Formation rates of Subantarctic mode water and Antarctic intermediate water within the South Pacific

The formation of Subantarctic Mode Water (SAMW) and Antarctic Intermediate Water (AAIW) significantly contributes to the total uptake and storage of anthropogenic gases, such as CO₂ and chlorofluorocarbons (CFCs), within the world's oceans. SAMW and AAIW formation rates in the South Pacific are quantified based on CFC-12 inventories using hydrographic data from WOCE, CLIVAR, and data collected in the austral winter of 2005. This study documents the first wintertime observations of CFC-11 and CFC-12 saturations with respect to the 2005 atmosphere in the formation region of the southeast Pacific for SAMW and AAIW. SAMW is 94% and 95% saturated for CFC-11 and CFC-12, respectively, and AAIW is 60% saturated for both CFC-11 and CFC-12. SAMW is defined from the Subantarctic Front to the equator between potential densities 26.80-27.06 kg m⁻³, and AAIW is defined from the Polar Front to 20°N between potential densities 27.06-27.40 kg m⁻³. CFC-12 inventories are 16.0×10⁶ moles for SAMW and 8.7×10⁶ moles for AAIW, corresponding to formation rates of 7.3±2.1 Sv for SAMW and 5.8±1.7 Sv for AAIW circulating within the South Pacific. Inter-ocean transports of SAMW from the South Pacific to the South Atlantic are estimated to be 4.4±0.6 Sv. Thus, the total formation of SAMW in the South Pacific is approximately 11.7±2.2 Sv. These formation rates represent the average formation rates over the major period of CFC input, from 1970 to 2005. The CFC-12 inventory maps provide direct evidence for two areas of formation of SAMW, one in the southeast Pacific and one in the central Pacific. Furthermore, eddies in the central Pacific containing high CFC concentrations may contribute to SAMW and to a lesser extent AAIW formation. These CFC-derived rates provide a baseline with which to compare past and future formation rates of SAMW and AAIW.     

Controlling factors of the δ 11B-pH proxy and its research direction

Significant boron isotope fractionation occurs in nature (?70 ‰ to +75 ‰) due to the high geochemical reactivity of boron and the large relative mass difference between ¹⁰B and ¹¹B. Since the 1990s, reconstruction of ancient seawater pH using the isotopic composition of boron in bio-carbonates (δ ¹¹B_carb), and then calculation of the past pCO₂ have become important issues for the international isotope geochemistry community, and are called the δ ¹¹B-pH proxy. Although many achievements have been made by this proxy, various aspects of boron systematics require rigorous evaluation. Based on the previous researches, mechanism of boron isotope fractionation, variation of boron isotope (δ ¹¹B) in nature (especially in bio-carbonates) and controlling factors of the δ ¹¹B-pH proxy, such as the dissociation constant of B(OH)₃ in seawater (pK_a), the δ ¹¹B of seawater (δ ¹¹B_SW), the boron isotopic fractionation factor between B(OH) ₄ ^? and B(OH)₃ (α _4–3), and the incorporated species of boron into bio-carbonates, are reviewed in detail and the research directions of this proxy are proposed. Generally, the controversy about pK_a, δ ¹¹B_sw, and α _4–3 is relatively less, but whether boron incorporated into bio-carbonates only in the form of B(OH) ₄ ^? remains doubtful. In the future, it is required that the physicochemical processes that control boron incorporation into carbonates be rigorously characterized and that the related chemical and isotopic fractionation be quantified. It is also necessary and important to establish a “best-fit empirically equation” between δ ¹¹B_carb and pH of seawater based on the precipitation experiments of inorganic or culture experiments of corals or foraminifera. In addition, extended application of the δ ¹¹B-pH proxy to the earlier part of the Phanerozoic relying on the Brachiopods is worthy of studying. Like other geochemical indicators, there are limiting factors of δ ¹¹B; however, it remains a very powerful tool in the reconstruction of past seawater pH at present.     

