Malachite Green Adsorption onto Chitosan Coated Bentonite Beads: Isotherms,Kinetics and Mechanism

The removal of Malachite green (MG) from aqueous solutions by cross‐linked chitosan coated bentonite (CCB) beads was investigated and the CCB beads were characterized by Fourier Transform Infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) coupled with energy dispersive spectroscopy (EDS) and X‐ray diffraction (XRD) analysis. Solubility and swelling tests were performed in order to determine the stability of the CCB beads in acidic solution, basic solution and distilled water. The amount of MG adsorbed was shown to be influenced by the initial pH of the solution, contact time and the initial MG concentration. A kinetic study indicated that a pseudo‐second‐order model agreed well with the experimental data. From the Langmuir isotherm model, the maximum adsorption capacity of MG was found to be 435.0 mg g^–1. Desorption tests were carried out at different concentrations of EDTA, H₂SO₄ and NaOH. However, all desorbing solutions showed zero recovery of MG at all concentrations.     

Dynamic Treatment Response of Olive Mills Wastewater Using Series of Adsorption Steps

Olive mills wastewater (OMW) is a critical environmental problem in the Mediterranean area due to its extremely high levels of COD and phenols. In this study, a group of adsorption experiments were conducted to investigate the dynamic response of the pH, COD, phenols, TSS, TDS, and TS concentrations of pretreated OMW, using different concentrations of activated carbon as adsorbent. The pretreatment included sedimentation and filtration of OMW. The pretreated OMW was then subjected to adsorption. A series of adsorption steps in stirred batch vessels were studied, namely, one stage, two‐stage countercurrent, and three‐stage countercurrent adsorption systems. A combined two‐ two‐stage countercurrent adsorption steps were also studied. Experimental results showed that such treatment protocols were promising. For example, a treatment protocol composed of a three‐stage countercurrent adsorption process using activated carbon of concentration of 24 g/L of OMW was able to reduce the COD from 60 000 mg/L down to 22 300 mg/L, while phenols were reduced from 450 to 15 mg/L.     

Extraction and accuracy assessment of high-resolution DEM and derived orthoimages from ALOS-PRISM data over Sahel-Doukkala (Morocco)

In Sahel-Doukkala, which is characterized by lands of a relatively low relief, global DEMs and DEMs generated from digitizing topographic maps, have been the primary source of several multidisciplinary researches. Although these products present a great value of the conducted research, the level of the given accuracy is not sufficient enough for detailed geospatial analysis. These requirements led us to generate a high-resolution DEM as an alternative of available global DEMs or/and DEMs generated from digitizing topographic maps. In this study, we present a workflow to extract high-resolution DEM at 5 m resolution and derived orthoimages from ALOS-PRISM data over Sahel-Doukkala, through photogrammetric techniques, using a variation of GCPs obtained from topographic maps at scale 1:25,000. The accuracy of the generated products is reported according to NSSDA standards. Using ten GCPs, a PRISM-DEM with 3.88 m vertical accuracy and 11.60 m horizontal accuracy, both at 95% confidence level is obtained. This DEM will serve as base dataset for further detailed geospatial analysis and mapping applications in order to identify the relationship between surface parameters and groundwater, and also to assess and understand all factors influencing the development of karst landscapes and consequently subsurface stability in the investigated area.     

Slope aspect effects of loess slides and its spatial differentiation in different geomorphologic types

Several researchers have evaluated landslide susceptibility using various factors, and only few have focused on only one landslide impacting factor in detail, especially its response to geomorphologic evolution. Slope aspect is one of the key conditioning factors for landslide susceptibility assessment in fine-scale studies. To elucidate the slope aspect effect of loess slides and its spatial differentiation, we selected three study areas with different geomorphologic settings in the Chinese Loess Plateau, and developed landslide inventory through the interpretation of remote sensing images and intensive field survey. By using GIS and statistical approach, including extreme ratio and coefficient of variation, we characterized the distribution of loess slides in different slope aspects and compared their spatial differentiation. The results showed that the slope aspect has a significant influence on the spatial distribution of loess slides. The number and area of loess slide is higher in south-facing slope in all the three counties. Moreover, the slope aspect effects on loess slides were mediated by the geomorphologic types. The more mature the development of geomorphology, the more obvious is the slope aspect effect on the landslide. This study is very important for the study on geomorphologic evolution of Loess Plateau.     

