The emergence of a Galápagos shield volcano, Roca Redonda

Roca Redonda volcano is a mostly submarine shield volcano that rises nearly 3 km from the adjacent seafloor. Over twenty lava flows and palagonite tuff are exposed in a 60 meter high oblong outcrop above sea level, and several other flows are exposed in the shallow water surrounding the islet. Thick, slightly alkaline picritic flows form the base of the section. Thinner picrites interbedded with sparsely porphyritic alkali-olivine basaltic pahoehoe toes characterize the upper section. The subaerial section probably records the filling of a palagonite tuff cone with younger lavas. Numerous fumaroles that may have a magmatic component are present in the shallow (<30 m) submarine zone and indicate that the volcano is probably still active. Three lava types are exposed: the basal picrites with 19% > MgO > 14%, high-Mg basalts with MgO of about 9%, and low-Mg basalts with MgO of about 6%. The Sr and Nd isotopic ratios of the three lava types are within analytical uncertainty. Olivine compositions indicate that the picrites are basaltic liquids that have accumulated olivine whose composition is in equilibrium with the host basaltic liquid. Apparently, basaltic magmas percolated through dunite and troctolite that had crystallized from slightly older Roca Redonda basaltic magma. Lavas from Roca Redonda have enriched trace element contents and isotopic ratios relative to nearby Wolf volcano, but they are quite similar to lavas from Cerro Azul and Ecuador volcanoes. The common characteristic of these volcanoes is that they lie on the periphery of the archipelago and are in a stage of subaerial growth. This suggests that Galápagos volcanoes may go through a juvenile alkaline stage before a mature tholeiitic stage, analogous to the Loihi stage of Hawaiian volcanism. A low ³He/⁴He ratio in olivine from one of the picrites indicates a small contribution by the Galápagos mantle plume. Received: 15 December 1997 / Accepted: 6 May 1998     

Origin of crystalline,cold desert salts in the McMurdo region,Antarctica

The distribution of crystalline salt minerals in deposits in the McMurdo region of Antarctica has been examined to study the origin of these salts. Sulphate, chloride, sodium and calcium salts are most frequently encountered. Salts containing chloride and sodium ions become less common away from the coast. Sulphate salts are more regularly distributed but tend to be related isotopically to sea water sulphate. Salts containing magnesium ion tend to exist mainly on substrates composed of basic igneous rocks, whereas calcium and carbonate salts are present on all rock types in the region.These distributions show that salts of marine origin are regionally and quantitatively most important but that chemical weathering of mafic materials in rocks and soils is also significant. However, biological, volcanic and hydrothermal processes are or have been active contributing to salts in local areas, that include penguin rookeries and eastern Taylor Valley, the summit area of Erebus Volcano, and subsurface rocks, respectively.     

Distribution surfaces in solvent extraction systems

In the solvent extraction of metals, the distribution of the metal is usually dependent on the concentrations of several different species in the two phases. Despite this fact, distribution isotherms are usually presented as plots of C_o as a function of C_aq and these are used for a McCabe-Thiele type evaluation of a number of stages and flow rates, etc., each individual isotherm being valid only for one set of initial conditions; this treatment limits the possibilities of optimizing the system. In the present paper an extension of three-dimensional plots is suggested with special reference to the Cu/LIX64N extraction system. The distribution surface is defined and the general properties of the plots are outlined.A procedure is outlined whereby the surface can be represented on a two dimensional plot and a theoretical model for the surface can be superimposed.The paper also shows how distribution ratios (D values) are related to the surface.     

Suspended‐sediment sources in an urban watershed,Northeast Branch Anacostia River,Maryland

Fine sediment sources were characterized by chemical composition in an urban watershed, the Northeast Branch Anacostia River, which drains to the Chesapeake Bay. Concentrations of 63 elements and two radionuclides were measured in possible land‐based sediment sources and suspended sediment collected from the water column at the watershed outlet during storm events. These tracer concentrations were used to determine the relative quantity of suspended sediment contributed by each source. Although this is an urbanized watershed, there was not a distinct urban signature that can be evaluated except for the contributions from road surfaces. We identified the sources of fine sediment by both physiographic province (Piedmont and Coastal Plain) and source locale (streambanks, upland and street residue) by using different sets of elemental tracers. The Piedmont contributed the majority of the fine sediment for seven of the eight measured storms. The streambanks contributed the greatest quantity of fine sediment when evaluated by source locale. Street residue contributed 13% of the total suspended sediment on average and was the source most concentrated in anthropogenically enriched elements. Combining results from the source locale and physiographic province analyses, most fine sediment in the Northeast Branch watershed is derived from streambanks that contain sediment eroded from the Piedmont physiographic province of the watershed. Sediment fingerprinting analyses are most useful when longer term evaluations of sediment erosion and storage are also available from streambank‐erosion measurements, sediment budget and other methods. Copyright © 2010 John Wiley & Sons, Ltd.     

