Early diagenetic vivianite [Fe3(PO4)2 · 8H2O] in a contaminated freshwater sediment and insights into zinc uptake: A μ-EXAFS, μ-XANES and Raman study

The sediments in the Salford Quays, a heavily-modified urban water body, contain high levels of organic matter, Fe, Zn and nutrients as a result of past contaminant inputs. Vivianite [Fe₃(PO₄)₂ · 8H₂O] has been observed to have precipitated within these sediments during early diagenesis as a result of the release of Fe and P to porewaters. These mineral grains are small (<100 μm) and micron-scale analysis techniques (SEM, electron microprobe, μ-EXAFS, μ-XANES and Raman) have been applied in this study to obtain information upon the structure of this vivianite and the nature of Zn uptake in the mineral. Petrographic observations, and elemental, X-ray diffraction and Raman spectroscopic analysis confirms the presence of vivianite. EXAFS model fitting of the FeK-edge spectra for individual vivianite grains produces Fe–O and Fe–P co-ordination numbers and bond lengths consistent with previous structural studies of vivianite (4O atoms at 1.99–2.05 Å; 2P atoms at 3.17–3.25 Å). One analysed grain displays evidence of a significant Fe³⁺ component, which is interpreted to have resulted from oxidation during sample handling and/or analysis. EXAFS modelling of the Zn K-edge data, together with linear combination XANES fitting of model compounds, indicates that Zn may be incorporated into the crystal structure of vivianite (4O atoms at 1.97 Å; 2P atoms at 3.17 Å). Low levels of Zn sulphate or Zn-sorbed goethite are also indicated from linear combination XANES fitting and to a limited extent, the EXAFS fitting, the origin of which may either be an oxidation artifact or the inclusion of Zn sulphate into the vivianite grains during precipitation. This study confirms that early diagenetic vivianite may act as a sink for Zn, and potentially other contaminants (e.g. As) during its formation and, therefore, forms an important component of metal cycling in contaminated sediments and waters. Furthermore, for the case of Zn, the EXAFS fits for Zn phosphate suggest this uptake is structural and not via surface adsorption.     

Splintered networks: The colonial and contemporary waters of Jakarta

This paper queries the relevance of the ‘splintering urbanism’ thesis to postcolonial cities of the South, and responds to calls for the production of a decentered theory of urbanization through a case study of Jakarta. Drawing on archival and interview data, the paper demonstrates that Jakarta has, since its inception, been characterized by a high degree of differentiation of access to water supply, and of fragmentation of water supply networks. We document the origins of this fragmentation in the colonial era, and trace the legacy of the colonial constructions within the postcolonial city. Moreover, we demonstrate that the introduction of private sector management (in 1988) has not significantly disrupted, and certainly not caused, this pattern. In short, we provide evidence to support our claim that Jakarta’s water supply system is ‘splintered’ rather than ‘splintering’, and demonstrate that this phenomenon was not caused by the rise (or fall) of the ‘modern infrastructural ideal’. In order to explain this sustained fragmentation of infrastructure and access, the paper develops a conceptual framework of postcolonial governmentality that emphasizes the interrelationship between materiality, governmentality, identity, and urbanization, in particular through demonstrating how contested and evolving process of social differentiation are linked to the differentiation of water supply infrastructures and of urban spaces. Although we are wary of any simplistic comparisons between the colonial past and present, we argue that the optic of postcolonial governmentality provides a powerful lens for dissecting the power relations that continue to structure access to water supply and urban space in cities in the South.     

Climate‐induced migration: Exploring local perspectives in Kiribati

A number of studies have indicated that the long term habitability of Kiribati, a low‐lying country in the central tropical Pacific Ocean, is tenuous given the impacts of climate change, particularly sea level rise. In an effort to plan for the resultant challenges ahead, a number of national policies and programs have surfaced to reduce the impact of localized changes on people's livelihoods. This study explores how local community members (n = 60) have taken it upon themselves to respond to the impacts of climate change by utilizing a number of different strategies. The results highlight that: first, respondents consider climate change to be the most concerning issue for sustaining their livelihoods; second, respondents have built physical defences, relocated temporarily or permanently, and sought government assistance to adapt to localized climate‐related impacts; and third, the majority of respondents indicated that they would migrate as a long term strategy to respond to the future impacts of climate change.     

