Titanian chondrodite and clinohumite in marbles from the Ötztal crystalline basement

Summary Marble lenses within the polymetamorphic Ötztal crystalline complex frequently contain pockets of clinohumite and chondrodite and their titanium-rich varieties. Chondrodites contain up to 9.1 wt% TiO₂ and clinohumites about half that amount. The maximum amounts of Ti in both minerals do not exeed values of 0.4 in the formula. XTi and X_F are correlated by a slope of –1, indicating the efficiency of the TiO₂Mg_–1F_–2 substitution at constant OH (Evans andTrommsdorff, 1983). Clinohumites sometimes contain lamellae which have nonstoichiometric cation ratios reflecting a composition between clinohumite and olivine. In many cases Ti-rich clinohumites and chondrodites coexist with Mg-ilmenite. Ti-rich clinohumites and chondrodites often break down to a symplectite of Ti-poor clinohumite (or olivine) and Mg-ilmenite. Parts of the marbles, which are barren of Mg-ilmenite contain F-rich clinohumites. The latter do not show any signs of breakdown features. We conclude therefore that fluorine stabilizes the humite group minerals to a wide range of metamorphic conditions. Ti-rich humite-group minerals are not stable till amphibolite facies conditions, and below F-rich humite-group minerals and olivine are the more stable phases in a H₂O-rich, SiO₂-poor carbonate system.

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Titanreiche Chondrodite und Klinohumite in Marmoren des Ötztalkristallins.

Zusammenfassung In Marmorlinsen des polymetamorphen Ötztalkristaliins kommen häufig titanarme und titanreiche Clinohumite und Chondrodite vor. Die höchsten Titan-Gehalte in Chondrodit betragen 9.1 Gew.-% TiO₂ während Clinohumite nur etwa die Hälfte dieses Wertes enthalten. Dies entspricht einem Maximalgehalt an Titan von 0.4 in den Formeln von Chondrodit und Clinohumit. Eine negative Korrelation zwischen X_Ti, und X_F mit der Steigung von –1 bestätigt die Wirksamkeit der Substitution TiO₂Mg_–1F_–2 bei konstantem OH (Evans undTrommsdorff, 1983). In Clinohumiten konnten nichtstöchiometrische Lamellen nachgewiesen werden, die chemisch zwischen Clinohumit und Olivin zusammengesetzt sind. Ti-reiche Clinohumite und Chondrodite koexistieren immer mit Mg-Ilmenit und wandeln sich häufig an ihren Rändern in einen Symplektit von Ti-ärmerem Clinohumit oder Olivin und Mg-Ilmenit um. In den Mg-Ilmenit freien Bereichen der Marmore kommen stets Ti-arme aber F-reiche Clinohumite vor, die niemals randliche Umwandlungserscheinungen zeigen. Die grobkörnigen (mm-großen) Humitminerale werden der variszischen Metamorphose in Amphibolitfazies zugeschrieben, während die Symplektite als Produkte der eoalpinen grünschieferfaziellen Überprägung angesehen werden. Wir schließen daraus, daß die Humitminerale durch Fluor in einem großen Bereich metamorpher Bedingungen stabilisiert werden, während Ti-reiche Humitminerale bei Bedingungen der Grünschieferfazies instabil werden und F-reiche Humitminerale und Olivin die stabilen Phasen in einem H₂O-reichen, SiO₂-armen Karbonatsystem sind.

