The place of schools in parents' community belonging

Abstract:  Schools are central community facilities in the daily lives of families with young children. The paper draws on survey and in-depth interview data to describe the role schools play in parents' sense of belonging to community. Māori and Pākehā parents indicated that schools and preschools were the most significant sites to their community belonging. They are a common meeting place, a source for community knowledge, and a point of departure for the development of parental friendship networks, and reciprocity in child care and support. Parents' perceptions of local schools in all socio-economic neighbourhoods influenced school choice and commitment to a neighbourhood. For Pacific and Asian parents schools were less significant as sites of community belonging.     

Arsenic Geochemistry of the Great Dismal Swamp,Virginia, USA: Possible Organic Matter Controls

Surface water samples for arsenic (As) concentration and speciation analysis were collected from organic matter-rich blackwaters of the Lake Drummond portion of the Great Dismal Swamp in southeastern Virginia, USA. Arsenic concentrations and speciation were determined by selective hydride generation, gas chromatography with photoionization detection. Surface waters from the Great Dismal Swamp are high in dissolved organic carbon (DOC) concentrations (445–9,600 μmol/kg) and of low pH (4.2–6.4). Total dissolved As concentrations [i.e., As(III) + As(V)], hereafter As_T, range from 2.2 nmol/kg to 21.4 nmol/kg. Arsenite, As(III), concentrations range from ∼1 nmol/kg to 17.7 nmol/kg, and As(V) ranges from ∼1 nmol/kg to 14.1 nmol/kg. Arsenate, As(V), is the predominant form of dissolved As in the inflow waters to the Great Dismal Swamp, whereas within the swamp proper arsenite, As(III), dominates. Arsenite accounts for 8–37% of As_T in inflow waters west of the Suffolk Scarp, and between 54% and 81% of As_T in Lake Drummond and Great Dismal Swamp waters east of the scarp. Arsenite is strongly correlated to DOC (r = 0.94) and inversely related to pH (r = −0.9), both at greater than the 99% confidence level. Arsenate is weakly related to pH and DOC (r = 0.4 and −0.37, respectively), and neither relationship is statistically significant. No statistical relationships exist between As(V) or As(III) and PO₄ concentrations. The predominance of As(III) and its strong correlation with DOC in Great Dismal Swamp waters suggest that DOC may inhibit As(III) adsorption or form stable aqueous complexes with As(III) in these waters. Alternatively, phytoplankton and/or bacterially mediated reduction of As(V) may be important processes in the organic-rich blackwaters and/or sediment porewaters of the swamp, leading to the prevalence of As(III) in the water column.     

Water and astrobiology

Water is formed from two of the three most abundant elements in the universe and so is abundant in interstellar space, in our Solar System, and on Earth, where it is an essential compound for the existence of life as we know it. Water ice acts as a substrate and reactant in interstellar clouds of gas and dust, enabling the formation of organic compounds that are important precursors to life and that eventually became incorporated into comets and asteroids in the early Solar System. Laboratory experiments have allowed us to infer the reaction pathways and mechanisms by which some of these compounds are formed. In these reactions, water can act as an energy transfer medium, increasing product yields, or it can lower yields by diluting reaction centers. Water can also destroy organic compounds when water ice decomposes under ionizing radiation and the decomposition products attack the compounds; whether this happens depends critically on temperature and structure of the ice, whether crystalline or amorphous. Ice structure and temperature also largely determine its gas content. As the solar nebula collapsed, icy mantles on interstellar grains probably sublimated and then recondensed onto other grains, thus influencing the transport of energy, mass, and angular momentum in the disk. Icy grains also influenced the temperature structure of the disk because they influence mean disk opacity. Outside the “snow line” at 3–5 AU icy grains accreted to become part of comets and planetesimals that occupy the region of the outer planets, the Kuiper belt, and the Oort cloud. Water was acquired by the growing Earth by several mechanisms. Evidence from noble gas isotopes indicates that Earth achieved sufficient mass fast enough to capture an early H-rich atmosphere from the Solar nebula itself. Although the remnant of this primary atmosphere is now found only in the mantle, it may also reside in the core, which could contain most of the H on Earth (or none at all). The bulk silicate Earth contains only 500–1100 ppm H₂O, an amount small enough to explain by “wet” accretion, although most of it probably accumulated with the latter half of Earth's mass from wetter planetary embryos originating beyond 1.5 AU. Degassing on impact delivered water to Earth's surface, where it dissolved into a magma ocean, a process that likely saved it from loss during subsequent catastrophic impacts such as the Moon-forming giant impact, which resulted in >99% loss of the noble gas inventory. Although most of Earth's water probably came from meteoritic material, the depletion on Earth of Xe relative to Kr strongly suggests a role for comets. The role of water in supporting life is an essential one on Earth and probably elsewhere, given the unusual properties of water compared with other potentially abundant compounds. Its dipolarity, high boiling point and heat of vaporization and, for ice, melting temperature; its expansion on freezing; and its solvent properties make it an ideal medium for life. Life originated early on Earth, indicating an abundance of water, nutrients, precursor molecules, substrates, and appropriate physical and chemical conditions. Life adapted quickly to (and may have originated in) extreme environments, of heat, cold, dryness, saltiness, and acidity. This adaptation to extreme conditions bodes well for the prospect of finding life elsewhere in our Solar System and in planetary systems around other stars.     

