H-chondrites: Trace element clues to their origin

We have analyzed 10 H-chondrites for 20 trace elements, using RNAA. The meteorites included 4 of petrologic type 4 and 2 each of types 3, 5 and 6.The data show that H-chondrites are not isochemical. H3's are depleted by some 10% not only in Fe (Dodd, 1976), but also in the siderophiles Os, Re, Ir, Ni, Pd, Au, and Ge. Moreover, the abundance pattern of siderophiles varies systematically with petrologic type. As similar fractionations of REE have been observed by Nakamura (1974), it appears that both the proportions and compositions of the main nebular condensates varied slightly during accretion of the H-chondrites. Thus the higher petrologic types are independent nebular products, not metamorphosed descendants of lower petrologic types.Abundances of highly volatile elements (Cs, Br, Bi, Tl, In, Cd, Ar³⁶) correlate with petrologic type, declining by ≤ 10^?3 from Type 3 to Type 6. The trends differ from those for artificially heated Type 3's (Ikramuddinet al., 1977b; Herzoget al., 1979), but agree passably with theoretical curves for nebular condensation. Apparently the low volatile contents of higher petrologic types are a primary feature, not the result of metamorphic loss.The mineralogy of chondrites suggests that they accreted between 405 K (absence of Fe₃O₄) and 560 K (presence of FeS), and the abundances of Tl, Bi, and In further restrict this interval to 420–500 K. Accretion at 1070 ± 100 K, as proposed by Hutchisonet al. (1979, 1980), leads to some extraordinary problems. Volatiles must be injected into the parent body after cooling, which requires permeation of the body by 10¹¹ times its volume of nebular gas. This process must also achieve a uniform distribution of the less volatile elements (Rb, Cu, Ag, Zn, Ga, Ge, Sn, Sb, Se, F), without freezeout in the colder outer layers.Factor analysis of our data shows 3 groupings: siderophiles (Os, Re, Ir, Ni, Pd, Au, and Ge), volatiles (Ag, Br, In, Cd, Bi, and Tl) and alkalis (Rb and Cs). The remaining 5 elements (U, Zn, Te, Se, and Sb) remain unassociated.     

On the accuracy of location of local shocks on the territory of Czechoslovakia and adjacent areas

Summary The calculation procedures for determining epicentre parameters of weak near shocks with foci in Poland are discussed and tested for explosions with known epicentres.

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The pre-Cretaceous deep-seated tectonics of the Abukuma massif and its place in the structural framework of Japan

The structures and microstructures of the Takanuki and Hitachi areas in the Abukuma massif, Northeast Japan are described. In the Takanuki area, the basic Gosaisho series thrusts the pelitic Takanuki ones in a HP metamorphic context. The nappe structure is afterwards refolded by a migmatitic dome: the Samegawa dome, in a HT metamorphic context. Microtectonic analysis shows that the nappe was transported from south to north along the stretching lineation. Geometric features suggest that the Samegawa dome was emplaced by diapirism. The role of the thrust surface as an instable interface promoting the doming is emphasized. The Hitachi metamorphic rocks composed of basic schist, limestone and sandstone shist thrust the pelitic rocks of the western Hitachi gneisses. As for the Takanuki area, the thrusting occurred in ductile synmetamorphic conditions with a north or northeastward displacement. Owing to lithologic, petrologic, structural similitudes, the nappe of the Hitachi metamorphic rocks and that of the Gosaisho series are unified into a unique nappe with a northward motion. The emplacement occurred between late Permian and late Cretaceous likely in late Jurassic. The allochthonous units of the Abukuma massif are correlated with the Green Schist nappe described in Southwest Japan, since they are surrounded by the same zones, namely the Tanba zone and the Kurosegawa-Kitakami one. Moreover both in Southwest and Northeast Japan, the emplacement of the Green Schist nappes is due to a shear deformation inducing rotational structures along the stretching lineation indicating the same sense of transport, that is eastward in Southwest Japan and northward in Northeast Japan, owing to the late bending of the Japanese Islands. The late Jurassic nappe structure is obliquely overprinted by a HT metamorphism, Ryoke in Southwest Japan, Abukuma in Northeast Japan, and afterwards cut by late faults as the Median Tectonic Line or the Tanakura fault, giving rise to the present complexity.     

