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81.
Abigail E. Noble Mak A. Saito Kanchan Maiti Claudia R. Benitez-Nelson 《Deep Sea Research Part II: Topical Studies in Oceanography》2008,55(10-13):1473
The vertical distributions of cobalt, iron, and manganese in the water column were studied during the E-Flux Program (E-Flux II and III), which focused on the biogeochemistry of cold-core cyclonic eddies that form in the lee of the Hawaiian Islands. During E-Flux II (January 2005) and E-Flux III (March 2005), 17 stations were sampled for cobalt (n=147), all of which demonstrated nutrient-like depletion in surface waters. During E-Flux III, two depth profiles collected from within a mesoscale cold-core eddy, Cyclone Opal, revealed small distinct maxima in cobalt at 100 m depth and a larger inventory of cobalt within the eddy. We hypothesize that this was due to a cobalt concentrating effect within the eddy, where upwelled cobalt was subsequently associated with sinking particulate organic carbon (POC) via biological activity and was released at a depth coincident with nearly complete POC remineralization [Benitez-Nelson, C., Bidigare, R.R., Dickey, T.D., Landry, M.R., Leonard, C.L., Brown, S.L., Nencioli, F., Rii, Y.M., Maiti, K., Becker, J.W., Bibby, T.S., Black, W., Cai, W.J., Carlson, C.A., Chen, F., Kuwahara, V.S., Mahaffey, C., McAndrew, P.M., Quay, P.D., Rappe, M.S., Selph, K.E., Simmons, M.P., Yang, E.J., 2007. Mesoscale eddies drive increased silica export in the subtropical Pacific Ocean. Science 316, 1017–1020]. There is also evidence for the formation of a correlation between cobalt and soluble reactive phosphorus during E-Flux III relative to the E-Flux II cruise that we suggest is due to increased productivity, implying a minimum threshold of primary production below which cobalt–phosphate coupling does not occur. Dissolved iron was measured in E-Flux II and found in somewhat elevated concentrations (0.5 nM) in surface waters relative to the iron depleted waters of the surrounding Pacific [Fitzwater, S.E., Coale, K.H., Gordon, M.R., Johnson, K.S., Ondrusek, M.E., 1996. Iron deficiency and phytoplankton growth in the equatorial Pacific. Deep-Sea Research II 43 (4–6), 995–1015], possibly due to island effects associated with the iron-rich volcanic soil from the Hawaiian Islands and/or anthropogenic inputs. Distinct depth maxima in total dissolved cobalt were observed at 400–600 m depth, suggestive of the release of metals from the shelf area of comparable depth that surrounds these islands. 相似文献
82.
A wild and a cultured greenshell mussel (Perna canaliculus) population were compared for biochemical genetic variation at seven polymorphic and four monomorphic allozyme loci. Significant heterozygote deficiencies were observed for all polymorphic loci (La—1, La—2, Lap, Lgg—1, Lgg— 2, Pgi, and Pgm) for both populations (except the Pgi locus of the wild mussel population). Genotypic disequilibrium was calculated for both populations: genotypic frequencies were significantly non‐random at three pairs of loci among the wild mussels, and significantly non‐random at three different pairs of loci among the cultured mussels. All six pairs of loci which exhibited significant genotypic disequilibrium involved amino‐peptidases, suggesting that these loci form a linkage group, and that neither the Pgi nor the Pgm loci are associated with this group. Exact tests for population differentiation based upon population‐specific allele distributions indicated that four of the polymorphic loci were significantly heterogeneous among the two populations, whereas the remaining three polymorphic loci were not. Based upon the private allele system, the number of migrants (N m) between the populations was estimated to be 2.009, which, according to the private allele system, represents a high level of gene flow. These findings are discussed with regard to the population biology and genetic structure of this species. 相似文献
83.
Depositional environment of mudflats and mangroves and bioavailability of selected metals within mudflats in a tropical estuary 总被引:1,自引:1,他引:0
M. C. Fernandes G. N. Nayak A. Pande S. P. Volvoikar D. R. G. Dessai 《Environmental Earth Sciences》2014,72(6):1861-1875
Four sediment cores representing adjacent mudflat and mangrove sub-environments of middle estuary (Shastri) were analyzed for sand, silt, clay, and organic carbon. Total metal concentration of iron (Fe), manganese (Mn), nickel (Ni), zinc (Zn), chromium (Cr), copper (Cu), cobalt (Co), and lead (Pb) and chemical speciation of Fe, Mn, and Co on selected samples was also carried out on mudflat cores. The sediments in the upper middle estuary were found to be deposited under highly varying hydrodynamic energy conditions; whereas lower middle estuary experienced relatively stable hydrodynamic energy conditions with time. The tributary joining the river near the upper middle estuary is found to be responsible for the addition of enhanced organic carbon and metal concentrations. Speciation study indicated Fe and Co are from natural lithogenic origin while Mn is derived from anthropogenic sources. Higher Mn and Co than apparent effects threshold can pose a high risk of toxicity to organisms associated with these sediments. 相似文献
84.
