Transformation of garnet epidote amphibolite to eclogite, western Dabie Mountains, China

Omphacite and garnet coronas around amphibole occur in amphibolites in the Hong'an area, western Dabie Mountains, China. These amphibolites consist of an epidote–amphibolite facies assemblage of amphibole, garnet, albite, clinozoisite, paragonite, ilmenite and quartz, which is incompletely overprinted by an eclogite facies assemblage of garnet, omphacite and rutile. Coronas around amphibole can be divided into three types: an omphacite corona; a garnet–omphacite–rutile corona; and, a garnet–omphacite corona with less rutile. Chemographic analysis for local reaction domains in combination with petrographical observations show that reactions Amp + Ab + Pg = Omp +Czo + Qtz + H₂O, and Amp + Ab = Omp ± Czo + Qtz + H₂O may lead to the development of omphacite coronas. The garnet–omphacite–rutile corona was formed from the reaction Amp + Ab + Czo + Ilm ± Qtz = Omp + Grt + Rt + H₂O. In garnet–omphacite coronas, the garnet corona grew during an early stage of epidote amphibolite facies metamorphism, whereas omphacite probably formed by the reactions forming the omphacite corona during the eclogite facies stage. It is estimated that these reactions occurred at 0.8–1.4 GPa and 480–610 °C using the garnet–clinopyroxene thermometer and omphacite barometer in the presence of albite.     

Conditions of pocket formation in the Oktyabrskaya tourmaline-rich gem pegmatite (the Malkhan field, Central Transbaikalia, Russia)

Coexisting melt (MI), fluid-melt (FMI) and fluid (FI) inclusions in quartz from the Oktaybrskaya pegmatite, central Transbaikalia, have been studied and the thermodynamic modeling of PVTX-properties of aqueous orthoboric-acid fluids has been carried out to define the conditions of pocket formation. At room temperature, FMI in early pocket quartz and in quartz from the coarse-grained quartz–oligoclase host pegmatite contain crystalline aggregates and an orthoboric-acid fluid. The portion of FMI in inclusion assemblages decreases and the volume of fluid in inclusions increases from the early to the late growth zones in the pocket quartz. No FMI have been found in the late growth zones. Significant variations of solid/fluid ratios in the neighboring FMI result from heterogeneous entrapment of coexisting melts and fluids by a host mineral. Raman spectroscopy, SEM EDS and EMPA indicate that the crystalline aggregates in FMI are dominated by mica minerals of the boron-rich muscovite–nanpingite CsAl₂[AlSi₃O₁₀](OH,F)₂ series as well as lepidolite. Topaz, quartz, potassium feldspar and several unidentified minerals occur in much lower amounts. Fluid isolations in FMI and FI have similar total salinity (4–8 wt.% NaCl eq.) and H₃BO₃ contents (12–16 wt.%). The melt inclusions in host-pegmatite quartz homogenize at 570–600 °C. The silicate crystalline aggregates in large inclusions in pocket quartz completely melt at 615 °C. However, even after those inclusions were significantly overheated at 650±10 °C and 2.5 kbar during 24 h they remained non-homogeneous and displayed two types: (i) glass+unmelted crystals and (ii) fluid+glass. The FMI glasses contain 1.94–2.73 wt.% F, 2.51 wt.% B₂O₃, 3.64–5.20 wt.% Cs₂O, 0.54 wt.% Li₂O, 0.57 wt.% Ta₂O₅, 0.10 wt.% Nb₂O₅, 0.12 wt.% BeO. The H₂O content of the glass could exceed 12 wt.%. Such compositions suggest that the residual melts of the latest magmatic stage were strongly enriched in H₂O, B, F, Cs and contained elevated concentrations of Li, Be, Ta, and Nb. FMI microthermometry showed that those melts could have crystallized at 615–550 °C.

