Silver and silver-bearing minerals at the Um Samiuki volcanogenic massive sulphide deposit, Eastern Desert, Egypt

The Um Samiuki Zn–Cu–Pb–Ag mineralisation, south Eastern Desert, Egypt is hosted by felsic volcanic rocks which form part of the 712-Ma-old, east-west-trending Shadli Volcanic Belt. Two major occurrences of massive sulphides are present at the top of rhyolitic breccia in the Western and Eastern mine areas. In each occurrence, a bornite-bearing zone is overlain by a pyrite-chalcopyrite-bearing zone and underlain by a disseminated, Cu-depleted zone. In the massive sulphide ore, sphalerite, chalcopyrite, pyrite, galena, bornite and tetrahedrite–tennantite are major minerals, whereas arsenopyrite, pyrrhotite, molybdenite and magnetite are accessory phases. Covellite and digenite are common secondary minerals. Bornite, tetrahedrite–tennantite and covellite contain high amounts of silver (averages of 1.97, 1.39 and 1.82 wt% respectively). Based on mineralogical balance calculations, bornite and covellite accommodate 80% of silver in the Um Samiuki deposit. Ag was incorporated in the crystal structure of the early-crystallised copper sulphides and sulphosalts and silver minerals. The temperature, sequential precipitation of the fluids and the structure of the crystallising phases control the distribution of silver. Post-depositional deformation and metamorphic processes caused liberation, remobilisation and redeposition of silver within the massive sulphides.Editorial handling: D. Lentz     

Flow exchange between the deep and shallow groundwaters in the Sbeϊtla synclinal basin (Tunisia): an isotopic approach

Stable (¹⁸O, ² H) and radiogenic (³H, ¹⁴C) isotopes of water have been used to constrain the source, origin, age, migration pathway and mixing processes in the Sbeïtla (Tunisia) system. The system is composed of an upper unconfined Middle Miocene aquifer with a variable thickness from 10–300 m, an intermediate confined/unconfined Lower Miocene aquifer about 100 m thick and a deeper confined Lower Cretaceous aquifer about 150 m thick separated by a thin clay layer. A total of 53 groundwater samples from the three aquifers and spring samples were collected during February and March 2000 and isotopically analysed using conventional methods. The stable isotopes composition of waters establishes that the deep groundwater (depleted as compared to present corresponding local rainfall) is ancient water recharged probably during the late Pleistocene and the early Holocene periods. The relatively recent water in the superficial aquifer is composed of mixed waters resulting presumably from upward leakage from the deeper groundwater. The radiogenic (³H, ¹⁴C) isotopes data confirm that the recent water, with a tritium content between 6.5 and 19 TU, represents post-nuclear recharge and the ancient groundwater with low carbon-14 contents between 7 and 26 pmC infiltrated between 8,000 to 20,000 years ago. When used in conjunction with the stable isotopes data, the mixing process can be clearly identified, especially in the Sbeïtla sill area. Groundwater of the upper aquifer exhibits isotopic signatures of both the old and recent waters. By using isotopic mass balance, the computed contribution of the deep groundwater in recharging the upper aquifer is up to 94%.     

The role of gender and age in fracture distribution following the 2008 Wenchuan earthquake

This study explored demographic variations among victims injured in the 2008 Wenchuan earthquake. The study analyzed records of 2,148 patients who were hospitalized with earthquake-related injuries in 14 hospitals between May 12 and May 21 of 2008. We tested the effects of gender and age on the incidence of fractures and amputations. Although more women than men were hospitalized as earthquake victims, the results indicated that a higher incidence of pelvic fracture in women was the only statistically significant injury with regard to gender. Age had a more complex effect on the rate and pattern of fractures. Children younger than 15 years old were the most likely to sustain skull fractures and amputations. The elderly were the most likely to be associated with limb fractures. Adult men were the most likely to suffer spine fractures and adult women rib fractures. The paper concludes with an interpretation of the results in the context of China’s rural conditions and discusses implications for post-disaster emergency operations and planning.     

Use of Landsat 7 ETM+ for lithological and structural mapping of Wadi Afara Heouine area (Tahifet–Central Hoggar, Algeria)

Wadi Afara Héouine area (Tahifet, Central Hoggar) is marked by the existence of very diversified lithologies affected by big submeridian accidents, of which Wadi Afara Héouine, who represents a "linear discontinuity" on near 80 km forming a morphological limit which separates, a strongly gneissic domain (Oua Hellèdjène) of a domain with metasedimentary dominant (Aghefsa). Lithologies not described in the former works were defined by the application of specific treatments (color composite, band ratios, and selective PCA). They also allow us to suggest some modifications to the geologic map of Tahifet. Directional filters associated to the previous treatments helped us in the elaboration of lineament map which accentuates the various accidents affecting the region. It seems clearly that treatments applied to the images ETM contribute in an undeniable way to the geologic study of this region especially since a big part of this region is inaccessible     

Investigating the Effects of Local Contact Loss on the Earth Pressure Distribution on Rigid Pipes

In this paper, the earth pressure distribution acting on a buried pipe with localized support loss is investigated experimentally and numerically in this study. A laboratory setup has been designed to facilitate the simulation of the local wall separation and to track the changes in earth pressure at selected locations along the pipe circumference. Validated by the experimental results, two-dimensional finite element analysis has been conducted to examine the role of soil-pipe interaction on the pressure distribution around the pipe before and after the contact loss is introduced. Experimental and numerical results revealed that the presence of a gap between the pipe wall and the surrounding backfill can lead to significant changes in contact pressure and bending moment in the pipe wall in the immediate vicinity of the gap. This study suggests that efforts to detect and repair areas experiencing support loss should be made before significant changes in pressure develop causing stress concentration in the pipe wall as it may lead to pipe damage.     

