Studying the Deep Structure of Elbrus Volcano by Microseismic Sounding

This paper presents results from a study of the deep structure of the Elbrus edifice and adjacent areas using geophysical techniques. We confirmed the existence of a shallow magma chamber, derived a more accurate location of the chamber in the host rocks and its characteristic dimensions, and compared new results with known studies. More accurate estimates have been obtained for the temperature at the top of the magma chamber and new evidence is adduced concerning the deep structure of the fluid magmatic systems in the Elbrus volcanic area.     

Variation in Coronal Activity from Solar Cycle 24 Minimum to Maximum Using Three-Dimensional Reconstructions of the Coronal Electron Density from STEREO/COR1

Three-dimensional electron density distributions in the solar corona are reconstructed for 100 Carrington rotations (CR 2054?–?2153) during 2007/03?–?2014/08 using the spherically symmetric method from polarized white-light observations with the inner coronagraph (COR1) onboard the twin Solar Terrestrial Relations Observatory (STEREO). These three-dimensional electron density distributions are validated by comparison with similar density models derived using other methods such as tomography and a magnetohydrodynamics (MHD) model as well as using data from the Solar and Heliospheric Observatory (SOHO)/Large Angle and Spectrometric Coronagraph (LASCO)-C2. Uncertainties in the estimated total mass of the global corona are analyzed based on differences between the density distributions for COR1-A and -B. Long-term variations of coronal activity in terms of the global and hemispheric average electron densities (equivalent to the total coronal mass) reveal a hemispheric asymmetry during the rising phase of Solar Cycle 24, with the northern hemisphere leading the southern hemisphere by a phase shift of 7?–?9 months. Using 14 CR (\(\approx13\)-month) running averages, the amplitudes of the variation in average electron density between Cycle 24 maximum and Cycle 23/24 minimum (called the modulation factors) are found to be in the range of 1.6?–?4.3. These modulation factors are latitudinally dependent, being largest in polar regions and smallest in the equatorial region. These modulation factors also show a hemispheric asymmetry: they are somewhat larger in the southern hemisphere. The wavelet analysis shows that the short-term quasi-periodic oscillations during the rising and maximum phases of Cycle 24 have a dominant period of 7?–?8 months. In addition, it is found that the radial distribution of the mean electron density for streamers at Cycle 24 maximum is only slightly larger (by \(\approx30\%\)) than at cycle minimum.     

Occurrence and Distribution of Organic Contaminants in the Aquatic System in Berlin.Part II: Substituted Phenols in Berlin Surface Water

In a surface water screening, 30 representative surface water samples collected from rivers, canals, and lakes in Berlin were investigated for the presence of 22 substituted phenols. The phenols selected include the 11 phenols considered as “priority pollutants” by the US Environmental Protection Agency (US-EPA). Surface water samples were extracted applying solid-phase extraction with styrenedivinylbenzene adsorbent. The recoveries, determined in spiking experiments, were between 80 % and 103 %. After derivatization with N-(tert-butyldimethylsilyl)-N-methyl-trifluoroacetamide (MTBSTFA) the samples were analyzed by capillary gas chromatography-mass spectrometry (GC-MS). Phenol, cresols, 2-ethylphenol, 2-chlorophenol, 4-chloro-3-methylphenol, pentachlorophenol, 2-nitrophenol, and 4-nitrophenol were detected in the surface water samples at concentrations between 0.02 μg/L and 7.8 μg/L, respectively. The distribution of these residues in the Berlin surface waters showed that the phenolic residues, with the exception of pentachlorophenol and 2-ethylphenol, do not originate primarily from municipal sewage treatment plants discharges. Some of the phenols are formed naturally or occur as ubiquitous anthropogenic contaminants in the aquatic system.     