Crystallization of quartz–feldspar pegmatite matrix leads to the formation of H₂O-, B- and F-enriched residual melts and associated fluids (prototypes of pockets). Fluids of different compositions and residual melts of different liquidus–solidus P–T-conditions would form pockets with various internal fluid pressures. During crystallization, those melts release more aqueous fluids resulting in a further increase of the fluid pressure in pockets. A significant overpressure and a possible pressure gradient between the neighboring pockets would induce fracturing of pockets and “fluid explosions”. The fracturing commonly results in the crushing of pocket walls, formation of new fractures connecting adjacent pockets, heterogenization and mixing of pocket fluids. Such newly formed fluids would interact with a primary pegmatite matrix along the fractures and cause autometasomatic alteration, recrystallization, leaching and formation of “primary–secondary” pockets.     

预应力锚索技术在大型水库除险加固工程中的应用

介绍了无粘结预应力锚固技术在吉林省二龙山水库除险加固工程中的应用。对造孔、编索、下索、张拉等工艺进行了详细介绍。     

基于宽带网的河南省太阳紫外线强度监测系统研究

使用自主研发的Gstar-Ⅱ型太阳紫外线监测仪,建立基于宽带网的河南省城市紫外线强度监测系统。太阳紫外线强度自动监测站将从紫外线传感器获得的气象要素信息传给本地专用计算机,进行数据处理和编码,然后通过互联网把数据信息送到数据业务中心站,数据业务中心站具有对接收数据进行初步处理和进库的功能;各级气象台站可以很方便地通过宽带Internet网WinSock协议进入数据处理中心,按照自己的要求调用全省紫外线强度历史和实时资料,为本地紫外线预报提供有力的科学依据和手段。     

A study on the focal parameters of Shidian M =5.9 earthquake sequences in 2001

On the basis of about 300 earthquake wave forms observed in the Shidian M _S=5.9 sequences on April 12, 2001 recorded in Kunming Digital Seismic Network, the spectra of shear wave have been used to estimate the focal parameters of these earthquake sequences. The results show that within the magnitude range of 1.5–5.3, the seismic moments are 10¹⁰–10¹⁶ N·m, the corner frequencies are 0.2–0.8 Hz, radii of the focal rupture are 200–2 500 m and the stress drops are 0.1×10⁵–20×10⁵Pa. Through the statistical analyses of variation of corner frequency f _c and stress drop Δσ with time, it is discovered that the average corner frequency of the foreshock sequences is obviously lower than that of the aftershock sequences. Contrarily, the average stress drops Δσ of the foreshock sequences are clearly higher than that of the aftershocks. It is considered that these variation characteristics of average corner frequency and stress drops before and after the main shock have index significance to the precursory information before a strong earthquake. The higher stress drops for the foreshock sequences show that the higher shear stresses have been stored in the area of main shock. After the main shock, most of the stresses have been released, so the aftershock sequences show a rupture process of lower stresses. Foundation item: Scientific and Technological Key Project of Yunnan Province (2001NG46)     

Migrating pingos in the permafrost region of the Tibetan Plateau, China and their hazard along the Golmud–Lhasa railway

Most pingos in the permafrost region of the high northern Tibetan Plateau form along active fault zones and many change position annually along the zones and thus appear to migrate. The fault zones conduct geothermal heat, which thins permafrost, and control cool to hot springs in the region. They maintain ground-water circulation through broken rock in an open system to supply water for pingo growth during the winter in overlying fluvial and lacustrian deposits. Springs remain after the pingos thaw in the summer. Fault movement, earthquakes and man's activities cause the water pathways supplying pingos to shift and consequently the pingos migrate.

The hazard posed to the new Golmud–Lhasa railway across the plateau by migrating pingos is restricted to active fault zones, but is serious, as these zones are common and generate large earthquakes. Pingos have damaged the highway and the oil pipeline adjacent to the railway since 2001. One caused tilting and breaking of a bridge pier and destroyed a highway bridge across the Chumaerhe fault. Another has already caused minor damage to a new railway bridge. Furthermore, the construction of a bridge pier in the North Wuli fault zone in July–August 2003 created a conduit for a new spring, which created a pingo during the following winter. Measures taken to drain the ground-water via a tunnel worked well and prevented damage before the railway tracks were laid. However, pier vibrations from subsequent train motion disrupted the drain and led to new springs, which may induce further pingo growth beneath the bridge.