Improving fluorometry as a source tracking method to detect human fecal contamination

In a continuing effort to develop inexpensive source tracking methods to detect human fecal contamination in environmental waters, targeted sampling was combined with fluorometry. Targeted sampling works by identifying hot spots of fecal contamination through multiple samplings over ever-decreasing distances. Fluorometry identifies human fecal contamination by detecting optical brighteners, primarily from laundry detergents. Because organic matter fluoresces and interferes with fluorometry, two locations were chosen for sampling: waters relatively low in organic matter at Mayagüez Bay, Puerto Rico, and waters relatively high in organic matter at St. Simons Island, Georgia. In Puerto Rico, targeted sampling and fluorometry quickly and easily identified two hot spots of human fecal contamination in the Yagüez River, which flows through the city of Mayagüez. Another source tracking method, detection of theesp gene, confirmed their human origin. On St. Simous Island, targeted sampling and fiuorometry identified two hot spots of potential human fecal contamination. Detection of theesp gene confirmed the human origin of one site but not the other, most likely because background organic matter fluorescence interfered with fhiorometry. A separate experiment showed that adding a 436-um emission filter to the fluorometer reduced this background fluorescence by > 50%. With the 436-nm Filter in place, another sampling was conducted on St. Simons Island, and the second hot spot was identified as fecal contamination from birds. As long as the fluorometer was equipped with a 436-nm filter and organic matter concentrations were considered, targeted sampling combined with fluorometry was a relatively inexpensive method for identifying human fecal contamination in water.     

Mangrove conversion and aquaculture development in Vietnam: A remote sensing-based approach for evaluating the Ramsar Convention on Wetlands

Remote sensing data have been proposed as a potential tool for monitoring environmental treaties. However, to date, satellite images have been used primarily for visualization, but not for systematic monitoring of treaty compliance. In this paper, we present a methodology to operationalize the use of satellite imagery to assess the impact of the Ramsar Convention on Wetlands. The approach uses time series analysis of landscape pattern metrics to assess land cover conditions before and after designation of Ramsar status to monitor compliance with the Convention. We apply the methodology to two case studies in Vietnam and evaluate the success of Ramsar using four metrics: (1) total mangrove extent; (2) mangrove fragmentation; (3) mangrove density; and (4) aquaculture extent. Results indicate that the Ramsar Convention did not slow the development of aquaculture in the region, but total mangrove extent has remained relatively constant, primarily due to replanting efforts. Yet despite these restoration efforts, the mangroves have become fragmented and survival rates for replanting efforts are low. The methodology is cost effective and especially useful to evaluate Ramsar sites that rely mainly on self-reporting methods and where third parties are not actively involved in the monitoring process. Finally, the case study presented in this paper demonstrates that with the appropriate satellite record, in situ measurements and field observations, remote sensing is a promising technology that can help monitor compliance with international environmental agreements.     

Temporal variations of colloidal carrier phases and associated trace elements in a boreal river

Elemental size distributions, from truly dissolved through colloidal to particulate, have been studied in a subarctic boreal river. The measurements, carried out during 2002, ranged from winter to summer conditions, including an intense spring flood event. Results are reported for a total of 42 elements. Size distributions were characterised using a combination of cross-flow (ultra)filtration (CFF), flow field-flow fractionation (FlFFF), and diffusive gradients in thin-films (DGT). The three techniques showed similar trends, but quantitative comparisons reveal some important differences that warrant further investigation.Previous work has identified two colloidal carrier phases in fresh waters, dominated by iron and carbon, respectively. The majority of the elements studied are associated with one or both of these colloidal carrier phases. The exceptions are the alkali metals and several anions that are only very weakly associated with colloidal material, and which therefore occur mainly as truly dissolved material (<1 kDa in molecular weight). We discuss the likely origin for the two colloidal carrier phases and consider how associated trace elements fit into the geochemical framework. The relative affinities of the elements for iron and carbon colloidal carrier phases are related to their chemistries, and are compared with earlier data from the Delsjö Creek in southern Sweden.Elemental colloidal concentrations show strong seasonal variations related to changes in the colloidal carrier phase(s) with which they associate. In particular, many elements show a strong spring maximum in colloidal concentrations associated with the strong maximum in colloidal carbon concentration during the spring flood.     