Classifying zones of suitability for manual drilling using textural and hydraulic parameters of shallow aquifers: a case study in northwestern Senegal

A method is proposed that uses analysis of borehole stratigraphic logs for the characterization of shallow aquifers and for the assessment of areas suitable for manual drilling. The model is based on available borehole-log parameters: depth to hard rock, depth to water, thickness of laterite and hydraulic transmissivity of the shallow aquifer. The model is applied to a study area in northwestern Senegal. A dataset of boreholes logs has been processed using a software package (TANGAFRIC) developed during the research. After a manual procedure to assign a standard category describing the lithological characteristics, the next step is the automated extraction of different textural parameters and the estimation of hydraulic conductivity using reference values available in the literature. The hydraulic conductivity values estimated from stratigraphic data have been partially validated, by comparing them with measured values from a series of pumping tests carried out in large-diameter wells. The results show that this method is able to produce a reliable interpretation of the shallow hydrogeological context using information generally available in the region. The research contributes to improving the identification of areas where conditions are suitable for manual drilling. This is achieved by applying the described method, based on a structured and semi-quantitative approach, to classify the zones of suitability for given manual drilling techniques using data available in most African countries. Ultimately, this work will support proposed international programs aimed at promoting low-cost water supply in Africa and enhancing access to safe drinking water for the population.     

Diffusive equilibrium in thin films provides evidence of suppression of hyporheic exchange and large‐scale nitrate transformation in a groundwater‐fed river

The hyporheic zone of riverbed sediments has the potential to attenuate nitrate from upwelling, polluted groundwater. However, the coarse‐scale (5–10 cm) measurement of nitrogen biogeochemistry in the hyporheic zone can often mask fine‐scale (<1 cm) biogeochemical patterns, especially in near‐surface sediments, leading to incomplete or inaccurate representation of the capacity of the hyporheic zone to transform upwelling NO₃^?. In this study, we utilised diffusive equilibrium in thin‐films samplers to capture high resolution (cm‐scale) vertical concentration profiles of NO₃^?, SO₄^2?, Fe and Mn in the upper 15 cm of armoured and permeable riverbed sediments. The goal was to test whether nitrate attenuation was occurring in a sub‐reach characterised by strong vertical (upwelling) water fluxes. The vertical concentration profiles obtained from diffusive equilibrium in thin‐films samplers indicate considerable cm‐scale variability in NO₃^? (4.4 ± 2.9 mg N/L), SO₄^2? (9.9 ± 3.1 mg/l) and dissolved Fe (1.6 ± 2.1 mg/l) and Mn (0.2 ± 0.2 mg/l). However, the overall trend suggests the absence of substantial net chemical transformations and surface‐subsurface water mixing in the shallow sediments of our sub‐reach under baseflow conditions. The significance of this is that upwelling NO₃^?‐rich groundwater does not appear to be attenuated in the riverbed sediments at <15 cm depth as might occur where hyporheic exchange flows deliver organic matter to the sediments for metabolic processes. It would appear that the chemical patterns observed in the shallow sediments of our sub‐reach are not controlled exclusively by redox processes and/or hyporheic exchange flows. Deeper‐seated groundwater fluxes and hydro‐stratigraphy may be additional important drivers of chemical patterns in the shallow sediments of our study sub‐reach. © 2015 The Authors. Hydrological Processes Published by John Wiley & Sons Ltd.     

Distribution of Indus born mica along Gulf of Kachchh coast: Implications in understanding current dynamics

Indus is one of the major sources of sediments to the Gulf of Kachchh. Yet only its <63 micron fraction is studied in detail with regards to the offshore current dynamics. Hence here we present our study on characteristic signature of the Indus sediment load (i.e. mica minerals) in >63 micron size fraction along the coast of Gulf of Kachchh. The spatial distribution of mica minerals along the Gulf of Kachchh coast was studied which showed in general decreasing trend as we move along the northern and southern coast of the Gulf of Kachchh but, an increase in amount near the southern mouth at Okha. The study shows that the earlier proposed tidal barrier is ineffective in restricting movement of mica across the mouth of the gulf due to its characteristic transport mechanism. Also the presence of mudflats along the gulf of Kachchh coast plays a vital role as sediment receptors in the active sediment transport processes and mica minerals prove to be a promising simple tracer in studying the Indus born sediments in the region.     