Evaluation of significant sources influencing the variation of physico-chemical parameters in Port Blair Bay,South Andaman,India by using multivariate statistics

Port Blair is the capital city of Andaman & Nicobar Islands, the union territory of India. More than 50% of the population of these islands lives around Port Blair Bay. Therefore the anthropogenic effects in the bay water were studied for monitoring purpose from seven stations. Physico-chemical parameters of seawater were analyzed in samples collected once in every 3 months for 2 years from seven sampling stations located in Port Blair Bay, South Andaman Island to evaluate the spatial and tidal variation. Cluster analysis and factor analysis were applied to the experimental data in an attempt to understand the sources of variation of physico-chemical parameters. In cluster analysis, the stations Junglighat Bay and Phoenix Bay having high anthropogenic influence formed a separate group. The factors obtained from factor analysis indicated that the parameters responsible for physico-chemical variations are mainly related to land run-off, sewage outfall and tidal flow.     

Space Weather: Physics,Effects and Predictability

The time varying conditions in the near-Earth space environment that may affect space-borne or ground-based technological systems and may endanger human health or life are referred to as space weather. Space weather effects arise from the dynamic and highly variable conditions in the geospace environment starting from explosive events on the Sun (solar flares), Coronal Mass Ejections near the Sun in the interplanetary medium, and various energetic effects in the magnetosphere–ionosphere–atmosphere system. As the utilization of space has become part of our everyday lives, and as our lives have become increasingly dependent on technological systems vulnerable to the space weather influences, the understanding and prediction of hazards posed by these active solar events have grown in importance. In this paper, we review the processes of the Sun–Earth interactions, the dynamic conditions within the magnetosphere, and the predictability of space weather effects on radio waves, satellites and ground-based technological systems today.     

Fields as a framework for integrating GIS and environmental process models. Part 1: Representing spatial continuity

Linking a GIS to a spatially distributed, physically-based environmental model offers many advantages. However, the implementation of such linkages is generally problematic. Many problems arise because the relationship between the reality being represented by the mathematical model and the data model used to organize the spatial data in the GIS has not been rigorously defined. In particular, while many environmental models are based on theories that assume continuity and incorporate physical fields as independent variables, current GISs can only represent continuous phenomena in a variety of discrete data models. This paper outlines a strategy in which field variables are used to enable modellers to work directly with the spatial data as spatially continuous phenomena. This allows the manner in which the spatial data has been discretized and the ways in which it can be manipulated to be treated independently from the conceptual modelling of physical processes. Modellers can express their spatial data needs as representations of reality, rather than as elements of a GIS database, and a GIS-independent language for model development may result. By providing a formal linkage between the various models of spatial phenomena, a mechanism is created for the explicit expression of transformation rules between the different spatial data models stored and manipulated by a GIS.     

Studying the Deep Structure of Elbrus Volcano by Microseismic Sounding

This paper presents results from a study of the deep structure of the Elbrus edifice and adjacent areas using geophysical techniques. We confirmed the existence of a shallow magma chamber, derived a more accurate location of the chamber in the host rocks and its characteristic dimensions, and compared new results with known studies. More accurate estimates have been obtained for the temperature at the top of the magma chamber and new evidence is adduced concerning the deep structure of the fluid magmatic systems in the Elbrus volcanic area.     

Variation in Coronal Activity from Solar Cycle 24 Minimum to Maximum Using Three-Dimensional Reconstructions of the Coronal Electron Density from STEREO/COR1

Three-dimensional electron density distributions in the solar corona are reconstructed for 100 Carrington rotations (CR 2054?–?2153) during 2007/03?–?2014/08 using the spherically symmetric method from polarized white-light observations with the inner coronagraph (COR1) onboard the twin Solar Terrestrial Relations Observatory (STEREO). These three-dimensional electron density distributions are validated by comparison with similar density models derived using other methods such as tomography and a magnetohydrodynamics (MHD) model as well as using data from the Solar and Heliospheric Observatory (SOHO)/Large Angle and Spectrometric Coronagraph (LASCO)-C2. Uncertainties in the estimated total mass of the global corona are analyzed based on differences between the density distributions for COR1-A and -B. Long-term variations of coronal activity in terms of the global and hemispheric average electron densities (equivalent to the total coronal mass) reveal a hemispheric asymmetry during the rising phase of Solar Cycle 24, with the northern hemisphere leading the southern hemisphere by a phase shift of 7?–?9 months. Using 14 CR (\(\approx13\)-month) running averages, the amplitudes of the variation in average electron density between Cycle 24 maximum and Cycle 23/24 minimum (called the modulation factors) are found to be in the range of 1.6?–?4.3. These modulation factors are latitudinally dependent, being largest in polar regions and smallest in the equatorial region. These modulation factors also show a hemispheric asymmetry: they are somewhat larger in the southern hemisphere. The wavelet analysis shows that the short-term quasi-periodic oscillations during the rising and maximum phases of Cycle 24 have a dominant period of 7?–?8 months. In addition, it is found that the radial distribution of the mean electron density for streamers at Cycle 24 maximum is only slightly larger (by \(\approx30\%\)) than at cycle minimum.     

