Characterization of carbon monoxide,methane and nonmethane hydrocarbons in emerging cities of Saudi Arabia and Pakistan and in Singapore

We investigate the composition of 63 C₂-C₁₀ nonmethane hydrocarbons (NMHCs), methane (CH₄) and carbon monoxide (CO), in Jeddah, Mecca, and Madina (Saudi Arabia), in Lahore, (Pakistan), and in Singapore. We established a database with which to compare and contrast NMHCs in regions where ambient levels and emissions are poorly characterized, but where conditions are favorable to the formation of tropospheric ozone, and where measurements are essential for improving emission inventories and modeling. This dataset will also serve as a base for further analysis of air pollution in Western Saudi Arabia including, but not limited to, the estimation of urban emissions and long range pollution transport from these regions. The measured species showed enhanced levels in all Saudi Arabian cities compared to the local background but were generally much lower than in Lahore. In Madina, vehicle exhaust was the dominant NMHC source, as indicated by enhanced levels of combustion products and by the good correlation between NMHCs and CO, while in Jeddah and Mecca a combination of sources needs to be considered. Very high NMHC levels were measured in Lahore, and elevated levels of CH₄ in Lahore were attributed to natural gas. When we compared our results with 2010 emissions from the MACCity global inventory, we found discrepancies in the relative contribution of NMHCs between the measurements and the inventory. In all cities, alkenes (especially ethene and propene) dominated the hydroxyl radical (OH) reactivity (k _OH) because of their great abundance and their relatively fast reaction rates with OH.     

Application of infrared thermography for temperature distributions in fluid-saturated porous media

Infrared thermography has increasingly gained importance because of environmental and technological advancements of this method and is applied in a variety of disciplines related to non-isothermal flow. However, it has not been used so far for quantitative thermal analysis in saturated porous media. This article suggests infrared thermographic approach to obtain the entire surface temperature distribution(s) in water-saturated porous media. For this purpose, infrared thermal analysis is applied with in situ calibration for a better understanding of the heat transfer processes in porous media. Calibration is achieved with a combination of invasive sensors which are inserted into the medium and non-invasive thermal sensors in which sensors are not inserted to measure temperatures but it works through the detection of infrared radiation emitted from the surface. Thermocouples of relatively thin diameter are used to minimize the disturbance for flow. Thermocouples give the temperature values at specified positions inside the porous medium, and these values are compared with the values suggested by the infrared thermographic device at the same positions, in the calibration exercise. The calibration process was repeated for different temperatures and flow rates to get the temperature distributions of the whole material inside the system. This technique enables us to measure accurate two-dimensional temperature distributions, which is not possible by using thermocouples only. Continuous point heat sources at different flow rates and temperatures are studied experimentally. Additionally, it offers numerical simulations of the experiments utilizing a finite element-based model. A two-dimensional density and viscosity-dependent flow and transport model accounting for thermal dispersion is utilized to simulate the experimental results. Possible small heat losses from the surface are incorporated in the model according to the properties and thickness of the Plexiglass material used for the construction of the experiment tank. The numerical results agree well with the experimental observations.     

Lunar concrete: Prospects and challenges

The possibility of using concrete as a construction material at the Moon surface is considered. Dissimilarities between the Earth and the Moon and their possible effects on concrete are also emphasized. Availability of constituent materials for concrete at lunar surface is addressed. An emphasis is given to two types of materials, namely, hydraulic concrete and sulfur concrete. Hydraulic concrete necessitates the use of water and sulfur concrete makes use of molten sulfur in lieu of cement and water.     

Climate change during the Triassic and Jurassic

The transition from the Triassic to Jurassic is associated with dramatic changes in Earth's climate. Pangaea was breaking up as North America rifted away from Africa, the Central Atlantic Magmatic Province erupted, and the concentration of atmospheric carbon dioxide increased dramatically. This article summarises the changes in Earth's climate associated with this transition, including a discussion of the various impacts of the increased carbon dioxide on the Earth system, the question of whether the wet episode in the Carnian was a global or regional event, the formation of bauxite deposits, and how dinosaur distributions changed over time. Palaeoclimate model simulations reveal the spatial changes in climate between the Triassic and Jurassic, illustrating the subtropics becoming slightly cooler and wetter despite the warming trend for the Earth's average temperature.     

Effect of climate change on overland flow generation: a case study in central Germany

The impact of global climate change on runoff components, especially on the type of overland flow, is of utmost significance. High‐resolution temporal rainfall plays an important role in determining the hydrological response of quick runoff components. However, hydrological climate change scenario analyses with high temporal resolution are rare. This study investigates the impact of climate change on discharge peak events generated by rainfall, snowmelt, and soil‐frost induced runoff using high‐resolution hydrological modelling. The study area is Schäfertal catchment (1.44 km²) in the lower Harz Mountains in central Germany. The WaSiM‐ETH hydrological model is used to investigate the rainfall response of runoff components under near future (2021–2050) and far‐distant future (2071–2100) climatic conditions. Disaggregated daily climate variables of WETTREG2010 SRES scenario A1B are used on a temporal resolution of 10 min. Hydrological model parameter optimization and uncertainty analysis was conducted using the Differential Evolution Adaptive Metropolis (DREAM_(ZS)) uncertainty tool. The scenario results show that total runoff and interflow will increase by 3.8% and 3.5% in the near future and decrease by 32.85% and 31% in the far‐distant future compared to the baseline scenario. In contrast, overland flow and the number and size of peak runoff will decrease moderately for the near future and drastically for the far‐distant future compared to the baseline scenario. We found the strongest decrease for soil‐frost induced discharge peaks at 79.6% in the near future and at 98.2% in the far‐distant future scenario. It can be concluded that high‐resolution hydrological modelling can provide detailed predictions of future hydrological regimes and discharge peak events of the catchment. Copyright © 2014 John Wiley & Sons, Ltd.