应用单体碳同位素分析技术探析农田土壤中多环芳烃的植物降解过程

长期以来,研究者在探讨土壤中多环芳烃(PAHs)的降解及修复过程中,缺乏简便有效的手段对化合物的降解动态进行定量研究。前人尝试用投加实验、对比采用降解措施前后污染物的浓度变化、模型计算等方法研究PAHs的降解过程,其结果常互相矛盾,或不能真实反映复杂的实际环境。本文应用单体碳同位素技术对农田土壤中多环芳烃的植物降解过程进行定量表征,采集了某地农田表土作为供试土壤,选择玉米作为供试作物,开展了作物对土壤中PAHs降解及消除过程的研究。气相色谱-质谱分析结果表明,培养所用的玉米原始土及分4批收集的空白土、根际土、非根际土样品中16种PAHs的浓度总和(∑PAHs)平均分别为380.8 ng/g、(281.5±34.7) ng/g、(272.2±11.6) ng/g和(299.8±37.9) ng/g;玉米生长期间,各土壤样品 的∑PAHs均比原始土壤有所下降,但除3环化合物(苊烯、苊、芴、菲、蒽)外,其他化合物并未随玉米的生长表现出显著趋势。与玉米根、叶倾向于富集低环PAHs化合物相对应,可以判断植物对土壤中的低环化合物去除作用最为显著。各采样时期玉米根际土、非根际土和空白土壤样品中多环芳烃单体化合物的碳同位素分馏值(δ¹³C)在-34.31‰~-23.95‰之间,且除芘外的其他化合物的δ¹³C值随时间呈现逐步变轻的趋势,波动值位于-0.6‰~-9.0‰之间;本文对于PAHs单体化合物,尤其是4、5环化合物,在玉米降解过程中的碳同位素分馏与浓度变化之间未发现明显关系。考虑3环以下的PAHs化合物更倾向于被降解和清除,且其碳、氢同位素分馏情况更容易被观察到,因此稳定同位素分析更有助于探明该类单体多环芳烃污染物在环境中的迁移、转化规律。     

云南石林世界地质公园阿诗玛石柱碳酸盐岩 显微特征及沉积环境

云南石林世界地质公园阿诗玛石柱,其岩石地层是呈水平产状的中二叠统茅口组厚层块状灰岩,但其构成岩石的具体岩性却未见做过详细工作。笔者等经公园管理部门同意,自下而上分别在阿诗玛石柱背侧底部、下部、中部、上部和顶部共采集样品五块,对其岩石学特征及沉积微相作了详细研究,弄清了这一世界著名景点自下而上的岩石构成及沉积相。底部为高能浅滩相灰色厚层块状具平行层理生屑颗粒灰岩,构成阿诗玛脚部。下部为中能浅潮下灰色厚层块状虫筳生屑泥粒灰岩,构成阿诗玛腿部。中部为中能浅潮下灰色厚层块状砂屑泥粒灰岩,构成阿诗玛腰部。上部为中能浅潮下灰色厚层块状具生物扰动含砂屑生屑泥粒灰岩,构成阿诗玛胸部;顶部为高能浅滩相灰色厚层块状砂屑生屑颗粒灰岩,构成阿诗玛头部。其中含有大量生物化石碎屑:有孔虫、三叶虫、藻类、介形虫、腕足、苔藓虫、虫筳、海百合茎、双壳类,为高能浅滩相和中等能量浅潮下环境。希能为石林形成过程研究和科学普及提供参考。     

Quartz and feldspar zoning in the eastern Erzgebirge volcano-plutonic complex (Germany, Czech Republic): evidence of multiple magma mixing

Zoned quartz and feldspar phenocrysts of the Upper Carboniferous eastern Erzgebirge volcano-plutonic complex were studied by cathodoluminescence and minor and trace element profiling. The results verify the suitability of quartz and feldspar phenocrysts as recorders of differentiation trends, magma mixing and recharge events, and suggest that much heterogeneity in plutonic systems may be overlooked on a whole-rock scale. Multiple resorption surfaces and zones, element concentration steps in zoned quartz (Ti) and feldspar phenocrysts (anorthite content, Ba, Sr), and plagioclase-mantled K-feldspars etc. indicate mixing of silicic magma with a more mafic magma for several magmatic phases of the eastern Erzgebirge volcano-plutonic complex. Generally, feldspar appears to be sensitive to the physicochemical changes of the melt, whereas quartz phenocrysts are more stable and can survive a longer period of evolution and final effusion of silicic magmas. The regional distribution of mixing-compatible textures suggests that magma mingling and mixing was a major process in the evolution of these late-Variscan granites and associated volcanic rocks.

Quartz phenocrysts from 14 magmatic phases of the eastern Erzgebirge volcano-plutonic complex provide information on the relative timing of different mixing processes, storage and recharge, allowing a model for the distribution of magma reservoirs in space and time. At least two levels of magma storage are envisioned: deep reservoirs between 24 and 17 km (the crystallisation level of quartz phenocrysts) and subvolcanic reservoirs between 13 and 6 km. Deflation of the shallow reservoirs during the extrusion of the Teplice rhyolites triggered the formation of the Altenberg-Teplice caldera above the eastern Erzgebirge volcano-plutonic complex. The deep magma reservoir of the Teplice rhyolite also has a genetic relationship to the younger mineralised A-type granites, as indicated by quartz phenocryst populations. The pre-caldera biotite granites and the rhyodacitic Schönfeld volcanic rocks represent temporally and spatially separate magma sources. However, the deep magma reservoir of both is assumed to have been at a depth of 24–17 km. The drastic chemical contrast between the pre-caldera Schönfeld (Westfalian B–C) and the syn-caldera Teplice (Westfalian C–D) volcanic rocks is related to the change from late-orogenic geotectonic environment to post-orogenic faulting, and is considered an important chronostratigraphic marker.     