Heat as a tracer to estimate dissolved organic carbon flux from a restored wetland

Heat was used as a natural tracer to characterize shallow ground water flow beneath a complex wetland system. Hydrogeologic data were combined with measured vertical temperature profiles to constrain a series of two-dimensional, transient simulations of ground water flow and heat transport using the model code SUTRA (Voss 1990). The measured seasonal temperature signal reached depths of 2.7 m beneath the pond. Hydraulic conductivity was varied in each of the layers in the model in a systematic manual calibration of the two-dimensional model to obtain the best fit to the measured temperature and hydraulic head. Results of a series of representative best-fit simulations represent a range in hydraulic conductivity values that had the best agreement between simulated and observed temperatures and that resulted in simulated pond seepage values within 1 order of magnitude of pond seepage estimated from the water budget. Resulting estimates of ground water discharge to an adjacent agricultural drainage ditch were used to estimate potential dissolved organic carbon (DOC) loads resulting from the restored wetland. Estimated DOC loads ranged from 45 to 1340 g C/(m2 year), which is higher than estimated DOC loads from surface water. In spite of the complexity in characterizing ground water flow in peat soils, using heat as a tracer provided a constrained estimate of subsurface flow from the pond to the agricultural drainage ditch.     

Timescales of melt generation and the thermal evolution of the Himalayan metamorphic core,Everest region,eastern Nepal

In the Everest region of the Nepalese Himalaya, ⁴⁰Ar/³⁹Ar and U-Pb geochronology provide evidence for a complex thermal history marked by multiple episodes of granite intrusion. The oldest mobilized melt formed syn-deformational granitic sills that have U-Pb crystallization ages of 21.33±0.03 and 21.80±0.05 Ma. Preserved in these same granites is a record of earlier magmatic crystallization of xenotime, zircon and monazite between ca. 26 Ma and ca. 23 Ma. This pattern of accessory phase crystallization is interpreted to reflect incremental melting and crystallization in the source region of the sills before ultimate melt migration, and provides the earliest evidence for anatexis in the Everest region. The beginning of crustal melting in the Everest region predates the earliest known movement on both the Main Central Thrust and the South Tibetan fault systems, but is temporally associated with the implied pressure decrease between Eohimalayan and Neohimalayan metamorphism.     

The role of organochlorines in cancer-associated mortality in California sea lions (Zalophus californianus)

Wild California sea lions (Zalophus californianus) have an unusually high prevalence of neoplasms (18% of stranded dead adults) and high levels of contaminants. The contribution of organochlorine (OC) tissue burdens to the probability of sea lions dying from carcinoma was explored using a logistic regression model. Levels of PCBs and DDTs were determined in blubber of sea lions diagnosed with metastatic carcinoma and animals that had died from non-carcinoma-related incidents (e.g., gunshot, domoic acid poisoning). Animals with carcinoma had higher mean concentrations (based on wet weight) of PCBs and DDTs (more than 85% and 30% higher, respectively) in blubber than did sea lions without carcinoma; the highest concentrations of OCs in the sea lions affected with carcinoma were measured in the males. Blubber thickness was significantly different between the two groups of sea lions, but after controlling for this difference, there was still a significant effect of PCBs, but not DDTs, on the probability of sea lions dying with carcinoma. Age, sex, mass and length did not affect the probability of dying from carcinoma.     

Mining,Environmental, Petroleum,and Engineering Industry Applications of Electromagnetic Techniques in Geophysics

Electromagnetic (EM) techniques are extremely important as a direct detection geophysical tool utilized in the base metal industry. They were developed in countries such as Canada, whose thin conductive weathering overburden did not hamper the penetration of EM signals and enabled exploration to depths on the order of 300 m. As a result, EM techniques were used widely in North America and Scandinavia for many years before they became common in countries with a thick conductive overburden, such as Australia. The 1980s and 1990s have seen the use of EM methods move from anomaly finding to mapping, as well as the development of better, faster and more accurate computer modelling algorithms. A review of EM papers, for the years 1998 to 2002, showed that most dealt with EM techniques as mapping tools. Airborne, ground and marine EM techniques are still being developed, as are data processing and interpretation software. The advent of robust 2-D and 3-D computer modelling and inversion algorithms has led to the acceptance of EM methods as a mapping tool for many environmental and petroleum industry applications, a trend which is expected to increase.