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381.
F. Parello A. Aiuppa H. Calderon F. Calvi D. Cellura V. Martinez M. Militello K. Vammen D. Vinti 《Applied Geochemistry》2008
This paper reports new geochemical data on dissolved major and minor constituents in surface waters and ground waters collected in the Managua region (Nicaragua), and provides a preliminary characterization of the hydrogeochemical processes governing the natural water evolution in this area. The peculiar geological features of the study site, an active tectonic region (Nicaragua Depression) characterized by active volcanism and thermalism, combined with significant anthropogenic pressure, contribute to a complex evolution of water chemistry, which results from the simultaneous action of several geochemical processes such as evaporation, rock leaching, mixing with saline brines of natural or anthropogenic origin. The effect of active thermalism on both surface waters (e.g., saline volcanic lakes) and groundwaters, as a result of mixing with variable proportions of hyper-saline geothermal Na–Cl brines (e.g., Momotombo geothermal plant), accounts for the high salinities and high concentrations of many environmentally-relevant trace elements (As, B, Fe and Mn) in the waters. At the same time the active extensional tectonics of the Managua area favour the interaction with acidic, reduced thermal fluids, followed by extensive leaching of the host rock and the groundwater release of toxic metals (e.g., Ni, Cu). The significant pollution in the area, deriving principally from urban and industrial waste-water, probably also contributes to the aquatic cycling of many trace elements, which attain concentrations above the WHO recommended limits for the elements Ni (∼40 μg/l) and Cu (∼10 μg/l) limiting the potential utilisation of Lake Xolotlan for nearby Managua. 相似文献
382.
383.
J.A. Saunders M.-K. Lee M. Shamsudduha P. Dhakal A. Uddin M.T. Chowdury K.M. Ahmed 《Applied Geochemistry》2008
Here new data from field bioremediation experiments and geochemical modeling are reported to illustrate the principal geochemical behavior of As in anaerobic groundwaters. In the field bioremediation experiments, groundwater in Holocene alluvial aquifers in Bangladesh was amended with labile water-soluble organic C (molasses) and MgSO4 to stimulate metabolism of indigenous SO4-reducing bacteria (SRB). In the USA, the groundwater was contaminated by Zn, Cd and SO4, and contained <10 μg/L As under oxidized conditions, and a mixture of sucrose and methanol were injected to stimulate SRB metabolism. In Bangladesh, groundwater was under moderately reducing conditions and contained ∼10 mg/L Fe and ∼100 μg/L As. In the USA experiment, groundwater rapidly became anaerobic, and dissolved Fe and As increased dramatically (As > 1000 μg/L) under geochemical conditions consistent with bacterial Fe-reducing conditions. With time, groundwater became more reducing and biogenic SO4 reduction began, and Cd and Zn were virtually completely removed due to precipitation of sphalerite (ZnS) and other metal sulfide mineral(s). Following precipitation of chalcophile elements Zn and Cd, the concentrations of Fe and As both began to decrease in groundwater, presumably due to formation of As-bearing FeS/FeS2. By the end of the six-month experiment, dissolved As had returned to below background levels. In the initial Bangladesh experiment, As decreased to virtually zero once biogenic SO4 reduction commenced but increased to pre-experiment level once SO4 reduction ended. In the ongoing experiment, both SO4 and Fe(II) were amended to groundwater to evaluate if FeS/FeS2 formation causes longer-lived As removal. Because As-bearing pyrite is the common product of SRB metabolism in Holocene alluvial aquifers in both the USA and Southeast Asia, it was endeavored to derive thermodynamic data for arsenian pyrite to better predict geochemical processes in naturally reducing groundwaters. Including the new data for arsenian pyrite into Geochemist’s Workbench, its stability field completely dominates in reducing Eh–pH space and “displaces” other As-sulfides (orpiment, realgar) that have been implied to be important in previous modeling exercises and reported in rare field conditions. 相似文献
384.
Gregory P. Marchildon Suren Kulshreshtha Elaine Wheaton Dave Sauchyn 《Natural Hazards》2008,45(3):391-411
Agriculture in the southern Great Plains of Canada has been particularly vulnerable to prolonged episodes of drought. Using
climate data and a precipitation minus potential evapotranspiration index, the extent of the region’s exposure to drought
is examined. Between 1914 and 1917, the Dry Belt was particularly vulnerable to drought, whereas after 1928, a much larger
region known as the Palliser Triangle covering most of southern Alberta and Saskatchewan was much more exposed to drought.
These droughts provoked major institutional adaptation, in particular the establishment of the Special Areas Board by the
Government of Alberta, and the creation of the Prairie Farm Rehabilitation Administration by the Government of Canada. Both
organizations have proved to be relatively permanent public adaptations to the natural hazard of drought in the region. Moreover,
these earlier experiences with prolonged drought as well as institution-building may be of value in helping the residents
of the Palliser Triangle adapt to predicted climate changes in the future as well as anticipate some of the barriers to effective
institutional adaptation. 相似文献
385.
In this study, households’ decisions on reconstruction of damaged houses were modeled, using questionnaire data in Japan.
Characteristics of households’ decisions were investigated using parameter estimation results. The effects of subsidizing
policy were evaluated as follows. First, subsidy for rebuilding may be effective for the households whose houses were heavily
damaged. Second, there is a possibility that subsidy accelerated rebuilding of houses by the households having children. Third,
subsidy for rebuilding may not be effective for elderly people’s households and households in depopulated areas. 相似文献
386.
