β-环糊精包合态三氟氯氰杀虫剂的制备

为了进一步提高三氟氯氰菊酯农药的防治效果。寻找适宜的农药新剂型，我们用液相法制备了三氟氯氰菊酯－β－环糊精包合物，并以水为基质进行了稳定性观察，同时又以差热分析法和气相色谱法确认了包合物的形成，以旋光度法证明两者间的包合比。结果表明，三氟氯氰菊酯与β-环糊精可形成1：1型包合物，该包合物稳定性高，具有一定的水溶性，而且在水中稳定，所以有望通过环糊 包合作用将三氟氯氰菊酯帛成水剂；当以气相法测试包合态三氟氯氰菊酯含量时，必须将其解络，使之成为游离状态，然后按常规方法进行含量测定。     

松辽盆地后五家户气田沉积相特征与控气作用

本文对松辽盆地东南部后五家户气田划分出22种沉积微相,建立7种相层序,分析了扇三角洲及三角洲沉积环境对天然气成藏的控制作用。指出了扇三角洲前缘砂体和三角洲前缘砂体较为发育,沉积物源来自气田东北部和东南部两个方向。后五家户气田多为构造—岩性气藏和岩性气藏。     

矿物热重差分析的应用

根据矿物差热曲线特征温度，拟定使用热重差分析岩矿中全碳、结晶水、硫化物硫和二氧化碳等项目的灼烧温度范围，并进行热重差分析。所得的结果与其他方法结果一致。     

Discussion on the feature of strong earthquake: Orderly distribution in time, space and intensity before the Western Kunlun Mountain Pass M=8.1 earthquake

Introduction The Western Kunlun Mountain Pass M=8.1 earthquake occurred on November 14, 2001 is the other M=8 earthquake occurred 50 years after Dangxiong, Tibet M=8.0 earthquake in Chinese mainland. The earthquake has caused the attention of the seismologists in the following aspects: 1) The fracture length is more than 400 km, which is far away from the estimated length by the statistic empirical function between the magnitude and the fracture length (WANG, et al, 2002); 2) The aftersh…     

盆地岩石圈结构与油气成藏及分布

本文综述了大陆岩石圈研究现状和克拉通盆地、裂谷盆地和前陆盆地的岩石圈结构特征,指出在古裂谷、褶皱带或区域性深断裂等陆壳构造薄弱带上发育起来的多期叠合盆地,具有很好的含油气前景。大型含油气盆地往往存在地幔上隆、地壳减薄和地壳内低速层,盆地基底沉降与盖层沉积厚度较大。适度的后期构造活动改造和岩浆活动有利于沉积盆地内油气生成与保存。     

Optimization of the Sampling Technique for the Determination of Dissolved Hydrogen in Groundwater

In this study a field‐sampling technique for dissolved hydrogen (H₂) in groundwater will be presented which allows the transport of gaseous samples into the laboratory for further analysis. The method consists of transferring the headspace trapped in a gas‐sampling bulb which is continuously purged by groundwater into previously evacuated vials using a gas‐tight syringe. Three transfer steps with preceding evacuation of the vial led to a H₂‐recovery of 100 % in laboratory experiments. The method has been applied to determine H₂ concentrations in an aquifer contaminated with chlorinated solvents. Tests concerning the effect of different pumping techniques on H₂ concentrations revealed that most reliable values were obtained with a bladder pump, while an electrically driven submersible pump generated considerable amounts of hydrogen due to electrochemical interactions with the sampled water. Concentrations of dissolved hydrogen in field and laboratory samples were about two orders of magnitude higher when sampling was performed with the electrically driven submersible pump compared to sampling with the bladder pump and a peristaltic pump. Lab experiments with a Plexiglas reservoir to produce H₂‐enriched water were used to study the effect of two tubing materials (PVC, polyamide) on H₂ losses. PVC tubing turned out to allow transfer of H₂‐enriched water over 25 m without significant losses, while PA‐tubing was not suitable for sampling of H₂.     

WebGIS应用服务器数据调度优化策略研究

应用服务器的数据调度是影响WebGIS系统性能的主要因素之一。本文在分析WebGIS体系结构的基础上,探讨了可以在服务器端数据调度中应用的若干优化技术,包括对象化包装、连接池、线程池、扩展SQL、多步传输协议和代理服务机制。经在实验中验证,采用这些技术的WebGIS系统在同等网络环境下,可以显著提高整体性能。     

Evidence for fullerenes in solid bitumen from pillow lavas of Proterozoic age from Mítov (Bohemian Massif, Czech Republic)

Andesitic pillow lavas containing biogenic, solid bitumen (SB) are a constituent of a Neoproterozoic volcanosedimentary sequence (Teplá-Barrandian unit, Bohemian Massif) in the Mítov area of the Czech Republic. A black shale formation that is crosscut by these andesitic basalts is 565 Ma old. Carbon disulfide extracts of two powdered samples of SB contain 0.2 and 0.3 ppm of C₆₀, respectively, as determined by high-pressure liquid chromatography. The peak assignment based on retention time is fully supported by high-resolution electron ionization mass spectrometry (EI-MS). No C₇₀ was detected, nor was C₆₀ found in two other SB samples from this locality. Other investigated carbonaceous samples from Bohemia (coals and anthracites of Upper Paleozoic age and anthraxolite, graphitoids, and graphite of Upper Proterozoic age) did not contain fullerenes at concentrations above the detection limit of 0.01 ppm. The absence of C₆₀ in these samples was confirmed by EI-MS. The proposed mechanism of fullerene formation involves a primary algal phase, generation of a hydrocarbonaceous mixture in the course of thermal evolution of the sedimentary series, and their high-temperature transformation related to the extrusion of basalt. An important feature for fullerene conservation was the enclosure of fullerenes in SB with a structure similar to glasslike carbon, where the fullerene was protected against oxidation.