He I 10830 observations of the 3N/M4.0 flare of 4 September, 1982

Hei 10830 Å spectroheliograms of a major 3N two-ribbon flare occurring in Boulder Region 3885/3886 early on 4 September, 1982 are discussed and compared with H and soft X-ray observations of the event. This flare, observed for more than 60 hr in Hei 10830, was associated with the eruption of a large filament in the active region complex, the formation of coronal holes, a long-duration soft X-ray event, and was the probable source of a earthward coronal mass ejection and the largest geomagnetic storm of this solar cycle. The results of this study suggest the Hei flare is a chromospheric manifestation of the X-ray coronal loop structures associated with flares.Visitor, National Solar Observatory, operated by the Association of Universities for Research in Astronomy, Inc., under contract with the National Science Foundation.     

Conjoint analysis of small‐boat recreational fishers in New Zealand

Conjoint analysis is a useful technique to assist recreational managers formulate policy, and develop strategies to efficiently and effectively distribute resources. Accurate estimates of the value of natural resources remain challenging, despite the development of a number of decision analysis techniques. This recreation geography study uses conjoint analysis to examine the relative importance of attributes associated with small‐boat recreational fishing experiences and demonstrates the value of conjoint analysis as a non‐market valuation tool. We found that the choices associated with companionship are the most important factors of recreational fishing and more tangible attributes such as the quality of launch facilities and catch probability are the least important factors.     

Environmental impacts of urban growth from an integrated dynamic perspective: A case study of Shenzhen, South China

China is home to one-fifth of the world's population and that population is increasingly urban. The landscape is also urbanizing. Although there are studies that focus on specific elements of urban growth, there is very little empirical work that incorporates feedbacks and linkages to assess the interactions between the dynamics of urban growth and their environmental impacts. In this study, we develop a system dynamics simulation model of the drivers and environmental impacts of urban growth, using Shenzhen, South China, as a case study. We identify three phases of urban growth and develop scenarios to evaluate the impact of urban growth on several environmental indicators: land use, air quality, and demand for water and energy. The results show that all developable land will be urban by 2020 and the increase in the number of vehicles will be a major source of air pollution. Demand for water and electricity will rise, and the city will become increasingly vulnerable to shortages of either. The scenarios also show that there will be improvements in local environmental quality as a result of increasing affluence and economic growth. However, the environmental impacts outside of Shenzhen may increase as demands for natural resources increase and Shenzhen pushes its manufacturing industries out of the municipality. The findings may also portend to changes other cities in China and elsewhere in the developing world may experience as they continue to industrialize.     

Stratospheric temperature trends: impact of ozone variability and the QBO

In most climate simulations used by the Intergovernmental Panel on Climate Change 2007 fourth assessment report, stratospheric processes are only poorly represented. For example, climatological or simple specifications of time-varying ozone concentrations are imposed and the quasi-biennial oscillation (QBO) of equatorial stratospheric zonal wind is absent. Here we investigate the impact of an improved stratospheric representation using two sets of perturbed simulations with the Hadley Centre coupled ocean atmosphere model HadGEM1 with natural and anthropogenic forcings for the 1979–2003 period. In the first set of simulations, the usual zonal mean ozone climatology with superimposed trends is replaced with a time series of observed zonal mean ozone distributions that includes interannual variability associated with the solar cycle, QBO and volcanic eruptions. In addition to this, the second set of perturbed simulations includes a scheme in which the stratospheric zonal wind in the tropics is relaxed to appropriate zonal mean values obtained from the ERA-40 re-analysis, thus forcing a QBO. Both of these changes are applied strictly to the stratosphere only. The improved ozone field results in an improved simulation of the stepwise temperature transitions observed in the lower stratosphere in the aftermath of the two major recent volcanic eruptions. The contribution of the solar cycle signal in the ozone field to this improved representation of the stepwise cooling is discussed. The improved ozone field and also the QBO result in an improved simulation of observed trends, both globally and at tropical latitudes. The Eulerian upwelling in the lower stratosphere in the equatorial region is enhanced by the improved ozone field and is affected by the QBO relaxation, yet neither induces a significant change in the upwelling trend.