Thermodynamic conditions of framework grain dissolution of clastic rocks and its application in Kela 2 gas field

Feldspar and clastic debris are the most important constituent framework grains of sedimentary clastic rocks and their chemical dissolution plays an essential role in the formation and evolution of the secondary pore in the reservoir rocks. On the basis of thermodynamic phase equilibrium, this study investigates the chemical equilibrium relationships between fluid and various plagioclase and K-feldspar in diagenesis of the sediments, particularly, the impact of temperature and fluid compositions (pH, activity of K+, Na+, Ca2+ and so on) on precipitation and dissolution equilibria of feldspars. Feldspar is extremely easily dissolved in the acid pore water with a low salinity when temperature decreases. The dissolution of anorthite end-member of plagioclase is related to the Ca content of the mineral and the fluid, higher Ca either in the mineral or in the fluid, easier dissolution of the feldspar. Moreover, the dissolution of albite end-member of plagioclase is related to Na of both the mineral and fluid,     

Seismic damage analysis including inelastic shear–flexure interaction

The paper focusses on seismic damage analysis of reinforced concrete (R/C) members, accounting for shear–flexure interaction in the inelastic range. A finite element of the beam-column type recently proposed by the writers for the seismic analysis of R/C structures is first briefly described. The analytical model consists of two distributed flexibility sub-elements which interact throughout the analysis to simulate inelastic flexural and shear response. The finite element accounts for shear strength degradation with inelastic curvature demand, as well as coupling between inelastic flexural and shear deformations after flexural yielding. Based on this model, a seismic damage index is proposed taking into account both inelastic flexural and shear deformations, as well as their interaction. The finite element and the seismic damage index are used to analyse the response of R/C columns tested under cyclic loading and failing either in shear or in flexure. It is shown that the analytical model and damage index can predict and describe well the hysteretic response of R/C columns with different types of failure.     

Hydrochemical,isotopic, and reservoir characterization of the Pasinler (Erzurum) geothermal field,eastern Turkey

The reservoir temperature and conceptual model of the Pasinler geothermal area, which is one of the most important geothermal areas in Eastern Anatolia, are determined by considering its hydrogeochemical and isotope properties. The geothermal waters have a temperature of 51 °C in the geothermal wells and are of Na–Cl–HCO₃ type. The isotope contents of geothermal waters indicate that they are of meteoric origin and that they recharge on higher elevations than cold waters. The geothermal waters are of immature water class and their reservoir temperatures are calculated as 122–155 °C, and their cold water mixture rate is calculated as 32%. According to the δ¹³C_VPDB values, the carbon in the geothermal waters originated from the dissolved carbon in the groundwaters and mantle-based CO₂ gases. According to the δ³⁴S_CDT values, the sources of sulfur in the geothermal waters are volcanic sulfur, oil and coal, and limestones. The sources of the major ions (Na⁺, Ca²⁺, Mg²⁺, Cl^?, and HCO₃ ^?) in the geothermal waters are ion exchange and plagioclase and silicate weathering. It is determined that the volcanic rocks in the area have effects on the water chemistry and elements like Zn, Rb, Sr, and Ba originated from the rhyolite, rhyolitic tuff, and basalts. The rare earth element (REE) content of the geothermal waters is low, and according to the normalized REE diagrams, the light REE are getting depleted and heavy REE are getting enriched. The positive Eu and negative Ce anomalies of waters indicate oxygen-rich environments.     

Uranium mineralisation associated with felsic volcanism at Mohar,Shivpuri district,Madhya Pradesh

Several small lensoidal bodies of felsic volcanics are exposed in a curvilinear pattern within the brecciated granitoids of Bundelkhand Gneissic Complex (BGC) at Mohar. Sub-surface data reveals extensive presence of these felsic volcanics below the sediment of Vindhyan Supergroup. It occurs like a sheet with thickness varying from 12 m to 134 m. Its lateral extent has been traced upto 4.8 km. Multiple flows of felsic magma are identified based on colour, granularity, cross cutting relations and cyclic distribution of multiple vesicular bands along the entire thickness of felsic magma. The felsic rock contains upto 13.21% K₂O. Chemical composition of these felsic volcanics varies across the column. Petrographically and chemically all these felsic volcanics are identified as rhyolite or rhyolite tuff.     

Ilmenite composition in the Tellnes Fe–Ti deposit,SW Norway: fractional crystallization,postcumulus evolution and ilmenite–zircon relation

