Zircon and whole-rock Zr/Hf ratios as markers of the evolution of granitic magmas: Examples from the Teplice caldera (Czech Republic/Germany)

Mineralogy and Petrology - Hafnium contents and Zr/Hf ratios were studied in zircons and their parent rocks from three magmatic suites associated with the Teplice caldera, Eastern Erzgebirge:...     

The Variscan belt: correlations and plate dynamics

International Journal of Earth Sciences -     

Correlation Analysis for Compositional Data

Compositional data need a special treatment prior to correlation analysis. In this paper we argue why standard transformations for compositional data are not suitable for computing correlations, and why the use of raw or log-transformed data is neither meaningful. As a solution, a procedure based on balances is outlined, leading to sensible correlation measures. The construction of the balances is demonstrated using a real data example from geochemistry. It is shown that the considered correlation measures are invariant with respect to the choice of the binary partitions forming the balances. Robust counterparts to the classical, non-robust correlation measures are introduced and applied. By using appropriate graphical representations, it is shown how the resulting correlation coefficients can be interpreted.     

Seasonal evolution of runoff generation on agricultural land in the Belgian loess belt and implications for muddy flood triggering

Muddy floods due to agricultural runoff are a widespread and frequent phenomenon in the European loess belt, and particularly in central Belgium. These floods are triggered when high quantities of runoff are generated on cropland and cause severe erosion. Three soil surface characteristics are relevant to determine the runoff potential of cultivated soils: soil cover by crops and residues, soil surface crusting and roughness. These characteristics have been observed on 65 cultivated fields throughout 2005. A heavy rainfall event representative for events triggering muddy floods in the region (60 mm h^?1 during 30 minutes) has been simulated using a 0·5 m² simulator on fields with the 17 most observed combinations of soil surface characteristics in central Belgium. Runoff is not observed in the case of (ploughed) bare uncrusted soils, nor in the case of soils covered by crops showing a transitional crust and a moderate roughness (1–2 cm). In the cases where runoff has been observed, mean runoff coefficients ranged from 13% (wheat in July) to 58% (sugar beet or maize in May and June). Grassed buffer strips (GBSs) and grassed waterways (GWWs) show a higher runoff coefficient (62% for GBSs and 73% for GWWs) than most cultivated soils (13–58%). Furthermore, it is demonstrated that small plot measurements can be used to estimate runoff generation at the field scale. A classification of runoff generation risk based on the surveys of soil surface characteristics has been applied to common crops of central Belgium. February as well as the period between May and September are the most critical for runoff at the field scale. However, it appears from monitoring of a 16 ha catchment that the highest runoff volumes and peak discharges are recorded between May and August after heavy rainfall, explaining why 85% of muddy floods are recorded during this period in central Belgium. Copyright © 2007 John Wiley & Sons, Ltd.     

Multiple Sources of Metals of Mineralization in Lower Cambrian Black Shales of South China: Evidence from Geochemical and Petrographic Study