Titanian chondrodite and clinohumite in marbles from the Ötztal crystalline basement

Summary Marble lenses within the polymetamorphic Ötztal crystalline complex frequently contain pockets of clinohumite and chondrodite and their titanium-rich varieties. Chondrodites contain up to 9.1 wt% TiO₂ and clinohumites about half that amount. The maximum amounts of Ti in both minerals do not exeed values of 0.4 in the formula. XTi and X_F are correlated by a slope of –1, indicating the efficiency of the TiO₂Mg_–1F_–2 substitution at constant OH (Evans andTrommsdorff, 1983). Clinohumites sometimes contain lamellae which have nonstoichiometric cation ratios reflecting a composition between clinohumite and olivine. In many cases Ti-rich clinohumites and chondrodites coexist with Mg-ilmenite. Ti-rich clinohumites and chondrodites often break down to a symplectite of Ti-poor clinohumite (or olivine) and Mg-ilmenite. Parts of the marbles, which are barren of Mg-ilmenite contain F-rich clinohumites. The latter do not show any signs of breakdown features. We conclude therefore that fluorine stabilizes the humite group minerals to a wide range of metamorphic conditions. Ti-rich humite-group minerals are not stable till amphibolite facies conditions, and below F-rich humite-group minerals and olivine are the more stable phases in a H₂O-rich, SiO₂-poor carbonate system.

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Titanreiche Chondrodite und Klinohumite in Marmoren des Ötztalkristallins.

Zusammenfassung In Marmorlinsen des polymetamorphen Ötztalkristaliins kommen häufig titanarme und titanreiche Clinohumite und Chondrodite vor. Die höchsten Titan-Gehalte in Chondrodit betragen 9.1 Gew.-% TiO₂ während Clinohumite nur etwa die Hälfte dieses Wertes enthalten. Dies entspricht einem Maximalgehalt an Titan von 0.4 in den Formeln von Chondrodit und Clinohumit. Eine negative Korrelation zwischen X_Ti, und X_F mit der Steigung von –1 bestätigt die Wirksamkeit der Substitution TiO₂Mg_–1F_–2 bei konstantem OH (Evans undTrommsdorff, 1983). In Clinohumiten konnten nichtstöchiometrische Lamellen nachgewiesen werden, die chemisch zwischen Clinohumit und Olivin zusammengesetzt sind. Ti-reiche Clinohumite und Chondrodite koexistieren immer mit Mg-Ilmenit und wandeln sich häufig an ihren Rändern in einen Symplektit von Ti-ärmerem Clinohumit oder Olivin und Mg-Ilmenit um. In den Mg-Ilmenit freien Bereichen der Marmore kommen stets Ti-arme aber F-reiche Clinohumite vor, die niemals randliche Umwandlungserscheinungen zeigen. Die grobkörnigen (mm-großen) Humitminerale werden der variszischen Metamorphose in Amphibolitfazies zugeschrieben, während die Symplektite als Produkte der eoalpinen grünschieferfaziellen Überprägung angesehen werden. Wir schließen daraus, daß die Humitminerale durch Fluor in einem großen Bereich metamorpher Bedingungen stabilisiert werden, während Ti-reiche Humitminerale bei Bedingungen der Grünschieferfazies instabil werden und F-reiche Humitminerale und Olivin die stabilen Phasen in einem H₂O-reichen, SiO₂-armen Karbonatsystem sind.

     

Olivine phenocrysts of Hawaiian olivine tholeiite and oceanite

Olivine phenocrysts of Hawaiian tholeiites display a variety of textures and a variation in composition which is due to supercooled crystallization. The highest forsterite content measured is 91%, and the highest magnesia content estimated for a tholeiitic liquid is 17%, using the olivine geothermometer. The liquid of this composition may be either a primary magma or a primitive magma. It is not yet possible to specify any particular composition range for the primary Hawaiian tholeiites.     

Eduard Suess' relations to the Pre-1950 schools of thought in global tectonics

Two main schools of thought in global tectonics are recognized during the first half of the XXth century on the basis of their proponents' attitude towards the principle of uniformitarianism and their belief in an inherent order and regularity vs. disorder and irregularity in tectonics. One group, here called the Wegener-Argand school, had a unifomitarian approach to global tectonics and believed in an inherently irregular Nature, in which probability rather than determinism was believed to be a realistic approach. The other, here called the Kober-Stille school, was largely non-uniformitarian (neocatastrophist) and believed in an orderly, regular Nature. These two schools correspond to Argand's mobilists and fixists respectively. In this paper I show that Eduard Suess was a convinced uniformitarian as far as his views on global tectonics are concerned and denied any inherent regularity in tectonic phenomena, temporal or spatial. In his interpretations of the causes and nature of orogeny, nature of geosynclines, and causes and nature of stabilisation, Suess appears to be the predecessor of the Wegener-Argandians, i. e. of the mobilists and not of the Kober-Stilleans as hitherto assumed. Although he remained a fixist and contractionist to the end Suess seems to have paved the way for the mobilists much as he did for the nappists during the last quarter of the XIX^th century.