Flood hazard delineation combining geomorphological and hydrological methods: an example in the Northern Iberian Peninsula 总被引:2,自引:1,他引:1
Flood mapping requires the combination and integration of geomorphological and hydrological-hydraulic methods; however, despite
this, there is very little scientific literature that compares and validates both methods. Two types of analysis are addressed
in the present article. On the one hand, maps of flood plains have been elaborated using geomorphological evidence and historical
flood data in the mountainous area of northwestern Spain, covering an area of more then 232 km2 of floodplains. On the other hand, a hydrometeorological model has been developed (Clark semidistributed unit hydrograph)
in the Sarria River basin (155 km2, NW Spain). This basin is not gauged, hence the model was subjected to a goodness-of-fit test of its parameter (curve number)
by means of Monte Carlo simulation. The peak flows obtained by means of the hydrological model were used for hydraulic modeling
(one-phase, one-dimensional and steady flow) in a 4 km2 urban stretch of the river bed. The delineation of surface areas affected by floods since 1918, as well as those analyzed
subsequent to the geomorphological study, reveals a high degree of reliability in the delineation of the flooded areas with
frequent recurrence intervals (<50 years). If we compare these flooded surface areas with the estimate obtained by the hydrological-hydraulic
method we can see that the latter method overestimates the extent of the surface water by 144% for very frequent recurrence
intervals (>10 years) and underestimates it as the recurrence interval increases, by up to 80% less floodplain for exceptional
events (>500 years). Finally, a management map is put forth combining the most reliable results available by integrating both
methods.
Originally presented at the Sixth International Conference on Geomorphology. 相似文献
387.
Prakash C. Sinha Indu Jain Neetu Bhardwaj Ambarukhana D. Rao Shishir K. Dube 《Natural Hazards》2008,45(3):413-427
The Orissa coast of India is one of the most vulnerable regions of extreme sea levels associated with severe tropical cyclones.
There was extensive loss of life and property due to the October 1999 super cyclone, which devastated large part of the Orissa
coast. The shallow nature of the head bay, presence of a large number of deltas formed by major rivers of Orissa such as Mahanadi
and Dhamra, and high tidal range are responsible for storm surge flooding in the region. Specifically, rising and falling
tidal phases influence the height, duration, and arrival time of peak surge along the coast. The objective of the present
study is to evaluate the tide-surge interaction during the 1999 Orissa cyclone by using nonlinear vertically integrated numerical
models. The pure tidal solution for the head bay region of the Bay of Bengal provides the initial condition for the fine resolution
nested grid Orissa model. However, the feedback from the Orissa model does not affect the head bay model as the study provides
a one-way interaction. Numerical experiments are performed to study the tide-surge interaction by considering various relative
phases of the tidal waves with the surge-wave produced by 1999 Orissa cyclone. The comparison, although utilizing only the
limited estimates of tidal data, appears adequate to assert that the principal features are reproduced correctly. 相似文献
388.
Rain-induced debris and mudflow triggering factors assessment in the Santiago cordilleran foothills,Central Chile 总被引:1,自引:1,他引:0
Debris and mudflows are some of the main geological hazards in the mountain foothills of the Chilean capital city of Santiago.
There, the risk of flows triggered in the basins of ravines that drain the range into the city increases with time due to
the city growth. A multivariate statistical study based on the logistic regression method is presented. The model provides
equations that allow the computation of combined meteorological triggering factors associated with a probability of rain-induced
flow occurrence. Daily rainfall, accumulated rainfall and the snowfall level, traditionally considered as the relevant factors,
are analysed for a 25-year period. The results show a strong relevance of the rainfall on the day of the flow event over the
other factors. However, the relatively low probabilities returned for some real flow events suggest that the model does not
capture all the significant variables and the problem is more complex than as it has been traditionally assumed, and further
investigations are needed to develop predictive models of flow triggering. 相似文献
389.
Serena C. Tarantino Michele Zema Tiziana Boffa Ballaran Paolo Ghigna 《Physics and Chemistry of Minerals》2008,35(2):71-76
High-pressure single-crystal X-ray diffraction measurements of lattice parameters of the compound Li2VOSiO4, which crystallises with a natisite-type structure, has been carried out to a pressure of 8.54(5) GPa at room temperature.
Unit-cell volume data were fitted with a second-order Birch-Murnaghan EoS (BM-EoS), simultaneously refining V
0 and K
0 using the data weighted by the uncertainties in V. The bulk modulus is K
0 = 99(1) GPa, with K′ fixed to 4. Refinements of third order equations-of-state yielded values of K′ that did not differ significantly from 4. The compressibility of the unit-cell is strongly anisotropic with the c axis (K
0(c) = 49.7 ± 0.5 GPa) approximately four times more compressible than the a axis (K
0(a) = 195 ± 3 GPa). 相似文献
390.
Flaring of associated gas from oil exploitation has several consequences on the environment. This study explores the spatial
variability effects of gas flaring on the growth and development of cassava (Manihot esculenta), waterleaf (Talinum triangulare), and pepper (Piper spp.) crops commonly cultivated in the Niger Delta, Nigeria. Data was collected on soil and atmospheric temperature and moisture
at a 20-m interval, starting at 40 m from the flare point to a distance of 140 m. Lengths and widths of crop leaves, height
of crop plants and cassava yields were measured at the specified distances. The amino acid, ascorbic acid, starch, and sugar
constituents of the cassava yields were determined. The results suggest that a spatial gradient exists in the effects of gas
flares on crop development. Retardation in crop development manifests in decreased dimensions of leaf lengths and widths of
cassava and pepper crops closer to the gas flare point. Statistical analysis also confirms that cassava yields are higher
at locations further away from the flare point. In addition, the amount of starch and ascorbic acid in cassava decreased when
the plant is grown closer to the gas flare. High temperatures around the gas flare appear to be the most likely cause of this
retardation. The waterleaf crop, on the other hand, appears to thrive better around the gas flare point. 相似文献