Paleozoic serpentinite-enclosed chromitites from Tehuitzingo (Acatlán Complex, southern Mexico): a petrological and mineralogical study

The serpentinites and associated chromitite bodies in Tehuitzingo (Acatlán Complex, southern Mexico) are in close relationship with eclogitic rocks enclosed within a metasedimentary sequence, suggesting that the serpentinites, chromitites and eclogitic rocks underwent a common metamorphic history.Primary chromites from the chromitite bodies at Tehuitzingo are of refractory-grade (Al-rich) and have a chemical composition similar to that expected to be found in an ophiolitic environment. The chromite grains in chromitites and serpentinites are systematically altered to ‘ferritchromite’. The alteration trend is usually characterized by a decrease in the Al, Mg and Cr contents coupled by an increase in Fe³⁺ and Fe²⁺.The Tehutizingo chromitites have low Platinum Group Elements (PGE) contents, ranging from 102 to 303 ppb. The chondrite-normalized PGE patterns are characterized by an enrichment in the Ir-subgroup elements (IPGE=Os, Ir, Ru) relative to the Pd-subgroup elements (PPGE=Rh, Pt, Pd). In addition, all chromitite samples display a negative slope from Ru to Pd [(Os+Ir+Ru)/(Pt+Pd)=4.78−14.13]. These patterns, coupled with absolute PGE abundances, are typical of ophiolitic chromitites elsewhere. Moreover, all the analyzed samples exhibit chondrite-normalized PGE patterns similar to those found for non-metamorphosed ophiolitic chromitites. Thus, the PGE distribution patterns found in the Tehuitzingo chromitites have not been significantly affected by any subsequent Paleozoic high-pressure (eclogite facies) metamorphic event.The chondrite-normalized PGE patterns of the enclosing serpentinites also indicate that the PGE distribution in the residual mantle peridotites exposed in Tehuitzingo was unaffected by high-pressure metamorphism, or subsequent hydrothermal alteration since the serpentinites show a similar pattern to that of partially serpentinized peridotites present in mantle sequences of non-metamorphosed ophiolites.Our main conclusion is that the chromitites and serpentinites from Tehuizingo experienced no significant redistribution (or concentration) of PGE during the serpentinization process or the high-pressure metamorphic path, or during subsequent alteration processes. If any PGE mobilization occurred, it was restricted to individual chromitite bodies without changing the bulk-rock PGE composition.Our data suggest that the Tehuitzingo serpentinites and associated chromitites are a fragment of oceanic lithosphere formed in an arc/back-arc environment, and represent an ophiolitic mantle sequence from a supra-subduction zone, the chemical composition of which remained essentially unchanged during the alteration and metamorphic events that affected the Acatlán Complex.     

Comparison of Sesimic Body Wave and Coda Wave Measures of Q

—Measurements of seismic attenuation (Q ^?1) can vary considerably when made from different parts of seismograms or using different techniques, particularly at high frequencies. These discrepancies may be methodological, or may reflect earth processes. To investigate this problem, we compare body wave with coda Q ^?1 results utilizing three common techniques i) parametric fit to spectral decay, ii) coda normalization of S waves, and iii) coda amplitude decay with lapse time. Q ^?1 is measured from both body and coda waves beneath two mountain ranges and one platform, from recordings made at seismic arrays in the Caucasus and Kopet Dagh over paths ≤ 4° long. If Q is assumed frequency independent, spectral decay fits show Q _s and Q _coda near 700–800 for both mountain paths and near 2100–2200 for platform paths. Similar values are determined with the coda normalization technique. However, frequency-dependent parameterizations fit the data significantly better, with Q _s ?(1 Hz) and Q _coda?(1 Hz) near 200–300 for mountain paths and near 500–600 for platform paths. Lapse decay measurements are close to the frequency-dependent values, showing that both spectral and lapse decay methods can give similar results when Q has comparable parameterizations. Above 6 Hz, coda measurements suggest some enrichment relative to body waves, perhaps due to scattering, but intrinsic absorption appears to dominate at lower frequencies. All approaches show sharp path differences between the Eurasian platform and adjacent mountains, and all are capable of resolving spatial variations in Q.     

Optical spectra of four objects identified with variable radio sources

We obtained optical spectra of four objects identified with variable radio sources. Three objects (0029+0554, 0400+0550, 2245+0500) were found to be quasars with redshifts of 1.314, 0.761, and 1.091. One object (2349+0534) has a continuum spectrum characteristic of BL Lac objects. We analyze spectra of the radio sources in the range 0.97–21.7 GHz for the epoch 1997 and in the range 3.9–11.1 GHz for the epoch 1990, as well as the pattern of variability of their flux densities on time scales of 1.5 and 7 years.     

Electrons in feldspar II: a consideration of the influence of conduction band-tail states on luminescence processes

 Most natural feldspars contain many charged impurities, and display a range of bond angles, distributed about the ideal. These effects can lead to complications in the structure of the conduction band, giving rise to a tail of energy states (below the high-mobility conduction band) through which electrons can travel, but with reduced mobility: transport through these states is expected to be thermally activated. The purpose of this article is twofold. Firstly, we consider what kind of lattice perturbations could give rise to both localized and extended conduction band-tail states. Secondly, we consider what influence the band tails have on the luminescence properties of feldspar, where electrons travel through the sample prior to recombination. The work highlights the dominant role that 0.04–0.05-eV phonons play in both the luminescence excitation and emission processes of these materials. It also has relevance in the dating of feldspar sediments at elevated temperatures. Received: 11 May 2001 / Accepted: 6 September 2001     

Calculating surface water PCO2 from foraminiferal organic δC

The δ¹³C of organic matter bound within the crystal lattice of foraminiferal calcite tests may provide a potential tracer of the isotopic composition of the surface water primary photosynthate. Using δ¹³C of the organic matter extracted from the crystal lattice and the calcite test, it is theoretically possible to estimate the paleo-surface water pCO₂. We have tailored this technique initially for the subpolar planktonic foraminifera species Globigerina bulloides. Initial surface water pCO₂ estimates from deep-sea core BOFS 5K (50°41.3′N, 21°51.9′W, water depth 3547 m) indicate that the northeast Atlantic Ocean may have been a greater sink for CO₂ during the last glacial than during the Holocene. Greatly reduced benthic foraminifera abundances, especially phytodetritus feeders, in BOFS 5K during the last glacial indicates low surface productivity. This rules out a productivity-driven CO₂ sink. The enhanced glacial CO₂ sink must, therefore, have results from a southwards shift of the centre of deep water formation.     

