Field Measurement of Suction, Water Content, and Water Permeability

This paper presents a review of techniques for field measurement of suction, water content, and water hydraulic conductivity (permeability). Main problems in the use of field tensiometers are addressed and hints on how to improve tensiometer performance are given. Advantages and limitations of instruments for indirect measurement of suction including electrical conductivity sensors, thermal conductivity sensors, dielectric permittivity sensors, filter paper, and psychrometer are discussed. Techniques for water content measurement based on dielectric methods are then presented. These include time and amplitude domain reflectometry and capacitance. Finally, a brief overview of methods for measurement of water permeability in the field is presented.     

Influence of the natural organic matter in the removal of caffeine from water by fixed-bed column adsorption

The removal of caffeine from tap water by F-400 granular activated carbon in fixed-bed adsorption experiments was carried out. Textural and chemical characterization of the adsorbent through N₂ adsorption–desorption isotherms, Fourier transform infrared spectrometry, isoelectric point determination and scanning electron microscopy studies was developed in studies previously reported. Caffeine breakthrough curves and total organic carbon profiles at different operation conditions (inlet concentration, volumetric flow rate and mass of adsorbent) were obtained. These experimental results showed a displacement of the natural organic matter from the active sites exerted by caffeine molecules due to their higher affinity to the surface carbon. This behavior led to an overshooting, a local outlet natural organic matter concentration higher than the feed quantity. A competitive effect seems to be observed in the removal of the target compound, decreasing the efficiency of the process. Axial dispersion coefficients and dimensionless numbers were estimated for the caffeine removal onto F-400 activated carbon. Therefore, the regeneration of the adsorbent by adsorption–desorption cycles was studied.     

Evaluating rock mass geometry from photographic images

Summary The importance of discontinuities in controlling rock mass behaviour in any engineering project involving excavations calls for a sound and spatial characterization of the discontinuity structure present. Such a characterization necessitates field work that requires sufficient rock exposures in order to obtain an adequate number of data, time and considerable cost. Photoanalysis techniques can help in overcoming the above difficulties equally well or better than other techniques. This paper refers to simple photographic techniques and their implementation for computer aided analyses for the characterization of the rock mass fracturing features. In particular attention is focused on scale problems and on reconstruction of fracture density stereoplots on the basis of data collected from one or two images according to different lithologies and outcropping conditions. The methodology for evaluating the volumetric fracture intensity follows in a slightly modified way a technique previously suggested in the literature. Certain reported examples allow to validate the photoanalytical technique used and the proposed method of analysis. Furthermore, analyses on planar density, spacing, frequency, terminations in solid rock or against other discontinuities and spatial correlation have been implemented in a software to yield a more complete rock mass characterization. At the same time input data and analysis results are produced in data files available as input for numerical analyses.     

Reference Samples of Rocks - The Search for "Best Values"

Because of the disparate data, reported in collaborative analyses of reference samples of rooks, various methods have been proposed for deriving "best values". This work compares those methods and several additional ones. Included are two simplified estimates of "mode" which yield values close to those of the Dominant Cluster and Gamma Transformation methods. An example is also cited of the hazards that may result from too superficial reading of raw data.     

The atmospheric tide as a continuous spectrum: Lunar semidiurnal tide in surface pressure