Black shales of the Lower Cambrian Niutitang Formation in southern China (Huangjiawan mine, Zunyi region, northern part of the Guizhou Province) host regionally distributed stratiform polymetallic Ni‐Mo‐platinum group elements (PGE)‐Au phosphate‐ and sulfide‐rich ores. These are confined to a ≥0.2‐m thick ore horizon composed of mineralized bodies of algal onkolites, phosphate nodules, and sulfide and shale clasts in a mineralized phosphate‐ and organic matter‐rich matrix. Compared to footwall and hanging wall shales, the ore bed is strongly enriched in Ni (up to 100‐fold), As (up to 97‐fold), Mo (up to 95‐fold), Sb (up to 67‐fold), Rh (up to 49‐fold), Cu (up to 37‐fold), Pd (up to 33‐fold), Ru (up to 24‐fold), Zn (up to 23‐fold), Pt (up to 21‐fold), Ir (up to 15‐fold), Co (up to 14‐fold), and Pb (up to 13‐fold). Even footwall and hanging wall black shales are significantly enriched by Mo (21‐fold) and Ni (12‐fold) but depleted in Cr in comparison to average Cambrian black shale. Organic matter is represented by separate accumulations dispersed in the rock matrix or as biotic bitumen droplets and veinlets in ore clasts. Similar organic carbon (C_org) values in an ore bed and enclosing footwall and hanging wall shales of little mineralization indicate that metal accumulation was not controlled only by biogenic productivity and organic matter accumulation rate. Evaporitic conditions during sedimentation of the basal part of the Niutitang Formation were documented by an occurrence of preserved Ni‐, V‐, Cr‐, and Cu‐enriched phosphate‐rich hardground with halite and anhydrite pseudomorphs on the paleosurface of the underlying Neoproterozoic carbonates. Neoproterozoic black shales of the Doushantuo Formation are characterized by increased metal concentrations. Comparison of metal abundances in both hardground and Doushantuo black shales indicate that black shales could have become a source of metal‐rich hardground during weathering. The polymetallic Ni‐Mo‐PGE sulfide‐rich ore bed is interpreted to represent a remnant of shallow‐water hardground horizon rich in metals, which originated in a sediment‐starved, semi‐restricted, seawater environment. During the Early Cambrian transgression an influx of fresh seawater and intensive evaporation, together with the hydrothermal enrichment of seawater in a semi‐restricted basin, resulted in the formation of dense metalliferous brines; co‐precipitation of metals together with phosphates and sulfides occurred at or above the oxic–anoxic sediment interface. Metal‐enriched hardground was disintegrated by the action of waves or bottom currents and deposited in a deeper part of the anoxic basin. Contemporaneously with the formation of a polymetallic Ni‐Mo‐PGE‐Au sulfide ore bed, economic sedimentary exhalative (SEDEX)‐type barite deposits were forming in a stratigraphically and geotectonically similar setting. The results of geochemical study at the Shang Gongtang SEDEX‐type Ba deposit indicate that concentrations of Ag, As, Cr, Cu, Fe, Mn, Ni, Pb, Sb, V, Zn and other metals decrease from top of the barite body toward the hanging wall black shale. Lower Cambrian black shales of the Niutitang Formation above the barite body also display similar element abundances as Neoproterozoic black shales of the Doushantuo Formation, developed in the footwall of the barite body. But the geochemical composition of the sulfide layer is different from the Ni‐Mo ore bed, showing only elevated Pb, Cu, Ni and Mo values. It is suggested that hydrothermal brines at Shang Gongtang might have leached metals from footwall Neoproterozoic sequences and became, after mixing with normal seawater, an additional source of Ag, Cr, Cu, Pb, Sb, Zn, Ni, PGE, V and other metals.     

Rapid changes of the outer high-latitude ionosphere combined with a penetration of intensive ULF (Pcl) signals

Variable values of the Pcl signal transmissivity through the ionosphere, experimentally obtained from the conjugated ULF experiment GEOS-1-Husafell during a roughly 1-h interval of the micropulsation disturbance on 13 July 1977, have been compared with the results of numerical simulation. Variations of the basic physical parameters of the high-latitude outer ionosphere have been considered. Quantitative estimates of the rapid changes of the ionized particle concentration in connection with the considered changes of the ionospheric plasma temperature have been made. It is assumed that the ioncyclotron waves themselves propagating along the plasmapause give rise to the non-stationary conditions in the outer high-latitude ionosphere (Φ≈ 70°).     

Filtration of Pc1 wave packets in the ionosphere. Conjugated experiment GEOS-1 — husafell and results of numerical modelling

Summary The spectral analysis of an hourly section of a synchronized conjugated record of an ULF signal made on the GEOS-1 satellite and the Husafell Observatory (Iceland) on July 13, 1977, has been carried out. The time variations of the spectral frequency-amplitude characteristics of the Pc1 wave packet in the neighbourhood of f 0.5 s^–1 at both measurement sites were examined. The transmissibility of the amplitude of the total magnetic component of the wave through the ionosphere towards the Earth's surface, found in the frequency range of the packets, varies from 0.03 to 0.07. Moreover, its time behaviour with the development of the micropulsation disturbance was studied. The frequency shift of the packet spectrum centre towards higher frequencies 0.04 s^–1) was determined at the Earth's surface as compared with the satellite conditions. Experimental results served to test the developed automated methods of numerical modelling of ionospheric filtration in the ULF range of Pc1 micropulsations. Good agreement between the experimental and numerical results of the two constructed limiting models of the daytime ionosphere at higher latitudes (low and high solar activity) was achieved. The values of the transmissibility calculated for the Pc1 packet frequencies vary from 0.075 to 0.3 and from 0.025 to 0.06.     

Near-ultraviolet observation of four bright Mn stars

Near-ultraviolet spectra, obtained with the ESRO TD-1A/S59 experiment, of the four Mn stars β Tau, γ Crv, α And, and μ Lep and six normal stars are compared. The normal stars show good agreement with synthetic spectra. The Mn stars have spectra which become hotter at shorter wavelengths. They also show strong Mnii lines and weak Mgii lines. A time-variation for Tiii λ 2828 was noted in γ Crv and α And.