Management of a marine protected area for sustainability and conflict resolution: Lessons from Loreto Bay National Park (Baja California Sur,Mexico)

The Loreto Bay National Park was established to protect the area's ecosystems from habitat destruction and overexploitation. However, the park has not met two of its primary goals: recovery of commercially valuable fish populations and their sustainable use by stakeholders. Based on evidence from the literature, dialogue with stakeholders, a literature review on using recreational fees for marine protected area (MPA) management, and an economic valuation survey, we provide practical guidelines for addressing factors hindering the park's success. These include: 1) the implementation of management based upon ecosystem science, and rigorous monitoring of park ecosystems, 2) increased communication among stake-holder groups, outreach and education, and 3) a re-organization of the park's administrative structure that would allow for more efficient use of funds. Our results also suggest that the park entrance fee could be raised to support these proposed improvements.     

EPR investigation of NO2 and CO2 − and other radicals in beryl

A number of different impurities are located in the open channels of natural beryl crystals. The rare Maxixe beryl contains an unusual amount of NO₂. The isoelectronic CO₂ ⁻ radical is found in the irradiated Maxixe-type beryl. The NO₂ radicals are distributed in the Be–Al plane of the crystal, with the nitrogen atom close to the oxygens of the beryl cavity wall. These oxygens repel the negative CO₂ ⁻ radical, which is located at the center of the beryl cavity and rotates around its O–O axis, which is parallel to the crystal c-axis. When there is a nearby alkali ion at the center of the beryl channel, it reorients the CO₂ ⁻ radical so that its bisector is parallel to the c-axis and points toward the positive ion. Different signals are analyzed for Li⁺, Na⁺, and another counter-ion, which probably is Cs⁺. The related NO₃ and CO₃ ⁻ radicals are the color centers in the investigated deep blue beryls. The slow decay of the color, which makes these beryls useless as gem stones, is related to the decay of the hydrogen atoms which are present in these crystals. Evidence is given that NO₃ is created in Maxixe beryl by a natural process, while CO₃ ⁻ in Maxixe-type beryl has been created by irradiation. The temperature dependence of the EPR signals of these two radicals was investigated, but a definitive proof that they rotate at the center of the beryl cavity could not be given. EPR signals from some other radicals in beryl have been observed and described.     

Nitrogen Uptake by Native and Invasive Temperate Coastal Macrophytes: Importance of Dissolved Organic Nitrogen

We investigated if the success of the invasive common reed Phragmites australis could be attributed to a competitive ability to use dissolved organic nitrogen (DON) when compared to the dominant macrophyte Spartina alterniflora in tidal wetlands. Short-term nutrient uptake experiments were performed in the laboratory on two genetic lineages of Phragmites (native and introduced to North America) and S. alterniflora. Our results provide the first evidence for direct assimilation of DON by temperate marsh plants and indicate that amino acids are assimilated intact by all plant types at similar rates. Both Phragmites lineages had significantly greater urea–N assimilation rates than S. alterniflora, and the affinity for dissolved inorganic nitrogen (DIN) species was the greatest in native Phragmites > introduced Phragmites > S. alterniflora. Field studies demonstrated uptake of both DON and DIN in similar proportion as those determined in the laboratory experiments. Based on these uptake rates, we estimate that DON has the potential to account for up to 47% of N demand for Phragmites plants, and up to 24% for S. alterniflora plants. Additionally, we suggest that differences in N uptake between native and introduced Phragmites lineages explain one mechanism for the success of the introduced type under increasingly eutrophic conditions.     

The water impacts of climate change mitigation measures

A variety of proposed activities to mitigate greenhouse gas emissions will impact on scarce water resources, which are coming under increasing pressure in many countries due to population growth and shifting weather patterns. However, the integrated analysis of water and carbon impacts has been given limited attention in greenhouse mitigation planning. In this Australian case study, we analyse a suite of 74 mitigation measures ranked as highest priority by one influential analysis, and we find that they have highly variable consequences for water quantity. We find: (1) The largest impacts result from land-based sequestration, which has the potential to intercept large quantities of water and reduce catchment yields, estimated to exceed 100 Mm³/MtCO₂-e of carbon mitigated (100,000 l per tonne CO₂-e). (2) Moderate impacts result from some renewable power options, including solar thermal power with a water cost estimated at nearly 4 Mm³/MtCO₂-e. However, the water impacts of solar thermal power facilities could be reduced by designing them to use existing power-related water supplies or to use air or salt-water cooling. (3) Wind power, biogas, solar photovoltaics, energy efficiency and operational improvements to existing power sources can reduce water demand through offsetting the water used to cool thermal power generation, with minor savings estimated at 2 Mm³/MtCO₂-e and amounting to nearly 100 Mm³ of water saved in Australia per annum in 2020. This integrated analysis significantly changes the attractiveness of some mitigation options, compared to the case where water impacts are not considered.