Study of terrestrial carbon flux by eddy covariance method in revegetated manganese mine spoil dump at Gumgaon,India

The micrometeorological technique of eddy covariance is a powerful tool for characterizing the carbon (C) budget of terrestrial ecosystems. Eddy covariance method was used for estimating Net Ecosystem Exchange (NEE) of carbon dioxide between atmosphere and revegetated manganese mine spoil dump at Gumgaon, India. In this paper, we analyzed the diel CO₂ flux pattern and its response to various physical environmental conditions. The carbon balance of terrestrial ecosystems is particularly sensitive to climatic changes. Study of diel pattern of CO₂ flux showed that carbon uptake was dependent on sunlight. Effect of temperature and latent heat on the CO₂ flux showed that rate of CO₂ uptake increased proportionally, but later declined due to various factors like stomatal response, high evaporative demand, circadian rhythm and/or a combination of all three. Net ecosystem production of revegetated land was found to be 28.196 KgC/ha/day whereas average net carbon release by the ecosystem, through respiration was observed to be 5.433 KgC/ha/day. Thus, quantifying net carbon (C) storage in degraded land is a necessary step in the validation of carbon sequestration estimates and in assessing the possible role of these ecosystems in offsetting adverse impacts of fossil fuel emissions.     

Sensitivity analysis of runoff hydrographs due to temporal rainfall patterns in Makkah Al-Mukkramah region,Saudi Arabia

Runoff peak and volume in flood studies are estimated relying on temporal rainfall distribution from various storm patterns. Usually, SCS distributions types (I, II, III, IA) are commonly used. Using these distributions in runoff calculations assume that the in situ temporal rainfall pattern typically behaves as the one described by the SCS-type distribution, which is due to cyclonic frontal storms and actually developed in temperate environment. To what extent such assumption is valid in the arid environment? How much the impacts of rainfall temporal patterns are reflected in runoff volumes and peaks? The aim objectives of the current study are to answer the above two questions and clarify the validity of aforementioned assumption and exemplify such effect. Real rainfall data collected from rain gauges of Makkah Al-Mukkramah region over a period of more than 20 years are utilized. Temporal rainfall patterns and their parameters are deduced. Many hydrological simulations are performed and comparisons, in terms of runoff volume and peak flows, are made to show the effects of the common rainfall storm patterns and the developed rainfall storm patterns in the region based on the current study. Results indicate that major bursts of the design rainfall storm pattern are located in the first time of the storm period in the two quartiles which is mainly due to convective rainfall type in thunderstorms unlike the commonly used by SCS types relying on frontal cyclonic storms. Makkah Al-Mukkramah temporal rainfall pattern does not behave as the “typical pattern” assumed by SCS distributions that are deduced from different environments. The impacts of the temporal pattern reflected as an overestimate in the runoff peak reached to 68 %. The developed hyetographs and tables presented in the current study are recommended to enhance economical and rational design practice in watersheds of Makkah Al-Mukkramah region.     

Fluid-induced seismicity: Pressure diffusion and hydraulic fracturing

Borehole fluid injections are common for the development of hydrocarbon and geothermic reservoirs. Often they induce numerous microearthquakes. Spatio-temporal dynamics of such induced microseismic clouds can be used to characterize reservoirs. However, a fluid-induced seismicity can be caused by a wide range of processes. Here we show that linear pore pressure relaxation and a hydraulic fracturing are two asymptotic end members of a set of non-linear diffusional phenomena responsible for seismicity triggering. To account for the whole range of processes we propose a rather general non-linear diffusional equation describing the pore pressure evolution. This equation takes into account a possibly strong enhancement of the medium permeability. Both linear pore pressure relaxation and hydraulic fracturing can be obtained as special limiting cases of this equation. From this equation we derive the triggering front of fluid induced seismicity, which is valid in the general case of non-linear pore pressure diffusion. We demonstrate corresponding seismicity signatures on different case studies.     

ELASTIC WAVE PROPAGATION IN TRANSVERSELY ISOTROPIC MEDIA USING FINITE DIFFERENCES1

When treating the forward full waveform case, a fast and accurate algorithm for modelling seismic wave propagation in anisotropic inhomogeneous media is of considerable value in current exploration seismology. Synthetic seismograms were computed for P-SV wave propagation in transversely isotropic media. Among the various techniques available for seismic modelling, the finite-difference method possesses both the power and flexibility to model wave propagation accurately in anisotropic inhomogeneous media bounded by irregular interfaces. We have developed a fast high-order vectorized finite-difference algorithm adapted for the vector supercomputer. The algorithm is based on the fourth-order accurate MacCormack-type splitting scheme. Solving the equivalent first-order hyperbolic system of equations, instead of the second-order wave equation, avoids computation of the spatial derivatives of the medium's anisotropic elastic parameters. Examples indicate that anisotropy plays an important role in modelling the kinematic and the dynamic properties of the wave propagation and should be taken into account when necessary.