A high-resolution infrared spectral survey of Comet C/1999 H1 Lee

We obtained high-resolution (λ/Δλ∼25,000) spectra of Comet C/1999 H1 (Lee) on UT 1999 August 19.6 and 21.6 using the cross-dispersed Near InfraRed SPECtrometer (NIRSPEC) at the Keck Observatory atop Mauna Kea, HI. Here we present spectra of Comet Lee between 2.874 and 3.701 μm (3479-2702 cm⁻¹) representing the most complete high-resolution infrared survey of a comet to date in this wavelength region. Using published line lists and laboratory spectra we have identified 444 of the 545 distinct emission features present in these spectra. We have tabulated the rest frequencies, assignments, relative intensities, and signal-to-noise ratios of all detected emissions. In addition to gaining insights into the chemistry of Comet Lee, this survey provides a valuable tool for planning future high-resolution infrared observations of comets and other astronomical targets, and for retrospective comparison to existing high-resolution infrared datasets.     

Response of surface water chemistry to reduced levels of acid precipitation: comparison of trends in two regions of New York,USA

In light of recent reductions in sulphur (S) and nitrogen (N) emissions mandated by Title IV of the Clean Air Act Amendments of 1990, temporal trends and trend coherence in precipitation (1984–2001 and 1992–2001) and surface water chemistry (1992–2001) were determined in two of the most acid‐sensitive regions of North America, i.e. the Catskill and Adirondack Mountains of New York. Precipitation chemistry data from six sites located near these regions showed decreasing sulphate (SO₄^2?), nitrate (NO₃^?), and base cation (C_B) concentrations and increasing pH during 1984–2001, but few significant trends during 1992–2001. Data from five Catskill streams and 12 Adirondack lakes showed decreasing trends in SO₄^2? concentrations at all sites, and decreasing trends in NO₃^?, C_B, and H⁺ concentrations and increasing trends in dissolved organic carbon at most sites. In contrast, acid‐neutralizing capacity (ANC) increased significantly at only about half the Adirondack lakes and in one of the Catskill streams. Flow correction prior to trend analysis did not change any trend directions and had little effect on SO₄^2? trends, but it caused several significant non‐flow‐corrected trends in NO₃^? and ANC to become non‐significant, suggesting that trend results for flow‐sensitive constituents are affected by flow‐related climate variation. SO₄^2? concentrations showed high temporal coherence in precipitation, surface waters, and in precipitation–surface water comparisons, reflecting a strong link between S emissions, precipitation SO₄^2? concentrations, and the processes that affect S cycling within these regions. NO₃^? and H⁺ concentrations and ANC generally showed weak coherence, especially in surface waters and in precipitation–surface water comparisons, indicating that variation in local‐scale processes driven by factors such as climate are affecting trends in acid–base chemistry in these two regions. Copyright © 2005 John Wiley & Sons, Ltd.     

Ekman layer damping of r modes revisited

We investigate the damping of neutron star r modes due to the presence of a viscous boundary (Ekman) layer at the interface between the crust and the core. Our study is motivated by the possibility that the gravitational wave driven instability of the inertial r modes may become active in rapidly spinning neutron stars, for example, in low-mass X-ray binaries, and the fact that a viscous Ekman layer at the core–crust interface provides an efficient damping mechanism for these oscillations. We review various approaches to the problem and carry out an analytic calculation of the effects due to the Ekman layer for a rigid crust. Our analytic estimates support previous numerical results, and provide further insight into the intricacies of the problem. We add to previous work by discussing the effect that compressibility and composition stratification have on the boundary-layer damping. We show that, while stratification is unimportant for the r-mode problem, composition suppresses the damping rate by about a factor of 2 (depending on the detailed equation of state).     

Tectonic setting of post-orogenic granites within SW Fennoscandia based on deep seismic and gravity data

Within the Svecononvegian Province of SW Scandinavia granite intrusions are abundant. Prominent ones are the Bohus-Iddefjord and the Flå granites, the so- called Bohus-Flå Granite belt. The age of these granites, consistent at ≅ 900 Ma, coincides with the late extensional stage of the Svecononvegian-Grenvillian orogen. Gravity observations and deep seismic profiling lines are presented that also cover the Skagerrak Sea. The geophysical data suggest that the Bohus granite continues seaward for at least 80 km and its thickness, offshore, is estimated to be 2–4 km. Where the seismic profiling lines intersect the inferred seaward extension of the Bohus granite, a distinct reflection pattern is observed at ≅ 1.6 s. TWT. This coincides with a gravity modelled thickness of ≅ 4 km. The seismic profiles also show a large Moho offset beneath the modelled granite. It is proposed that this offset is related to Svecononvegian crustal underthrusting and that the granite melt could have formed by anatexis of mid-crustal rocks downthrusted to greater depths in the vicinity of the seismically observed Moho offset.     