Deciphering interaction of regional aquifers in Southern Tunisia using hydrochemistry and isotopic tools

Groundwater is the most important source of water supply in southern Tunisia. Previous hydrogeologic and isotopic studies carried out in this region revealed the existence of two major aquifer systems: the “Complex Terminal” (CT) and the “Continental Intercalaire” (CI). Turonian carbonates constitute one of the major aquifer levels of the CT multilayered aquifer. It extends over most of southern Tunisia, and its hydrodynamic regime is largely influenced by tectonics, lithology and recharge conditions. Forty-eight groundwater samples from the CI and Turonian aquifers were collected between January and April 2004 for chemical and isotopic analyses. Hydrochemistry and isotopic tools were combined to get an insight into the processes controlling chemical composition of groundwater and wide-scale interaction of these two aquifer systems. Analysis of the dissolved constituents revealed that several processes control the observed chemical composition: (i) incongruent dissolution of carbonate minerals, (ii) dissolution of evaporitic minerals, and (iii) cation exchange. Dissolution alone cannot account for the observed high supersaturation states of groundwater with respect to calcite and dolomite. The observed supersaturation is most probably linked to geogenic CO₂ entering water-bearing horizons of the CT and CI aquifers via deep tectonic faults and discontinuities and subsequent degassing in the exploitation wells. Presence of geogenic CO₂ in the investigated region was confirmed by C isotope data of the DIC reservoir. The radiocarbon content of the Turonian samples varied between 9.5 and 43 pmc. For CI samples generally lower values were recorded, between 3.8 and 22.5 pmc. Stable isotope composition of Turonian groundwater samples varied from −8.3 to −5.3‰ for δ¹⁸O and from −60 to −25‰ for δ²H. The corresponding ranges of δ values for the Continental Intercalaire samples were from −8.9‰ to −6.9‰ for δ¹⁸O and from −68.2‰ to −45.7‰ for δ²H. Stable isotope composition of groundwater representing CT and CI aquifers provide strong evidence for regional interaction between both systems.     

Application of environmental tracers to study groundwater recharge in a semi-arid area of Central Tunisia

Abstract

Groundwater of the Tertiary-Quaternary Formations in the Jeloula basin (Central Tunisia), together with rain and surface waters, were analysed to investigate the mineralization processes, the origin of the water and its recharge sources. The water samples present a large spatial variability of chemical facies which is related to their interaction with the geological formations. The main sources of the water mineralization are the dissolution of evaporitic and carbonate minerals and cation exchange reactions. Stable isotopes indicate that most groundwater samples originate from infiltration of modern precipitation. Surface water samples from small dam reservoirs show a ¹⁸O/²H enrichment, which is typical of water exposed to open-surface evaporation in a semi-arid region. Considerable data of ³H and ¹⁴C allow the qualitative identification of the present-day recharge that is probably supplied by infiltration of recent flood waters in the Wadi El Hamra valley, and by direct infiltration of meteoric water through the local carbonate outcrops.

Editor D. Koutsoyiannis; Associate editor S. Faye     

A note on the Hori-Lie perturbation technique

In this paper we describe how to avoid the introduction of Hori's pseudo time in general planetary theory in the case of two planets.     

Marine Sr (Ca) input in Quaternary volcanic rock weathering profiles from the Mediterranean coast of Morocco: Sr isotopic approach

Carbonate commonly accumulates in weathering profiles developed on noncalcareous parent material under arid and semiarid climatic conditions. Such weathering profile types are widespread in Morocco, making it critical to know the sources of the calcium in order to understand the genesis of carbonate-rich soils. In this study, we use ⁸⁷Sr/⁸⁶Sr as a geochemical tracer of the Ca sources in weathering profiles developed on volcanic rocks (basalt, tuff, andesite and latite) in the Mediterranean coast of Morocco. The results show that the most of the Sr, and hence Ca, is of an external origin, derived from (i) sea-water for the profiles located near to the coast or (ii) sea-water plus Liassic carbonate outcropping in the catchment for the profiles more distant from the coastline. The contribution of the host rock is small, being less than 25%. The ratio of the Sr (Ca) from the parent material to that from the external sources is controlled by the degree of porosity developed in the profile.     

Rotational excitation of aluminium monofluoride (AlF) by?He?atom at low temperature

We report on the calculation of collision induced rotational excitation cross sections and rate coefficients of AlF by He atom at low temperature. These quantities were obtained by first computing the interaction potential energy surface (PES) of the AlF(X  ¹Σ⁺)-He(¹ S) van der Waals complex at the ab initio Coupled Cluster with Single and Double and perturbative Triple excitations [CCSD(T)] level of theory. The aug-cc-pVQZ Gaussian basis, to which was added a set of bond functions, was used for that purpose. The calculations account for basis set superposition errors (BSSE). The interaction potential presents a minimum of ∼24 cm⁻¹ below the AlF-He dissociation limit. The PES was fitted on a basis of Legendre polynomial functions to allow for the calculation of cross sections in the close-coupling (CC) approach. By averaging these cross sections over a Maxwell-Boltzmann velocity distribution, rate coefficients were inferred at low temperatures (T≤300 K). From our computations, a propensity towards ΔJ=1 transitions is observed.