Mineralogy and metasomatic evolution of the Mianeh iron skarn deposit,Norduz-Agarak border,NW Iran

The Mianeh iron skarn deposit lies in the Arasbaran region within the Qaradagh metallogenic district, NW Iran. This high-grade massive magnetite skarn originated by the interaction of Upper Cretaceous limestone with metasomatic ore-bearing fluids associated with hypabyssal Oligo-Miocene quartz diorite. Mineral chemistry of the primary clinopyroxenes demonstrates the sub-alkaline, volcanic arc setting of magmatism. Two general stages of skarnification are recognized: (1) silicate skarn (stage I) is composed essentially of grossular and low-Fe diopside formed before the main mineralization and (2) magnetite-garnet skarn (stage II) composed of strongly anisotropic coarse-grained garnets with a narrow compositional zoning radially formed by addictive infiltrating of silica and iron-rich metasomatic fluids which overprint and/or crosscut the early stage silicate skarn. Anhydrous prograde calc-silicate assemblages were replaced by a series of hydrous calc-silicates (epidote, tremolite-actinolite) and/or quartz, calcite, magnetite, hematite, and pyrite. Magnetite (±hematite) is the dominant hypogene ore mineral that initially precipitated coincident with the late prograde to the early retrograde metasomatic stages. Mineralogical studies suggest that silicate skarn formation commenced at temperatures about 560 °C, X(CO₂)_fluid ≤ 0.15, αSiO₂～?1.0, and fluid pressure 1.0 kbar. The magnetite-garnet skarn formed from H₂O-rich fluids [X(CO₂)_fluid < 0.1] at a temperature of 525 to 450 °C and maximum log ?O₂ between ?20.2 and ?23. During the late stages of prograde skarn development, the stability field of andradite shifted to low ?O₂ and ?S₂ conditions resulting in main iron ore deposition (as magnetite). The andradite replacement temperature and presence of pyrite (instead of pyrrhotite) suggest that log?S₂ remained constant at about ?6 to ?7 during cooling of the system.     

Hydrochemical characteristics and evaluation of the granite aquifer in the Alwadeen area,southwest Saudi Arabia

This study was carried out in the Alwadeen area of Khamis Mushayt district of southwestern Saudi Arabia to evaluate the hydrochemical characteristics of the shallow hard rock aquifers. These hard rock aquifers mostly comprise granites and contain significant quantities of groundwater that complement the available groundwater from the unconsolidated alluvial sediments in the nearby wadis. The field investigation indicates two main fracture sets which intersect each other and are oriented in the west-northwest and east-west directions. The granitic rocks in the area are intruded by coarse-grained and quartz-rich monzogranite and pegmatite veins. Hydrogeologically, the fracture systems are important since they facilitate the groundwater storage and assume the transmissive function during times of groundwater abstraction. Given the fact that groundwater in the fractured rock aquifers generally occurs at shallow depths, it may be exposed to contamination from surface and/or near-surface sources, and it is therefore important to evaluate its quality. To this end, a hydrochemical analysis was carried out on six groundwater samples collected from the area. The hydrochemistry revealed that the groundwater is fairly fresh, and facies analysis reveals mixed Na-Cl and Ca-Mg-Cl-SO₄ types. Overall, the results reveal that the groundwater is saturated with calcite and dolomite, but unsaturated with gypsum and halite. The degree of salinity increases in the direction of the groundwater flow due to increased rock-water interaction.     

