Palaeopedological marker horizons in northern central Europe: characteristics of Lateglacial Usselo and Finow soils

Lateglacial buried soil horizons, which occur widely in sandy aeolian sequences of northern central Europe, were analysed in order to evaluate their regional pedostratigraphical and palaeoenvironmental potential. Data on stratigraphy, sedimentology, pedology, geochronology and palaeobotany from 29 palaeosol-bearing profiles at terrestrial sites are presented. Greyish Ahb and Eb horizons occur, as well as brownish Bwb and BwAhb horizons. They are 5–30 cm thick, showing similar pedological properties except colour, and they frequently bear charcoal typically from pine. Soil classification results in Albic Arenosols (Dystric) and Brunic Arenosols (Dystric) representing palaeosols of the Usselo and Finow types, respectively. Radiocarbon dating of the palaeosols reveals a dominance of Allerød ages followed by Younger Dryas and Preboreal ages. Most luminescence ages on overlying aeolian sands date into the Allerød–Younger Dryas interval. Mapping of all Usselo and Finow soil occurrences ( n =96) in northern central Europe known so far reveals a nearly closed Finow soil province between Usselo soil areas in NW Germany and central Poland, mainly situated in NE Germany. Most Usselo soils compiled contain charcoal, indicating widespread and repeated fires. Recent claims that the Usselo soil represents an event layer from rapid aeolian sedimentation caused by an extraterrestrial impact is rejected. Instead, both Usselo and Finow soils can be assumed to be pedostratigraphical marker horizons in northern central Europe and beyond.     

Propagation and source of Pc5 frequency range pulsation at cusp latitude

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Recommendations for the processing and storage of water samples before polymerase chain reaction (PCR) analysis

A range of options for the storage and partial processing of water samples before polymerase chain reaction (PCR) analysis were evaluated. In addition, temporal storage of extracted DNA at 4 °C was investigated. Filtering the water sample and then storing that filter at ?20 °C for up to six months before DNA extraction was equivalent to extracting DNA immediately. Freezing a water sample resulted in an immediate 1 log loss of PCR signal, although thereafter the sample was stable for at least three months. A rapid loss of detectable PCR product was found when storing a water sample at 4 °C for longer than one week. Extracted DNA could be stored at 4 °C for at least six months without considerable loss of PCR signal.     

Faecal indicators and pathogens in selected New Zealand waterfowl

Freshly excreted droppings from Canada geese (n=80), black swans (n=80), ducks (n=80) and gulls (n=80) were collected from sites around New Zealand. The droppings were enumerated for Escherichia coli, enterococci and Salmonella spp., and for the presence/absence of Cryptosporidium spp. Overall prevalence of E. coli and enterococci in samples was 95% and 94%, respectively. Cryptosporidium spp. was detected in 2% of the samples, whereas no Salmonella spp. were detected in the survey. Preliminary estimates of daily microbial outputs suggest that ducks will produce the highest loadings of E. coli and enterococci per bird, whereas Canada geese will produce the highest loadings of Campylobacter spp. per bird. This study provides the first set of indicator and pathogen counts for one of the largest sources of diffuse faecal contamination of natural waters in New Zealand.     

Late Weichselian sea level changes at Sotra, Hordaland, western Norway

Sediments from twenty-eight basins were surveyed; ten of these basins with a representative lithostrati-gfaphy wee studied to determine their isolation from the sea during Late Weichselian. Diatom analysis was used to determine salinity changes, which were dated by pollen analysis and the radiocarbon method. The area was deglaciated in the early Boiling, and a regression of about 5 m followed. A transgression of more than 10 m started in late Boiling and terminated in middle Younger Dryas, with a transgression maximum between 38.2 and 40 m above present sea level. All the investigated basins were finally isolated in late Younger Dryas/early Preboreal, during a rapid regression. Repeated cycles of chinophilous/ chinophobous plant communities in the area reflect climatic changes in the period. No evidence of an Older Dryas ice readvance was found.     