Can Plant Competition and Diversity Reduce the Growth and Survival of Exotic <Emphasis Type="Italic">Phragmites australis</Emphasis> Invading a Tidal Marsh?

The rapid proliferation of Phragmites australis in North America has challenged resource managers to curb its expansion and reduce the loss of functional tidal marsh. We investigated whether native plant competition could reduce the ability of Phragmites to invade a tidal marsh, and if plant diversity (species richness, evenness, and composition) altered the competitive outcome. Immature Phragmites shoots and four native halophytes were transplanted to small but dense field plots (~1,200 shoots m⁻²) comprising three community structure types (Phragmites alone, Phragmites + 1 native species, and Phragmites + 4 native species). Interspecific competition significantly reduced Phragmites aboveground biomass, shoot length production, density, and survival by approximately 60%. Additionally, plots planted with greater native diversity contained Phragmites with the lowest growth and survival, potentially indicating diversity-enhanced resource competition. Competition consistently reduced the growth of Phragmites even under favorable conditions: lack of strong tidal flooding stresses as well as elevated nutrient pools.     

Evidence for the occurrence of hydrogeochemical processes in the groundwater of Khoy plain,northwestern Iran,using ionic ratios and geochemical modeling

Rapid population growth, industrialization, and agricultural expansion in the Khoy area (northwestern Iran) have led to its dependence on groundwater and degradation of groundwater quality. This study attempts to decipher the major processes and factors that degrade the groundwater quality of the Khoy plain. For this purpose, 54 groundwater samples from unconfined and confined aquifers of the plain were collected in July 2017 and analyzed for major cations and anions (Na, K, Ca, Mg, HCO₃, SO_4, and Cl), minor ions (NO₃ and F), and Al. Magnesium and bicarbonate were identified as the dominant cation and anion, respectively. Several ionic ratios and geochemical modeling using PHREEQC indicated that the most important hydrogeochemical processes to affect groundwater quality in the plain were weathering and dissolution of evaporitic and silicate minerals, mixing, and ion exchange. There were smaller effects from evaporation and anthropogenic factors (e.g., industries). Results showed that the high salinity of the groundwater in the northeast area of the plain was due to the high solubility of the evaporitic minerals, e.g., halite and gypsum. Reverse ion exchange and the contribution of mineral dissolution were more significant than ion exchange in the northeastern part of the plain. Elevated salinity of the groundwater in the southeast was attributed mostly to reverse ion exchange and somewhat to evaporation.     

Computing the Sensitivity Kernels for 2.5-D Seismic Waveform Inversion in Heterogeneous,Anisotropic Media

2.5-D modeling and inversion techniques are much closer to reality than the simple and traditional 2-D seismic wave modeling and inversion. The sensitivity kernels required in full waveform seismic tomographic inversion are the Fréchet derivatives of the displacement vector with respect to the independent anisotropic model parameters of the subsurface. They give the sensitivity of the seismograms to changes in the model parameters. This paper applies two methods, called ‘the perturbation method’ and ‘the matrix method’, to derive the sensitivity kernels for 2.5-D seismic waveform inversion. We show that the two methods yield the same explicit expressions for the Fréchet derivatives using a constant-block model parameterization, and are available for both the line-source (2-D) and the point-source (2.5-D) cases. The method involves two Green’s function vectors and their gradients, as well as the derivatives of the elastic modulus tensor with respect to the independent model parameters. The two Green’s function vectors are the responses of the displacement vector to the two directed unit vectors located at the source and geophone positions, respectively; they can be generally obtained by numerical methods. The gradients of the Green’s function vectors may be approximated in the same manner as the differential computations in the forward modeling. The derivatives of the elastic modulus tensor with respect to the independent model parameters can be obtained analytically, dependent on the class of medium anisotropy. Explicit expressions are given for two special cases—isotropic and tilted transversely isotropic (TTI) media. Numerical examples are given for the latter case, which involves five independent elastic moduli (or Thomsen parameters) plus one angle defining the symmetry axis.