85.
The paper deals with massive fluid spheres with an isothermal core (having finite central density) and a polytropic envelope in terms of the General Relativity. The matching of the solutions in the core and envelope has been done using Bondi's condition,H=0 and also without it. The study reveals that since this condition does not correspond to any particular physical situation the maximum values of fractional core size, fractional core mass and the redshift do not occur atH=0, but that they occur at some other point. Within the permissible physical conditions (dP/dρ≤1) the maximum values ofM core/M,R core/R and the surface redshift, for an isothermal coreP=ρ/3, are respectively 0.473, 0.554, and 0.565. Using the conditionH=0, it has been shown that for isothermal cores corresponding to the equation of the stateP≥0.6ρ, the configurations are pulsationally unstable. 相似文献
86.
The flow of a viscous incompressible and electrically conducting fluid produced by harmonically oscillating wall of infinite extent in presence of a transverse magnetic field is considered. Exact solutions for velocity, induced magnetic field, electrical current density and skin-friction are obtained when the magnetic Prandtl number is unity. It is shown that the velocity has a phase lag with respect to the oscillations of the wall. This phase lag is found to be significantly affected by the applied magnetic field.On study-leave from Defence Science Laboratory, Delhi, India. 相似文献
87.
Assuming local thermodynamic equilibrium and the same relative abundances to prevail both in photosphere and faculae, the concentration-optical depth curves for molecules CH, NH, OH, C2, CN and CO have been obtained for the four combinations of two photospheric and two facular models and the relative excesses of these molecules in the photosphere over those in faculae have been calculated. The change of photospheric model significantly affects the relationship, for a given facular model, between and D
0, the dissociation energy of the molecule concerned. Besides, the average depth of formation in the facular models and photospheric models shows a relationship with D
0. 相似文献
88.
Determination of transport properties of geomaterials is an important issue in many fields of engineering analysis and design. For example, in petroleum engineering, in situ permeability of an oil reservoir may be crucial in establishing its viability for exploitation, whilst prevention of leakage from underground storage facilities for oil and gas, nuclear waste as well as viability of CO2 sequestration projects crucially depends on its long‐term values. Permeability is indirectly related to the porosity, pore‐size distribution and pore architecture of the porous media. These parameters evolve when a strain field is imposed. Physical measurement of permeability under a strain field in laboratory conditions is difficult, expensive and prone to a number of uncertainties. In the past, pore network models have been used to compute permeability of materials under stress/strain‐free conditions. In this paper, we propose an enhanced pore network model to compute permeability of rocks and rock‐like porous media under a stress/strain field. Data of pore‐size distribution obtained from mercury intrusion porosimetry are used to compute permeability of rock samples from various unspecified oilfields in the world. It is shown that the two permeabilities can be predicted from the model with sufficient accuracy. A hypothesis for change in porosity, pore‐size distribution and pore architecture as a result of imposed mechanical strains is then proposed. Based on this, permeability is computed again for one of the rock samples under uniaxial and triaxial compressive and tensile strain fields. It is shown that depending on the state of strain field imposed, permeability evolves in an anisotropic manner. Permeability under tensile strain field increases dramatically compared with the reduction that takes place under compressive strain field of the same magnitude. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
89.
Ajay Kumar S. N. S. Birua Dheeraj Pande A. R. Nath P. V. Ramesh Babu S. A. Pandit 《Journal of the Geological Society of India》2009,73(4):537-542
Several radioactive quartz-pebble conglomerate (QPC) occurrences at the western margin of Archaean Bonai granite and overlying
Iron Ore Group (IOG) rocks have recently been located over a total strike length of 8–10 km intermittently in a NE-SW to E-W
trend with steep dips due north-west to north in parts of Sundargarh district of Orissa. The QPC samples have analysed up
to 0.039% U3O8 and 0.035% ThO2 with high concentration of Y (74 to 518 ppm), La(<100 to 880 ppm), Cr ( 126 to 633 ppm), Zr (137 to 1250 ppm) and Pb (31
to 581 ppm). Cellulose Nitrate (CN) film studies of few QPC samples indicated adsorbed uranium over goethite and infiltrated
ferruginous material (limonite), secondary uranium as encrustation and fracture filling and discrete sub-rounded grains of
monazite, zircon, allanite and rare xenotime in the matrix of QPC as radioactive phases. Higher content of Th over U, elevated
concentration of Y and La in QPC eliminates the possibility of its low temperature product by epigenetic processes. Poor correlation
of U with elements like Pb, Y, Zr, La and Cr can be explained due to surficial leaching of uranium from QPC after its deposition
as reflected by adsorbed U over iron-oxides and low U/Th ratio in QPC in the area. 相似文献
90.
A consideration of the dissociation equilibrium of diatomic molecules in the Utrecht Reference Photosphere leads us to conclude that SH, SiO, CS, HF and HCl may show up in enough concentrations in the solar atmosphere. The number above photosphere for these molecules is comparable with or more than that of MgH. 相似文献