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Zusammenfassung Während der ersten Hälfte des XX. Jahrhunderts kann man zwei globaltektonische Denkungsweisen oder Großschulen unterscheiden, die gekennzeichnet sind durch ihre Stellungnahme zum aktualistischen Prinzip in der Tektonik und ob sie an eine ordentliche und regelmäßige Natur glaubten oder nicht. Die erste, hier die Wegener-Argand-Schule genannt, hatte die Gültigkeit des aktualistischen Prinzips in der Tektonik anerkannt und die Natur, im Grunde genommen, als unordentlich und unregelmäßig betrachtet. Die Anhänger dieser Denkweise glaubten, daß probablistische Lösungen tektonischer Probleme realistischer seien als deterministische. Die andere Großschule, hier die Kober-Stille-Schule genannt, war im Grunde genommen anti-aktualistisch (Neo-Katastrophistisch) und glaubte, daß die Natur ordentlich und regelmäßig sei. Diese zwei Schulen entsprechen Argands' Einteilung in Mobilisten und Fixisten. In diesem Artikel zeige ich, daß E. Suess ein überzeugter Aktualist in bezug auf seine tektonischen Ansichten war, und daß er jede Regelmäßigkeit, zeitlicher oder räumlicher Art, der tektonischen Ereignisse ablehnte. In seinen Interpretationen der Ursachen und der Art der Orogenese, der Art der Geosynklinalen und der Ursache und der Art der Erstarrung, erscheint Suess als ein Vorgänger der Wegener-Argand-Schule, d. h. der Mobilisten, deren Gedankengänge er viel näher stand als dem der Kober-Stille-Schule. Obwohl Suess selbst bis zuletzt ein Fixist und Kontraktionist blieb, bereitete er eigentlich den Weg für die Mobilisten, wie er es früher auch für die Nappisten getan hatte.

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Résumé Durant la première moitié du XX^e siêcle, on peut distinguer deux principales écoles de pensée en tectonique globale, selon l'attitude de ses adhérents envers le principe de l'actualisme et selon leur croyance ou non à un ordre et une régularité intrinsèques en tectonique. Le premier groupe, ici appelé l'école de Wegener-Argand, suivit une voie actualiste et crût la Nature essentiellement irrégulière, de telle sorte qu'un traitement probabiliste fût considéré plus réaliste qu'un traitement déterministe. L'autre, appelé ici l'école de Kober-Stille, était essentiellement non-actualiste (néo-catastrophiste) et crût à une Nature ordonnée, régulière. Ces deux écoles correspondent aux mobilistes et aux fixistes d'Argand. Dans cet article, je montre que E. Suess, fût un actualiste convaincu, du moins en ce qui concerne ses opinions sur la tectonique globale, et qu'il rejetta toute notion de régularité dans les phénomènes tectoniques, autant spatiaux que temporaux. Dans ses interprétations des causes et de la nature de l'orogenèse, de la nature des géosynclinaux, et des causes et de la nature de la «stabilisation», Suess est un des précurseurs des «Wegener-Argandiens», c'est à dire des mobilistes. Bien qui'il fût demeuré, jusqu'à la fin de sa vie, fixiste et un avocat de la contraction, il semble que Suess ait préparé la voie aux mobilistes, de la mème façon qu'il l'avait fait pour les nappistes pendant le derier quart du XIX^e siècle.

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Neotectonics of the Pontides: implications for ‘incompatible’ structures along the North Anatolian fault

Data for the post-Serravallian, ‘neotectonic’ evolution of the Pontides in northern Turkey indicate predominant ENE-WSW shortening with complementary NNW-SSE extension. We present a new fault plane solution for the Bartin earthquake (3 September 1968) and compare its mechanism with the movement picture of other neotectonic faults in the Pontides and northern Greece together with that of the Thessaloniki earthquake (20 May 1978). The general strain pattern exhibited by these structures agrees remarkably well with that inferred from early Tortonian-early Pleistocene structures reported from within the North Anatolian fault zone, which have been interpreted as indicating a possible reversal of the sense of movement along the North Anatolian transform fault. Here, we argue that such ‘incompatible’ structures may be related to the overall E-W shortening of Anatolia and the southern parts of the Black Sea resulting from the sideways continental escape from around the African and the Arabian promontories, rather than to hypothetical reversal of motion along the North Anatolian fault, for which there is no evidence other than the above-mentioned ‘incompatible’ structures. This new model also has important implications for seismicity and earthquake risk in regions contained within the southern part of the Black Sea plate.     