Occurrence and Distribution of Organic Contaminants in the Aquatic System in Berlin.Part II: Substituted Phenols in Berlin Surface Water

In a surface water screening, 30 representative surface water samples collected from rivers, canals, and lakes in Berlin were investigated for the presence of 22 substituted phenols. The phenols selected include the 11 phenols considered as “priority pollutants” by the US Environmental Protection Agency (US-EPA). Surface water samples were extracted applying solid-phase extraction with styrenedivinylbenzene adsorbent. The recoveries, determined in spiking experiments, were between 80 % and 103 %. After derivatization with N-(tert-butyldimethylsilyl)-N-methyl-trifluoroacetamide (MTBSTFA) the samples were analyzed by capillary gas chromatography-mass spectrometry (GC-MS). Phenol, cresols, 2-ethylphenol, 2-chlorophenol, 4-chloro-3-methylphenol, pentachlorophenol, 2-nitrophenol, and 4-nitrophenol were detected in the surface water samples at concentrations between 0.02 μg/L and 7.8 μg/L, respectively. The distribution of these residues in the Berlin surface waters showed that the phenolic residues, with the exception of pentachlorophenol and 2-ethylphenol, do not originate primarily from municipal sewage treatment plants discharges. Some of the phenols are formed naturally or occur as ubiquitous anthropogenic contaminants in the aquatic system.     

Diffusive equilibrium in thin films provides evidence of suppression of hyporheic exchange and large‐scale nitrate transformation in a groundwater‐fed river

The hyporheic zone of riverbed sediments has the potential to attenuate nitrate from upwelling, polluted groundwater. However, the coarse‐scale (5–10 cm) measurement of nitrogen biogeochemistry in the hyporheic zone can often mask fine‐scale (<1 cm) biogeochemical patterns, especially in near‐surface sediments, leading to incomplete or inaccurate representation of the capacity of the hyporheic zone to transform upwelling NO₃^?. In this study, we utilised diffusive equilibrium in thin‐films samplers to capture high resolution (cm‐scale) vertical concentration profiles of NO₃^?, SO₄^2?, Fe and Mn in the upper 15 cm of armoured and permeable riverbed sediments. The goal was to test whether nitrate attenuation was occurring in a sub‐reach characterised by strong vertical (upwelling) water fluxes. The vertical concentration profiles obtained from diffusive equilibrium in thin‐films samplers indicate considerable cm‐scale variability in NO₃^? (4.4 ± 2.9 mg N/L), SO₄^2? (9.9 ± 3.1 mg/l) and dissolved Fe (1.6 ± 2.1 mg/l) and Mn (0.2 ± 0.2 mg/l). However, the overall trend suggests the absence of substantial net chemical transformations and surface‐subsurface water mixing in the shallow sediments of our sub‐reach under baseflow conditions. The significance of this is that upwelling NO₃^?‐rich groundwater does not appear to be attenuated in the riverbed sediments at <15 cm depth as might occur where hyporheic exchange flows deliver organic matter to the sediments for metabolic processes. It would appear that the chemical patterns observed in the shallow sediments of our sub‐reach are not controlled exclusively by redox processes and/or hyporheic exchange flows. Deeper‐seated groundwater fluxes and hydro‐stratigraphy may be additional important drivers of chemical patterns in the shallow sediments of our study sub‐reach. © 2015 The Authors. Hydrological Processes Published by John Wiley & Sons Ltd.