Major and trace element XRF and in situ LA-ICP-MS analyses of ilmenite in the Tellnes ilmenite deposit, Rogaland Anorthosite Province, SW Norway, constrains a two stage fractional crystallization model of a ferrodioritic Fe-Ti-P rich melt. Stage 1 is characterized by ilmenite-plagioclase cumulates, partly stored in the lower part of the ore body (Lower Central Zone, LCZ), and stage 2 by ilmenite-plagioclase-orthopyroxene-olivine cumulates (Upper Central Zone, UCZ). The concentration of V and Cr in ilmenite, corrected for the trapped liquid effect, (1) defines the cotectic proportion of ilmenite to be 17.5 wt% during stage 1, and (2) implies an increase of D _V^Ilm during stage 2, most likely related to a shift in fO₂. The proportion of 17.5 wt% is lower than the modal proportion of ilmenite (ca. 50 wt%) in the ore body, implying accumulation of ilmenite and flotation of plagioclase. The fraction of residual liquid left after crystallization of Tellnes cumulates is estimated at 0.6 and the flotation of plagioclase at 26 wt% of the initial melt mass. The increasing content of intercumulus magnetite with stratigraphic height, from 0 to ca. 3 wt%, results from differentiation of the trapped liquid towards magnetite saturation. The MgO content of ilmenite (1.4–4.4 wt%) is much lower than the expected cumulus composition. It shows extensive postcumulus re-equilibration with trapped liquid and ferromagnesian silicates, correlated with distance to the host anorthosite. The Zr content of ilmenite, provided by in situ analyses, is low (<114 ppm) and uncorrelated with stratigraphy or Cr content. The data demonstrate that zircon coronas observed around ilmenite formed by subsolidus exsolution of ZrO₂ from ilmenite. The U-Pb zircon age of 920 ± 3 Ma probably records this exsolution process. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Evaluation of Curve Fitting Techniques in Deriving p–y Curves for Laterally Loaded Piles

The p–y method is one of the most popular methods for the analysis and design of laterally loaded piles. The mathematical relationship it provides between the bending moment, which can be easily measured at strain gauges along the pile, and the soil resistance and lateral pile displacement, facilitates the construction of p–y curves. Numerical techniques are required to fit smooth continuous curves to the discrete bending moment data in order to improve the accuracy of subsequent differentiation and integration operations. Due to the lack of guidance on the optimum positioning of strain gauges and the reliability and accuracy of curve fitting methods, a unifying study, inclusive of small (0.61 m) and large (3.8 and 7.5 m) diameter piles in clay, was carried out using 18 strain gauge layouts and cubic spline, cubic to quintic B-spline and 3rd to 10th degree global polynomial techniques. Bending moment data was obtained using 3D finite element analysis. Through a comprehensive evaluation, the cubic and cubic B-spline methods were found to be consistently accurate in deriving p–y curves for both the small and large diameter piles.     

Nonlinear Atmospheric and Climate Dynamics in China （2003-2006）： A Review

Recent advances in the study of nonlinear atmospheric and climate dynamics in China （2003 2006） are briefly reviewed. Major achievements in the following eight areas are covered： nonlinear error dynamics and predictability; nonlinear analysis of observational data; eddy-forced envelope Rossby soliton theory; sensitivity and stability of the ocean＇s thermohaline circulation; nonlinear wave dynamics; nonlinear analysis on fluctuations in the atmospheric boundary layer; the basic structures of atmospheric motions; some applications of variational methods.     

Developing a model of climate change behavior among adolescents

Research on adolescent climate change perceptions has uncovered key insights about how knowledge, concern, and hope might relate to behavior and the potential for educational interventions to influence these factors. However, few of these studies have employed treatment/control designs that might address causality and none have addressed how these factors might interact to influence behavior. We developed a model of behavior change where a climate education treatment impacted knowledge, knowledge impacted hope and concern, and hope and concern together impacted behavior. We empirically tested the utility of this model and the causal relationships within it using a pre/post, treatment/control evaluation of climate education among adolescents in North Carolina, USA (n?=?1041). We found support for a causal relationship between the treatment and gains in knowledge, but not between treatment and behavior. However, we did find support for a path model in which climate change knowledge positively relates to increased climate change concern and hope, and increases in concern and hope predict changes in pro-environmental behavior. Low SES was related to smaller gains in knowledge, concern, and behavior. Our results contribute to a theoretical understanding of climate change behaviors among adolescents and suggest that climate education aiming to change behavior should focus on building hope and concern.     

Study and application of PS-wave pre-stack migration in HTI media and an anisotropic correction method

Anisotropy correction is necessary during the processing of converted PSwave seismic data to achieve accurate structural imaging, reservoir prediction, and fracture detection. To effectively eliminate the adverse effects of S-wave splitting and to improve PSwave imaging quality, we tested methods for pre-stack migration imaging and anisotropic correction of PS-wave data. We based this on the propagation rules of seismic waves in a horizontal transverse isotropy medium, which is a fractured medium model that reflects likely subsurface conditions in the field. We used the radial (R) and transverse (T) components of PS-wave data to separate the fast and slow S-wave components, after which their propagation moveout was effectively extracted. Meanwhile, corrections for the energies and propagation moveouts of the R and T components were implemented using mathematical rotation. The PS-wave imaging quality was distinctly improved, and we demonstrated the reliability of our methods through numerical simulations. Applying our methods to three-dimensional and three-component seismic field data from the Xinchang-Hexingchang region of the Western Sichuan Depression in China, we obtained high-quality seismic imaging with continuous reflection wave groups, distinct structural features, and specific stratigraphic contact relationships. This study provides an effective and reliable approach for data processing that will improve the exploration of complex, hidden lithologic gas reservoirs.