     

Inter-annual and seasonal variations in the air–sea CO2 balance in the central Baltic Sea and the Kattegat

We estimated the net annual air–sea exchange of carbon dioxide (CO₂) using monitoring data from the East Gotland Sea, Bornholm Sea, and Kattegat for the 1993–2009 period. Wind speed and the sea surface partial pressure of CO₂ (pCO₂^w), calculated from pH, total alkalinity, temperature, and salinity, were used for the flux calculations. We demonstrate that regions in the central Baltic Sea and the Kattegat alternate between being sinks (−) and sources (+) of CO₂ within the −4.2 to +5.2 mol m⁻² yr⁻¹ range. On average, for the 1994–2008 period, the East Gotland Sea was a source of CO₂ (1.64 mol m⁻² yr⁻¹), the Bornholm Sea was a source (2.34 mol m⁻² yr⁻¹), and the Kattegat was a sink (−1.16 mol m⁻² yr⁻¹). Large inter-annual and regional variations in the air–sea balance were observed. We used two parameterizations for the gas transfer velocity (k) and the choice varied the air–sea exchange by a factor of two. Inter-annual variations in pCO₂^w between summers were controlled by the maximum concentration of phosphate in winter. Inter-annual variations in the CO₂ flux and gas transfer velocity were larger between winters than between summers. This indicates that the inter-annual variability in the total flux was controlled by winter conditions. The large differences between the central Baltic Sea and Kattegat were considered to depend partly on the differences in the mixed layer depth.     

Preservation of high‐P rocks coupled to rock composition and the absence of metamorphic fluids

Eclogites, blueschists and greenschists are found in close proximity to one another along a 1‐km coastal section where the Cyclades Blueschist Unit (CBU) is exposed on SE Syros, Greece. Here, we show that the eclogites and blueschists experienced the same metamorphic history: prograde lawsonite blueschist facies metamorphism at 1.2–1.9 GPa and 410–530°C followed, at 43–38 Ma, by peak blueschist/eclogite facies metamorphism at 1.5–2.1 GPa and 520–580°C. We explain co‐existence of eclogites and blueschists by compositional variation probably reflecting original compositional layering. It is also shown that the greenschists record retrogression at 0.34 ± 0.21 GPa and T = 456 ± 68°C. This was spatially associated with a shear zone on a scales of 10–100‐m and veins on a scale of 1–10‐cm. Greenschist facies metamorphism ended at (or shortly after) 27 Ma. We thus infer a period of metamorphic quiescence after eclogite/blueschist facies metamorphism and before greenschist facies retrogression which lasted up to 11–16 million years. We suggest that this reflects an absence of metamorphic fluid flow at that time and conclude that greenschist facies retrogression only occurred when and where metamorphic fluids were present. From a tectonic perspective, our findings are consistent with studies showing that the CBU is (a) a high‐P nappe stack consisting of belts in which high‐P metamorphism and exhumation occurred at different times and (b) affected by greenschist facies metamorphism during the Oligocene, prior to the onset of regional tectonic extension.     

Effects of the Upstream-Flow Regime and Canyon Aspect Ratio on Non-linear Interactions Between a Street-Canyon Flow and the Overlying Boundary Layer

Large-scale structures within a rough-wall boundary layer generated over a cube array have recently been linked to small-scale fluctuations close to the roughness through a dynamical mechanism similar to amplitude modulation. Demonstrating the existence of this mechanism for different roughness types is a crucial step towards the development of a generic model for wind fluctuations in the urban canopy. Here the influence of the upstream roughness geometry (two-dimensional (2D) and three-dimensional (3D)) and planform packing density (\( \lambda_{p} \)) and street-canyon aspect ratio on the non-linear interactions between large-scale momentum regions and the small scales induced by the presence of the roughness is studied within a wind tunnel using combined particle-image velocimetry and hot-wire anemometry. A multi-time delay linear stochastic estimation is used to decompose the flow into large scales that participate in modulation and the remaining small scales. Using three different upstream roughness configurations composed of either 3D cubes or 2D rectangular blocks it is shown that the upstream roughness configuration has an influence on the non-linear interactions in the rough-wall boundary layer. Analysis of the turbulence skewness decomposition shows a change in the location of the maximum of the term \( \overline{{u_{L}^{\prime} u_{S}^{\prime 2}}} \), which represents the influence of the large-scale momentum regions on the small scales, whilst the temporal correlation shows a modification of the interaction located closer to the roughness with a change from 3D to 2D roughness. Furthermore, a two-point spatio–temporal correlation demonstrates that the non-linear relationship is significantly modified in the wake-interference-flow regime compared to the skimming-flow regime. Through skewness decomposition and temporal correlations the canyon aspect ratio is shown to have no influence on the non-linear interactions, indicating that the mechanism depends only on the flow developing upstream. Finally, although the upstream roughness configuration is shown to influence the non-linear interactions, the nature of the mechanism remains the same in all configurations.     