The inverse problem for pulsating neutron stars: a 'fingerprint analysis' for the supranuclear equation of state

We study the problem of detecting, and inferring astrophysical information from, gravitational waves from a pulsating neutron star. We show that the fluid f and p modes, as well as the gravitational-wave w modes, may be detectable from sources in our own Galaxy, and investigate how accurately the frequencies and damping rates of these modes can be inferred from a noisy gravitational-wave data stream. Based on the conclusions of this discussion we propose a strategy for revealing the supranuclear equation of state using the neutron star fingerprints: the observed frequencies of an f and a p mode. We also discuss how well the source can be located in the sky using observations with several detectors.     

A geochemical record of the mining history of the Erme Estuary, south Devon, UK

The concentration of selected trace metals (Cu, Pb and Zn) in salt-marsh sediments from within the Erme Estuary have been measured in order to assess possible historical sources of pollution. The Erme Estuary, south Devon, UK is an Area of Outstanding Natural Beauty and has remained largely unaffected by industrialisation, although a number of small silver–lead mines were in operation in the 1800s. Five cores reveal comparable geochemical profiles. An increase of lead at 40 cm depth is observed, reaching maximum values of 427 ppm. Less distinct trends are revealed by zinc and copper, probably reflecting the lack of widespread mining for ores of these elements within the catchment and possible post-depositional mobility rendering the metal concentrations non-contemporaneous with the chemostratigraphy of lead. The geochemical analysis of the salt-marsh sediments provides a fairly robust chemostratigraphic scheme and the likely sources of mine waste can be pinpointed within the catchment. Based upon reference to the historical mining record of these mines chemostratigraphic dating of the sediments can be achieved in order to provide an estimate of salt-marsh accretion rates and sea-level rise.     

An analysis of carrier phase differential kinematic GPS positioning using DynaPos

A series of activities have been carried out at the University of New Brunswick in an effort to evaluate advances in long-range marine kinematic differential positioning. These activities involved processing and analysis of GPS carrier phase kinematic data sets. Some of the data was collected by UNB and some was provided by The XYZs of GPS Inc. Data were collected using Trimble 5700 and Ashtech Z-12 receivers. The data sets were processed using the software DynaPos provided by the The XYZs of GPS Inc. The best results obtained in our analysis indicate an agreement of 5 cm RMS for the horizontal component and 12 cm RMS for the vertical component between two ionospheric-delay free solutions, in baselines varying from 40 to 100 km.     

The positions of H+, Li+ and Na+ impurities in beryl

Electron Paramagnetic Resonance (EPR) measurements show that Li⁺ impurities are located at two different positions in beryl, one in the crystal lattice and the other in the crystal channel. The position of the Li⁺ impurity in the lattice is generally assumed to be at the site of a missing Be²⁺ ion. It is shown that this is not the case, but that the Li⁺ ion is located in a tetrahedron formed by the oxygens of one side of the Be tetrahedron and the nearest oxygen in the channel ring. This Li site has the coordinates (0.423, 0.344, 0.167) and can only be occupied when the neighbouring Be site is empty. There are four such sites around every Be tetrahedron at the distance of 1.46 Å from the Be site. The distance from the Li site to the oxygens of the Li tetrahedron is 1.84 Å. This compares favourably with the much smaller distance of 1.65 Å in the Be tetrahedron. Protons in beryl are trapped at or near these Li sites. Na⁺ is known to be located at the 2b position at the center of the silicate rings, where it is stabilized by one water molecule located at each of the two surrounding 2a sites. This is also the position of Li⁺ in the beryl channel. It is found that the presence of Na⁺ in the ring of six oxygens reduces the radius of this ring. The Na⁺ impurity has also been supposed to be located at position 2a alone and at 2b stabilized by only one water molecule. It is now proposed that Na⁺ and H₂O are located together in the Al–Be plane when only one water molecule is associated with Na⁺. The water oxygen is located at or near 2a and Na is closer to the Be site in tetrahedral beryl and closer to the Al site in octahedral beryl. It is proposed that the water protons are also located in the Al–Be plane, which would mean that there exists a third type of water in beryl. The origin of protons and OH^? ions in beryl is discussed and it is suggested that the plugs in the beryl channels are CO ₃ ^2? ions. Diffusion of OH^? ions and natural radiation may have led to the creation of NO₃ and the blue colour of Maxixe beryl.     

Mass composition of the escaping plasma at Mars

Data from the Ion Mass Analyzer (IMA) sensor of the ASPERA-3 instrument suite on Mars Express have been analyzed to determine the mass composition of the escaping ion species at Mars. We have examined 77 different ion-beam events and we present the results in terms of flux ratios between the following ion species: CO⁺₂/O⁺ and O⁺₂/O⁺. The following ratios averaged over all events and energies were identified: CO⁺₂/O⁺ = 0.2 and O⁺₂/O⁺ = 0.9. The values measured are significantly higher, by a factor of 10 for O⁺₂/O⁺, than a contemporary modeled ratio for the maximum fluxes which the martian ionosphere can supply. The most abundant ion species was found to be O⁺, followed by O⁺₂ and CO⁺₂. We estimate the loss of CO⁺₂ to be by using the previous measurements of Phobos-2 in our calculations. The dependence of the ion ratios in relation to their energy ranges we studied, 0.3-3.0 keV, indicated that no clear correlation was found.