Melting of a Hydrous Mantle: III. Phase Relations of Garnet Websterite+H2O at High Pressures and Temperatures

A garnet websterite nodule from the Honolulu volcanic series,Oahu, Hawaii, has been melted in the presence of nearly pureH₂O. The solidus is intermediate between that of peridotiteand gabbro. The curve displays a temperature minimum around20 kb reflecting the breakdown of plagioclase. The Iiquidusis between 1130 ?C and 1150 ?C between 10 and 20 kb vapor pressure.Amphibole (pargasitic hornblende) has an extensive stabilityfield, reaching a maximum temperature about 20 ?C below thegarnet websterite liquidus at 15 kb and a maximum pressure of27.5 kb at 950 ?C. The amphibole-out curve intersects the soliduswith a positive slope. Liquids formed by partial melting of garnet websterite are quartz-normativewithin the stability field of amphibole, but become olivine-normative(tholeiitic) with increasing temperature. Amphibole and clinopyroxeneare enriched in Tschermak's molecule at higher temperatures,pargasite content of amphibole increases with increasing pressure. A garnet websterite-rich upper mantle containing modal olivineyields quartz-normative (13–16 per cent), aluminous (21–4wt. per cent A1₂O₃) melts at 17 P 10 kb and in the presenceof nearly pure H₂O. However, the presence of amphibole controlsthe liquid composition, a situation not found for liquids formedfrom wet peridotite. In contrast to many basalt liquids, liquidof garnet websterite composition cannot fractionate to andesiteby precipitation of amphibole, as amphibole is not a liquidusphase.     

The genesis of nodular limestones in the Ordovician and Silurian of the Oslo Region (Norway)

Nodular limestones have been studied from the Lower Chasmops Shale (Middle Ordovician) and the Rytteráker Formation (Lower Silurian). Observations on nodule-host-rock relations and variations of ferroan/non-ferroan calcite cements help explain the role of precipitation, dissolution and redistribution of carbonate. Distribution and frequency of nodules depends on environmental parameters such as carbonate/clay ratio, grain size distribution and bioturbation, though final shapes are the result of pressure-dissolution and cleavage.     

Fluid flow in sedimentary basins: model of pore water flow in a vertical fracture

Open fractures provide high-permeability pathways for fluid flow in sedimentary basins. The potential for flow along permeable or open fractures and faults depends on the continuity of flow all the way to the surface except in the case of convective flow. Upward flowing fluid cools and may cause cementation due to the prograde solubility of quartz, but in the case of carbonates such flow may cause dissolution. The rate and duration of these processes depend on the mechanisms for sustaining fluid flow into the fracture, the geometries of fracture and sedimentary beds intersected, permeability, pressure and temperature gradients. Heat loss to the adjacent sediments causes sloping isotherms which can induce non-Rayleigh convection. To analyse these problems we have used a simple model in which a single fracture acts as a pathway for vertically moving fluid and there is no fluid transport across the walls of the fracture except near its inlet and outlet. Four mechanisms for fluid flow into the lower part of the fracture are considered: decompression of pore water; compaction of intersected overpressared sediments; focusing of compaction water derived from sediments beneath the fracture; and finally focusing of pore water moving through an aquifer. Water derived from the basement is not considered here. We find that sustained flow is unlikely to have velocities much higher than 1–100 m/yr, and the flow is laminar. The temperature of the fluid expelled at the top of the fracture increases by less than 1% and the vertical temperature gradient in the fracture remains close to the geothermal gradient. Where hot water is introduced from basement fractures (hydrothermal water) during tectonic deformation, much higher velocities may be sustained in the overlying sediments, but here also this depends on the permeability near the surface. Most of the cooling of water with (ore) mineral precipitation will then occur near the surface. In most cases, pore water decompression and sediment compaction will yield only very limited pore water flux with no significant potential for cementation or heating of the sediments adjacent to the fracture. Focusing of compaction water from sediments beneath the fracture or from an intersected aquifer can yield fluxes high enough to cement an open fracture significantly but the flow must be sustained for a very long time. For velocities of 1–100 m/yr, it takes typically 0.3–30 Myr to cement a fracture by 50%. The highest velocities may be obtained when a fracture extends all the way to the surface or sea floor. When a fracture does not reach the sediment surface, the flow velocity is reduced by the displacement of water in the sediments near the top of the fracture. The flow into the fracture from the sediments may often be rate limiting rather than the flow on the fracture. Sedimentary rocks only a few metres from the fracture will receive a much lower flux than the fracture. The fracture will therefore close due to cementation before significant amounts of silica can be introduced into adjacent sandstones. The isotherm slope in the adjacent sediments will in most cases be less than 10–20°. Non-Rayleigh convection velocities in the sediments adjacent to the fracture are too small to cause any significant diagenetic reactions such as quartz cementation. These quantifications of fluid flow in fractures in sedimentary basins are important in terms of constraining models for diagenesis, heat transport and formation of ore minerals in a compaction-driven system.