Summary The standard equations for the theory of atmospheric tides are solved here by an integral representation on the continuous spectrum of free oscillations. The model profile of back-ground temperature is that of the U.S. Standard Atmosphere in the lower and middle atmosphere, and in the lower thermosphere, above which an isothermal top extends to arbitrarily great heights. The top is warm enough to bring both the Lamb and the Pekeris modes into the continuous spectrum.Computations are made for semidiurnal lunar tidal pressure at sea level at the equator, and the contributions are partitioned according to vertical as well as horizontal structure. Almost all the response is taken up by the Lamb and Pekeris modes of the slowest westward-propagating gravity wave. At sea level, the Lamb-mode response is direct and is relatively insensitive to details of the temperature profile. The Pekeris mode at sea level has an indirect response-in competition with the Lamb mode-and, as has been known since the time of its discovery, it is quite sensitive to the temperature profile, in particular to stratopause temperature. In the standard atmosphere the Lamb mode contributes about +0.078 mb to tidal surface pressure at the equator and the Pekeris mode about –0.048 mb.The aim of this investigation is to illustrate some consequences of representing the tide in terms of the structures of free oscillations. To simplify that task as much as possible, all modifying influences were omitted, such as background wind and ocean or earth tide. Perhaps the main defect of this paper's implementation of the free-oscillation spectrum is that, in contrast to the conventional expansion in the structures of forced oscillations, it does not include dissipation, either implicity or explicity, and thus does not satisfy causality. Dissipation could be added implicity by means of an impedance condition, for example, which would cause up-going energy flux to exceed downgoing flux at the base of the isothermal top layer. To achieve complete causality, however, the dissipation must be modeled explicity. Nevertheless, since the Lamb and Pekeris modes are strongly trapped in the lower and middle atmosphere, where dissipation is rather weak (except possibly in the surface boundary layer), more realistic modeling is not likely to change the broad features of the present results.Symbols a earth's mean radius; expansion coefficient in (5.3) - b recursion variable in (7.4); proximity to resonance in (9.2) - c sound speed in (2.2); specific heatc _p in (2.2) - f Coriolis parameter 2sin in (2.2) - g standard surface gravity - h equivalent depth - i ; discretization index in (7.3) - j index for horizontal structure - k index for horizontal structure; upward unit vectork in (2.2) - m wave number in longitude - n spherical-harmonic degree; number of grid layers in a model layer - p tidal pressure perturbation; background pressurep ₀ - q heating function (energy per mass per time) - r tidal state vector in (2.1) - s tidal entropy perturbation; background entropys ₀ - t time - u tidal horizontal velocityu - w tidal vertical component of velocity - x excitation vector defined in (2.3); vertical coordinate lnp _*/p ₀ [except in (3.8), where it is lnp /p ₀] - y vertical-structure function in (7.1) - z geopotential height - A constant defined in (6.2) - C spherical-harmonic expansion coefficient in (3.6) - D vertical cross section defined in (5.6) and (5.9) - E eigenstate vector - F vertical-structure function for eigenstate pressure in (3.2) [re-defined with WKB scaling in (7.2)] - G vertical-structure function for eigenstate vertical velocity in (3.2) [re-defined with WKB scaling in (7.2)] - H pressure-scale height - I mode intensity defined in (8.1) - K quadratic form defined in (4.4) - L quadratic form defined in (4.4); horizontal-structure magnification factor defined in (5.11) - M vertical-structure magnification factor defined in (4.6) - P eigenstate pressure in (3.2); tidal pressure in (6.2) - R tidal state vector in (5.1) - S eigenstate entropy in (3.2); spherical surface area, in differential dS - T background molecular-scale (NOAA, 1976) absolute temperatureT ₀ - U eigenstate horizontal velocityU in (3.2); coefficient in (7.3) - V horizontal-structure functionV for eigenstate horizontal velocity in (3.2); recursion variable in (7.3) - W eigenstate vertical velocity in (3.2) - X excitation vector in (5.1) - Y surface spherical harmonic in (3.7) - Z Hough function defined in (3.6) - +dH/dz - (1––)/2 - Kronecker delta; Dirac delta; correction operator in (7.6) - equilibrium tide elevation - (square-root of Hough-function eigenvalue) - ratio of specific gas constant to specific heat for air=2/7 - longitude - - - background density ₀ - eigenstate frequency in (3.1) - proxy for heating functionq =c _P/t - latitude - tide frequency - operator for the limitz - horizontal-structure function for eigenstate pressure in (3.2) - Hough function defined in (6.2) - earth's rotation speed - horizontal gradient operator - ()₀ background variable - ()_* surface value of background variable - () value at base of isothermal top layer - Õ state vector with zerow-component - , energy product defined in (2.4) - | | energy norm - ()^* complex conjugate With 10 Figures     

Measurement of DNA single-strand breaks in gill and hemolymph cells of mussels, Mytilus sp., collected on the French Atlantic Coast

DNA single-strand breaks were measured by the comet assay in both gill and hemolymph cells of mussels collected in 3 sampling areas of the French coast (Pointe du Castelli, Pen Bron and Saint-Nazaire Harbour). Whole mussel tissue samples were also collected for the chemical determination of PAH, PCB and heavy metal concentrations. In mussel, a higher level of DNA strand breaks was measured in gill than in hemolymph cells (p < 0.01). Despite a factor of contamination from 2 to 3 between sites, no difference in the extent of mussel DNA strand breaks was shown between sampling locations (p > 0.05), questioning the sensitivity of the assays used in biomonitoring studies.     

Variations of antioxidant efficiency and presence of endosymbiotic diatoms in the Antarctic porifera Haliclona dancoi

The role of endosymbiotic diatoms as pro-oxidant stressors in porifera has been investigated in the Antarctic sponge Haliclona dancoi in which the presence of diatoms is influenced by marked seasonal variations during the austral summer. Both chlorophaeopigments and frustules were absent in sponge tissues sampled in early November at the beginning of the summer and increased from the mid of December with slightly shifted temporal trends. The efficiency of antioxidant defenses in the sponge showed a marked response to symbionts with clearly enhanced values corresponding to the peak of diatoms.