. However, this co-management approach, presently implemented in six pilot projects, will take a long time to develop through a sustained process of experimentation and improvement.     

Surficial and Deep Earth Material Prediction from Geochemical Compositions

Prediction of true classes of surficial and deep earth materials using multivariate spatial data is a common challenge for geoscience modelers. Most geological processes leave a footprint that can be explored by geochemical data analysis. These footprints are normally complex statistical and spatial patterns buried deep in the high-dimensional compositional space. This paper proposes a spatial predictive model for classification of surficial and deep earth materials derived from the geochemical composition of surface regolith. The model is based on a combination of geostatistical simulation and machine learning approaches. A random forest predictive model is trained, and features are ranked based on their contribution to the predictive model. To generate potential and uncertainty maps, compositional data are simulated at unsampled locations via a chain of transformations (isometric log-ratio transformation followed by the flow anamorphosis) and geostatistical simulation. The simulated results are subsequently back-transformed to the original compositional space. The trained predictive model is used to estimate the probability of classes for simulated compositions. The proposed approach is illustrated through two case studies. In the first case study, the major crustal blocks of the Australian continent are predicted from the surface regolith geochemistry of the National Geochemical Survey of Australia project. The aim of the second case study is to discover the superficial deposits (peat) from the regional-scale soil geochemical data of the Tellus Project. The accuracy of the results in these two case studies confirms the usefulness of the proposed method for geological class prediction and geological process discovery.

     

Stream nitrate uptake and transient storage over a gradient of geomorphic complexity,north‐central Colorado,USA

The understanding of nutrient uptake in streams is impeded by a limited understanding of how geomorphic setting and flow regime interact with biogeochemical processing. This study investigated these interactions as they relate to transient storage and nitrate uptake in small agricultural and urban streams. Sites were selected across a gradient of channel conditions and management modifications and included three 180‐m long geomorphically distinct reaches on each of two streams in north‐central Colorado. The agricultural stream has been subject to historically variable cattle‐grazing practices, and the urban stream exhibits various levels of stabilisation and planform alteration. Reach‐scale geomorphic complexity was characterised using highly detailed surveys of channel morphology, substrate, hydraulics and habitat units. Breakthrough‐curve modelling of conservative bromide (Br^?) and nonconservative nitrate (NO₃^?) tracer injections characterised transient storage and nitrate uptake along each reach. Longitudinal roughness and flow depth were positively associated with transient storage, which was related to nitrate uptake, thus underscoring the importance of geomorphic influences on stream biogeochemical processes. In addition, changes in geomorphic characteristics due to temporal discharge variation led to complex responses in nitrate uptake. Copyright © 2011 John Wiley & Sons, Ltd.     

The Portuguese bend landslide

The Portuguese Bend landslide, in coastal southern California, is an active, slow-moving mass of blocks and debris that extends from the shoreline to moderate altitudes along part of the southerly margin of the Palos Verdes Hills. These hills form a peninsula that is underlain by Cenozoic sedimentary and volcanic rocks draped anticlinally over a core of Mesozoic schist. In the southerly parts of the peninsula, inherently weak units in the Altamira Shale Member of the Miocene Monterey Formation dip seaward in general concordance with the ground surface. Ground failure has been widespread in this area. It evidently began in mid- to late-Pleistocene time, and it has continued intermittently to the present.

The Portuguese Bend landslide represents a reactivation of movement of the eastern part of a complex of prehistoric landslides occupying an area of approximately two square miles. This latest episode of movement began in 1956, presumably in response to placement of fill during a road construction project. The active slide subsequently was enlarged by sequential failure of adjoining blocks of ground, and by September 1969 about 54,500,000 metric tons of debris was slowly moving downslope in an area of approximately 104 ha. Movement has been continuous since recent failure began in 1956, although the velocity of the active slide decreased markedly after that year. Between 1962 and 1972 the velocity fluctuated only slightly about an average value of about 1 cm per day.

The active slide is an irregular prism, roughly triangular in plan view. The southern side of the triangle trends approximately 1100 m east-west along a stretch of shoreline that essentially coincides with the toe of the slide. The other two sides of the triangle trend northeast and northwest from the ends of the toe and meet about 1200 m north of the shoreline. The thickness of the moving mass differs considerably from one place to another, reflecting both topographic irregularities and major undulations in the underlying surface of movement. The maximum thickness is approximately 75 m.

Movement is occurring along a distinct basal failure surface. The eastern part of the slide is underlain by bedrock, and is bordered by bedrock with a general structure that limits further deep-seated propagation of failure to the east and northeast. In contrast, the western part of the slide is underlain and bordered by extensive ancient landslide deposits that are marginally stable. Further encroachment of the active slide westward and northwestward into these materials was viewed as a distinct possibility at the time the dissertation was prepared and has occurred since then.

Continued movement of the Portuguese Bend landslide since 1956 has been due to four main factors. A rise in the water table during the period 1957–1968 has been documented in the northwestern part of the moving mass and is attributable mainly to infiltration of surface runoff entering numerous open fissures that cut the surface of the slide. The toe of the active slide daylights along the shoreline and is subjected to storm-wave erosion, so that any natural build-up of resisting forces is prevented in this area. The redistribution of mass as the slide has moved along an undulatory failure surface has been responsible for local fluctuations in the driving and resisting forces. Finally, smoothing of irregularities in the failure surface by the moving slide mass must have decreased some of the forces resisting movement.     

PHYSICAL GEOGRAPHY OF TROPICAL LATIN AMERICA: THE SPATIAL AND TEMPORAL HETEROGENEITY OF ENVIRONMENTS

For the past 40 years, studies of physical geography in tropical Latin America have concentrated on the spatial and temporal diversity of biophysical environments and biota. Environmental heterogeneity arises from historical and present-day interaction between climatic, geomorphologic, edaphic, and biogeographic systems. Recent research emphasizes three major themes involving these systems: Quaternary climate change; human-altered biophysical environments; and geomorphologic activity. Findings on these themes are evaluated with respect to the tropical highlands, the tropical lowlands and related extra-tropical areas. Research on physical geography in Latin America promises numerous contributions toward a better understanding of environmental conservation.