铀矿山废石堆表面氡析出率的变化规律

铀矿的退役处理是放射性固体废物处理的一个重要领域,研究退役铀矿的放射性水平及其影响因素具有重要的意义。对某矿山的11个废石堆进行表面氡析出率的实地测量,探讨废石堆表面氡析出率的影响变化规律,提出平地堆放型较依山堆放型的析出率高且更不稳定,建立了废石的粒度大小、在堆表面所处的位置和废石中u,Ra的活度与表面氡析出率的相关性,并建立了表面氡析出率与气温、地温、气压、相对湿度、降雨等气象因素的相关规律,为铀矿山退役治理提供理论依据。     

1997年广东台山小震群特征

分析了１９９７年１１～１２月在广东台山市三合镇附近发生的最大震级为４１级小震群的活动特征、地质构造背景和震源机制解,并将其与１９７０年７～１２月发生的最大震级为４０级的台山震群进行了对比,计算了两次小震群的序列特征参数,结果表明,１９９７年震群具有前兆震群的某些特征。     

城市水生态管理问题分析

随着经济社会的发展,济南市水生态系统出现了一系列问题,如泉水景观萎缩、水资源量收支失衡、水环境污染、用水配置不合理等,针对这些水生态环境问题,提出了济南市水生态管理的一系列有效措施: 以地下水作为居民饮用水,合理使用黄河客水与其它地表水;把南部山区— — 地下水补给区建成水源涵养生态功能保护区; 在强污染负荷条件下,利用生态工程技术恢复稳定健康的水生态系统等。      

层状侵入体韵律层理形成过程的定量模拟——以四川攀枝花层状岩体为例

层状侵入体的韵律层理是一种特殊的岩石构造,长期以来其成因倍受关注,成因假说很多。本文在综合这些观点关于岩浆物理,化学性质的研究,尤其是在岩浆房地对流特征研究成果的基础上,提出了新的成因解释,认为固化带前锋处矿物的结晶,熔浆组分的扩散及固化带前锋本身的推进等３个因素的相互耦合是形成韵律层理的主要机制,这个过程是发生在一定过冷却条件下的,在这种定性认识基础上,笔者提出了旨在对韵律层理形成过程进行模拟计     

点苍山-哀牢山变质杂岩带变沉积岩的变质演化

点苍山-哀牢山变质杂岩带位于青藏高原东南缘大理-元江-元阳-河口一带,出露规模达数百千米,是扬子板块和印支陆块之间的一条重要构造带.该变质杂岩带主要由各类正片麻岩、副片麻岩、大理岩所组成,夹有斜长角闪岩、石榴辉石岩和超镁铁质岩石的透镜体或团块.其中,变沉积岩如含夕线石和蓝晶石的片麻岩类岩石保存了多阶段的矿物组合及异常复杂的矿物相转变关系.详细的岩相学、成因矿物学以及矿物相转变关系分析表明,变沉积岩系经历了早期进变质阶段(M1)、峰期角闪-麻粒岩相变质阶段(M2)、峰后近等温减压(脱水熔融)阶段(M3)以及晚期退变质阶段(M4)的变质演化.其中,M1阶段的稳定矿物组合为石榴石+斜长石+白云母+石英+十字石±蓝晶石±黑云母±钾长石,M2阶段的稳定矿物组合为石榴石+黑云母+蓝晶石/夕线石+斜长石+石英、石榴石+黑云母+斜长石+石英±钾长石±夕线石,M3阶段的共生矿物组合为石榴石+黑云母+夕线石+斜长石+石英,M4阶段的矿物组合为黑云母+白云母+斜长石+石英±钾长石±石榴石等.通过传统GB-GASP温压计和二云母温度计的估算结果,配合P-T视剖面定量计算,确定早期进变质阶段(M1)的温压条件为T=560 ～ 590℃,P=5.5 ～6.3kb,峰期角闪-麻粒岩相阶段(M2)的温压条件为T=720～ 760℃、P=8.0～9.3kb,峰后近等温减压阶段(M3)的温度压力条件为T=640～760℃,P=5.0～7.3kb,晚期退变阶段(M4)的温压条件为T=521～648℃,P=4.0～5.0kb.上述研究结果表明,点苍山-哀牢山变沉积岩记录了典型碰撞造山带型式的顺时针P-T演化轨迹,表明点苍山-哀牢山变质杂岩带的形成与印度板块和欧亚板块之间的俯冲-碰撞存在密切的成因关系.     

The changes of vegetation cover in Ejina Oasis based on water resources redistribution in Heihe River

The Ejina Oasis (EO), located in arid northwest China, is a typical arid area in the world. The ecosystem in the oasis has become worse since the 1990s. However, it began to improve after the Chinese government took the mandatory measure to redistribute the water in Heihe in 2000. To understand this change, the remote sensing images in 1990, 2000 and 2006 were selected, and exertion related Land Use/Cover Change (LUCC) model was employed. Results showed that: (1) non-vegetation cover was the main body of the vegetation cover in oasis, showing a trend of increase at the beginning and diminution later, while low, medium and high vegetation cover was the other way around; (2) the area of low, medium and high vegetation cover in 2006 was less than that in 1990; the status and trend index P _t of oasis vegetation cover was 0.62 in 1990–2000, which means that the oasis ecosystem of Ejina was getting worse and was under an unbalanced status; P _t was 0.27 in 2000–2006 indicating that the oasis ecosystem was restored obviously and the whole system tended to be balanced; (3) all of these changes should be attributed to the water resources redistribution in Heihe River, which played a leading role, as well as the measures and relevant policies taken by the local government, which promoted the rapid recovery of the medium and high vegetation.