Evaluation of a high-resolution regional climate simulation over Greenland

A simulation of the 1991 summer has been performed over south Greenland with a coupled atmosphere–snow regional climate model (RCM) forced by the ECMWF re-analysis. The simulation is evaluated with in-situ coastal and ice-sheet atmospheric and glaciological observations. Modelled air temperature, specific humidity, wind speed and radiative fluxes are in good agreement with the available observations, although uncertainties in the radiative transfer scheme need further investigation to improve the model’s performance. In the sub-surface snow-ice model, surface albedo is calculated from the simulated snow grain shape and size, snow depth, meltwater accumulation, cloudiness and ice albedo. The use of snow metamorphism processes allows a realistic modelling of the temporal variations in the surface albedo during both melting periods and accumulation events. Concerning the surface albedo, the main finding is that an accurate albedo simulation during the melting season strongly depends on a proper initialization of the surface conditions which mainly result from winter accumulation processes. Furthermore, in a sensitivity experiment with a constant 0.8 albedo over the whole ice sheet, the average amount of melt decreased by more than 60%, which highlights the importance of a correctly simulated surface albedo. The use of this coupled atmosphere–snow RCM offers new perspectives in the study of the Greenland surface mass balance due to the represented feedback between the surface climate and the surface albedo, which is the most sensitive parameter in energy-balance-based ablation calculations.     

Installation of a vertical slurry wall around an Italian quarry lake: complications arising and simulation of the effects on groundwater flow

Slurry walls are non-structural barriers that are constructed underground to impede groundwater flow or manage groundwater control problems. The study area is in the Piemonte plain (Italy), close to the River Po. Quarrying works carried out below the piezometric surface created two big quarry lakes. The local groundwater system is characterized by a lower semi-confined aquifer, which is overlain by a semi-permeable bed of clayey peat (aquitard) and an upper unconfined aquifer. Locally, the peat fades away and the granulometry of this horizon becomes silty sandy. A planned enlargement of the quarry will increase the size and depth of the quarry lakes. So the aquitard bed between the two aquifers will be damaged, creating a mixing rate of groundwater. Such a procedure would not be compatible with the presence of two municipal wells upstream from the quarries. Consequently, the installation of a vertical diaphragm (slurry wall) is recommended to separate the aquifers and to act as a filter for the groundwater flowing from the unconfined to the semi-confined aquifer. To predict the consequences caused by the installation of the vertical diaphragm separating the unconfined aquifer and the semi-confined one, a specifically adjusted finite-difference model was used. The model showed a maximum rising of the water table equal to 12 cm, just upstream of the diaphragm and for a distance of about 100 m, and a maximum lowering of 2 cm just downstream of the diaphragm. However, the slurry wall would not cause any change in the piezometric head in the area where there are municipal wells and, hence, will not have any negative effect on the functionality of the municipal wells. Moreover, the migration of water from the unconfined aquifer through the vertical diaphragm will stimulate a series of attenuation and auto-depuration processes of eventual contaminants. These processes are due to the higher crossing time that the groundwater flow takes to go through the vertical barrier (t _a = 96.5 days, whereas for the horizontal semi-permeable layer t _a = 9.6 days). So, the vertical diaphragm can be a resolutive element, representing a mediation and separation factor between the unconfined and the semi-confined aquifers along the border of the quarrying areas, and a protective barrier for the water quality of the quarry lake and the semi-confined aquifer.     

A structural model for the seismicity of the Arudy (1980) epicentral area (Western Pyrenees, France)

The Western Pyrenees presents a diffuse and moderate ( M ≤ 5.7) instrumental seismicity. It nevertheless historically suffered from strong earthquakes (I = IX MSK). The seismic sources of these events are not yet clearly identified. We focus on the Arudy (1980) epicentral area ( M = 5.1) and propose here the reactivation of early Cretaceous normal faults of the Iberian margin as a potential source. The late Cretaceous inversion of this basin, first in a left-lateral strike-slip mode and then in a more frontal convergence, resulted in a pop-up geometry. This flower structure attests of the presence of a deep crustal discontinuity.
The present-day geodynamic arrangement suggests that this accident is reactivated in a right lateral mode. This reactivation leads to a strain partitioning between the deep discontinuity that accommodates the lateral component of the motion and shallow thrusts, rooted on this discontinuity. These thrusts accommodate the shortening component of the strain. The distribution of the instrumental seismicity fits well the structural model of the Arudy basin. Whatever the compressive regional context, the structural behaviour of the system explains too the extensive stress tensor determined for the Arudy crisis if we interpret it in terms of strain ellipsoid. Indeed numerical modelling has shown that this concomitant activity of strike-slip and thrust faulting results in an extensive component that can rise 50 per cent of the finite strain.
We identify too a 25–30 km long potential seismic source for the Arudy area. The size of the structure and its potential reactivation in a strike-slip mode suggest that a maximum earthquake magnitude of ∼6.5 could be expected. The extrapolation of this model at the scale of the Western Pyrenees allows to propose other potential sources for major regional historical earthquakes.