Analysis of shallow gas and fluid migration within the Plio-Pleistocene sedimentary succession of the SW Barents Sea continental margin using 3D seismic data

Three-dimensional (3D) seismic data acquired for hydrocarbon exploration reveal that gas accumulations are common within the 2–3 km thick Plio-Pleistocene stratigraphic column of the south-western Barents Sea continental margin. The 3D seismic data have relatively low-frequency content (<40 Hz) but, due to dense spatial sampling, long source-receiver offsets, 3D migration and advanced interpretation techniques, they provide surprisingly detailed images of inferred gas accumulations and the sedimentary environments in which they occur. The presence of gas is inferred from seismic reflection segments with anomalously high amplitude and reversed phase, compared with the seafloor reflection, so-called bright spots. Fluid migration is inferred from vertical zones of acoustic masking and acoustic pipes. The 3D seismic volume allows a spatial analysis of amplitude anomalies inferred to reflect the presence of gas and fluids. At several locations, seismic attribute maps reveal detailed images of flat spots, inferred to represent gas–water interfaces. The data indicate a focused fluid migration system, where sub-vertical faults and zones of highly fractured sediments are conduits for the migration of gas-bearing fluids in Plio-Pleistocene sediments. Gas is interpreted to appear in high-porosity fan-shaped sediment lobes, channel and delta deposits, glacigenic debris flows and sediment blocks, probably sealed by low-permeability, clayey till and/or (glacio)marine sediments. Gas and fluid flow are here attributed mainly to rapid Plio-Pleistocene sedimentation that loaded large amounts of sedimentary material over lower-density, fine-grained Eocene oozes. This probably caused pore-fluid dewatering of the high-fluid content oozes through a network of polygonal faults. The study area is suggested to have experienced cycles of fluid expulsion and hydrocarbon migration associated with glacial–interglacial cycles.     

Gas hydrate and free gas indications within the Cenozoic succession of the Bjørnøya Basin, western Barents Sea

Multichannel seismic data, containing high-amplitude reflections from Cenozoic sediments of the Bjørnøya Basin, southwestern Barents Sea, have been studied, inferring the existence of gas hydrate and free gas. The Cenozoic succession comprises Late Palaeocene and Early Eocene claystones and siltstones and locally also some sandstones overlain by Late Pleistocene glaciogenic sediments. The inferred gas hydrate and free gas accumulations are mainly located in the vicinity of larger faults which can be followed up to base Tertiary level, and which seem to have controlled the geographical distribution of the accumulations. Free gas accumulations are inferred to occur most frequently within the Late Palaeocene strata that occur below the gas hydrate stability zone, and indicate that relatively small gas leakages from deeper accumulations have dominated. Larger gas leakages have probably led to gas migration up into the gas hydrate stability zone and, together with the increasing thickness of the hydrate stability zone towards the north, control the distribution of the suspected gas hydrates. The inferred gas leakages are closely related to the Cenozoic evolution of the Barents Sea, and are probably caused by gas expansion due to the removal of up to 1 km of sediments from the Barents Sea shelf and/or reservoir tilting during the Late Cenozoic glaciations which affected this area.     

Farm size comparison with analytical model of linear generator wave energy converters

Ocean wave energy is an emerging kind of renewable energy, and several energy conversion methods are available today. One solution is to connect a buoy to a linear generator. Such units are quite small (10–100 kW), and farm solutions are suggested to increase power production. This paper shows the results from small farm simulations where the translator motion is varied for the generators in the farm.Simulations with five and 10 units show that power fluctuations decrease with an increasing number of generators.