Beach monazites from Alleppey: A window to the Trivandrum Block,Southern India

Detrital monazites can be used to reconstruct the tectonothermal history of their provenance. Dating of beach monazites from Alleppey by EPMA U-Th-Pb_total technique using the centroid method demonstrates that the ages recorded by even a small number of 28 analyses from a single thin section grain mount can potentially reveal a considerable portion of the tectonothermal history of the Trivamdrum block. Three monazite populations were identified that yielded ages 605 ± 9, 575 ± 23 and 548 ± 11 Ma, which have their more or less exact counterparts reported from the Trivandrum Block. One monazite grain yielded random Paleoproterozoic ages ranging from 1756 Ma to 1345 Ma representing similar ages which earlier have been interpreted as due to differential Pb-loss from >2000 Ma monazites during the late Neoproterozoic-Cambrian metamorphism.     

Surface soil assessment in the Ubhur area,north of Jeddah,western Saudi Arabia,using a multichannel analysis of surface waves method

Ten boreholes drilled in Ubhur area up to the depth of bedrock indicted the shallow depth of bedrock where the average depth ranges between 10 and 15 m. The standard penetration test N-values of these boreholes were measured and averaged. Based on N-values to the depth of bedrock, Ubhur area can be classified as site class C and D. Multichannel analysis of surface waves technique has been applied along seventy six profiles using 24-channel geophone array and 4.5Hz vertical geophones with 1m geophone spacing and sledgehammer and/or weight drop as seismic energy sources. Values of shear wave velocity to 30 m are calculated and then averaged (Vs30) where it ranges between 310.08 m/s and 1139.8 m/s. Therefore, Ubhur area can be classified into site class B, C and D based on site classification of the national earthquake hazards reduction program (NEHRP) recommendations. Accordingly, the greatest part of the study area falls in site class C while class B and D covered limited areas in the western and the eastern parts respectively. Depending on the shallow depth of bedrock in the study area, the Vs30 parameter is not applicable in the study area so the average values of Vs for the soil thickness, excluding the bedrock, have been calculated and mapped for site class C and D only. So Vs30 approach is not applicable for areas with shallow depth of bedrock which gives higher classification.     

Shake Table Tests and Numerical Modeling of Liquefaction of Kasai River Sand

As a part of the seismic safety evaluation of several bridges and other hydraulic structures located on Kasai River bed in India, the liquefaction potential of Kasai River sand is studied in 1-g shake table in laboratory and numerically using a commercial software FLAC 2D. The surface settlement, lateral spreading, predominant frequency, amplification of the ground motion and pore water pressure development in Kasai River sand in dry and liquefied states have been studied when subjected to sinusoidal motions of amplitude 0.35 g at a frequency of 2 Hz. The nonlinear curves used to represent shear strain dependency of stiffness and damping ratio of Kasai River sand are obtained from cyclic triaxial tests. Reasonably good agreement between the experimental and the numerical results is observed. It is found that the settlement and lateral spreading for the liquefied sand is 2.60 and 2.50 times than those of the sand in the dry state. The volumetric strain of the liquefied sand is found to be around 4%, which is significantly higher than 1.53% observed in the dry sand. It is observed that the amplification of the peak ground acceleration for the saturated sand is 1.08 and 1.32 times higher than that for the dry sand from theoretical and experimental results, respectively. The shear strain developed in the liquefied sand is 1.17 times more than that for dry sand. The fundamental and higher modal frequencies of dry sand are found to be 1.13, 1.117 and 1.119 times more than those for the saturated sand, respectively.     

Expanding and shearing inhomogeneous cosmological models for viscous fluid distributions with electromagnetic field

Some inhomogeneous viscous fluid cosmological models in the presence of an electromagnetic field for cylindrical symmetry are obtained. To get a determinate solution, it is assumed that the coefficient of shear viscosity is proportional to the rate of expansion. The paper also discusses the behaviour of the model when viscosity is absent and comments on some other physical properties.