The migrating pingos result from active fault movement promoting artesian ground-water circulation and changing water pathways under the seasonal temperature variations in the permafrost region. They pose a serious hazard to railway construction, which, in turn can further disturb the ground-water conduits and affect pingo migration.     

桩基筒形翼状钻头的改进设计及应用

针对浙江省温州市世贸中心大厦桩基施工中硬岩钻进时出现的堵管、卡钻和效率低等问题,从所钻地层和钻头的磨损分析出发,提出了钻头的改进设计方案.改进型筒形翼状钻头比原先使用的平底滚刀钻头增加了18个孕镶金刚石-针状硬质合金复合式钻齿和3个钎头,并按受力特点进行了合理分布.实际钻进效果表明改进型钻头应用于超深、大直径钻孔的钻进效率较高、钻进过程平稳.针对钻头的实际磨损情况提出了钻头进一步改进设计的建议.     

复杂条件下深圳汝南大厦基础工程方案的优选与实践

位于复杂地质条件和环境条件下的深圳汝南大厦在基坑支护的施工过程中出现钻进困难,必须重新选择基础工程施工方案.结合场地特殊地质和环境条件在对人工挖孔桩、换填法、树根桩法、旋喷桩复合地基等8种基础工程施工方案进行分析与优选的基础上,借助模糊决策理论进行方法优选验算,最终选定了人工挖孔桩加部分钻(冲)成孔灌注桩的方案.采用该方案在深圳市汝南大厦的施工实践表明其施工效果良好.     

钻孔灌注桩后压浆作用机理与应用

通过对桩侧和桩底后压浆,可大幅度提高钻孔灌注桩单桩承载力.应用桩-土理论分析了后压浆中浆液对土体及桩体的作用,并从分析影响桩基承载力的因素出发,研究了后压浆的作用机理.在渗透率小的地层中后压浆以压密注浆为主,在渗透率大的地层中后压浆以渗透注浆为主.为避免过分压裂土层,在压浆过程中应控制灌浆压力.压浆量是影响后压浆质量和提高单桩承载力的关键因素之一.     

Pristine and reacted surfaces of pyrrhotite and arsenopyrite as studied by X-ray absorption near-edge structure spectroscopy

Fe L-, S L-, and O K-edge X-ray absorption spectra of natural monoclinic and hexagonal pyrrhotites, Fe_1-xS, and arsenopyrite, FeAsS, have been measured and compared with the spectra of minerals oxidized in air and treated in aqueous acidic solutions, as well as with the previous XPS studies. The Fe L-edge X-ray absorption near-edge structure (XANES) of vacuum-cleaved pyrrhotites showed the presence of, aside from high-spin Fe²⁺, small quantity of Fe³⁺, which was higher for a monoclinic mineral. The spectra of the essentially metal-depleted surfaces produced by the non-oxidative and oxidative acidic leaching of pyrrhotites exhibit substantially enhanced contributions of Fe³⁺ and a form of high-spin Fe²⁺ with the energy of the 3d orbitals increased by 0.3–0.8 eV; low-spin Fe²⁺ was not confidently distinguished, owing probably to its rapid oxidation. The changes in the S L-edge spectra reflect the emergence of Fe³⁺ and reduced density of S s–Fe 4s antibonding states. The Fe L-edge XANES of arsenopyrite shows almost unsplit e_g band of singlet Fe²⁺ along with minor contributions attributable to high-spin Fe²⁺ and Fe³⁺. Iron retains the low-spin state in the sulphur-excessive layer formed by the oxidative leaching in 0.4 M ferric chloride and ferric sulphate acidic solutions. The S L-edge XANES of arsenopyrite leached in the ferric chloride, but not ferric sulphate, solution has considerably decreased pre-edge maxima, indicating the lesser admixture of S s states to Fe 3d orbitals in the reacted surface layer. The ferric nitrate treatment produces Fe³⁺ species and sulphur in oxidation state between +2 and +4.