Structure Function Analysis of Two-Scale Scalar Ramps. Part II: Ramp Characteristics and Surface Renewal Flux Estimation

Ramp features in the turbulent scalar field are associated with turbulent coherent structures, which dominate energy and mass fluxes in the atmospheric surface layer. Although finer scale ramp-like shapes embedded within larger scale ramp-like shapes can readily be perceived in turbulent scalar traces, their presence has largely been overlooked in the literature. We demonstrate the signature of more than one ramp scale in structure functions of the turbulent scalar field measured from above bare ground and two types of short plant canopies, using structure-function time lags ranging in scale from isotropic to larger than the characteristic coherent structures. Spectral analysis of structure functions was used to characterize different scales of turbulent structures. By expanding structure function analysis to include two ramp scales, we characterized the intermittency, duration, and surface renewal flux contribution of the smallest (i.e., Scale One) and the dominant (i.e., Scale Two) coherent structure scales. The frequencies of the coherent structure scales increase with mean wind shear, implying that both Scale One and Scale Two are shear-driven. The embedded Scale One turbulent structure scale is ineffectual in the surface-layer energy and mass transport process. The new method reported here for obtaining surface renewal-based scalar exchange works well over bare ground and short canopies under unstable conditions, effectively eliminating the α calibration for these conditions and forming the foundation for analysis over taller and more complex surfaces.     

Mapping of sound scattering objects in the northern part of the Barents Sea and their geological interpretation

On cruises 25 (2007) and 28 (2011) of the R/V Akademik Nikolai Strakhov in the northern part of the Barents Sea, the Geological Institute, Russian Academy of Sciences, conducted comprehensive research on the bottom relief and upper part of the sedimentary cover profile under the auspices of the International Polar Year program. One of the instrument components was the SeaBat 8111 shallow-water multibeam echo sounder, which can map the acoustic field similarly to a side scan sonar, which records the response both from the bottom and from the water column. In the operations area, intense sound scattering objects produced by the discharge of deep fluid flows are detected in the water column. The sound scattering objects and pockmarks in the bottom relief are related to anomalies in hydrocarbon gas concentrations in bottom sediments. The sound scattering objects are localized over Triassic sequences outcropping from the bottom. The most intense degassing processes manifest themselves near the contact of the Triassic sequences and Jurassic clay deposits, as well as over deep depressions in a field of Bouguer anomalies related to the basement of the Jurassic–Cretaceous rift system     

A multi-equation spatial econometric model,with application to EU manufacturing productivity growth

A multi-equation spatial econometric model is used to explain variations across EU regions in manufacturing productivity growth based on recent theoretical developments in urban economics and economic geography. The paper shows that temporal and spatial parameter homogeneity is an unrealistic assumption, contrary to what is typically assumed in the literature. Constraints are imposed on parameters across time periods and between core and peripheral regions of the EU, with the significant loss of fit providing overwhelming evidence of parameter heterogeneity, although the final model does highlight increasing returns to scale, which is a central feature of contemporary theory.      

Assessing landslide movements in volcanic islands using near-shore marine geophysical data: south Pico island,Azores

Marine geophysical data from around the submarine flanks of volcanic islands can potentially help to resolve whether large-scale instability of an edifice has been geologically recently active. We use geophysical data to investigate part of the coast of Pico Island of the Azores where, above sea-level, a major slump of Topo volcano has been interpreted previously from arcuate escarpments and a rugged irregular topography seaward of them. Multibeam echo-sounder data collected offshore of this feature show remarkably little evidence for slump fault movements in the island's submarine slope. Mid-slope benches, like those associated with the Hilina Slump of Kilauea, are absent. The high-resolution data extends onto the island's shelf, allowing us to evaluate evidence for continuing activity there. In particular, as the shelf's rock platform will have been last modified by surf erosion during the postglacial period of sea-level transgression, it provides a reference surface of intermediate age (7–19 ka) that can potentially reveal whether any movements occurred in pre-historic times. Where the arcuate escarpments are continued offshore, the modern seabed shows no bathymetric evidence for active faults where the shelf rock platform crops out in the multibeam data. Elsewhere, mobile shelf sediments could be disguising evidence for active faulting so we examined boomer profiles able to image the rock platform beneath them. The data reveal a platform that is steep (6.6°) compared with the dips of platforms that we have studied previously around the coast of adjacent Faial Island and steeper than the platform outside the proposed slump. This suggests that it was created by coastal erosion over a shorter period and hence is consistent with a younger age of the coastline. As with the multibeam data, where escarpments are continued offshore onto the shelf, the rock surface imaged with these boomer data also shows no clear evidence of major slump-related fault displacements. This study therefore illustrates how high-resolution boomer seismic and multibeam data could usefully contribute to hazard assessment of volcanic islands, by helping to evaluate areas with no historical movements. Explanations to reconcile the onshore and offshore data here are also put forward.     

Eignung mikrobieller Biotests für gebundene Schadstoffe Suitability of Microbial Bioassays for Bound Contaminants

Toxicity of soil spiked with water soluble and insoluble contaminants was assessed with bacteria. Three bioassays were used with common soil bacteria. Water soluble fractions from the soils were estimated in microtiterplates via dehydrogenase activity of B. cereus and growth of P. putida. A new method was developed using B. cereus to include effects of soil particles with bound contaminants. As contaminants p-nitrophenol and 2-naphthol were tested in these systems. Results indicated that the concentration of the contaminants in the soil solution is determined by soil properties. Toxicity of water soluble fractions was not only a result of the toxicant's concentration but further modified by soluble components of the soils. It is not possible to assess soil pollution from toxicity of the water soluble fraction in general, because unknown factors of the soluble soil fraction can influence toxicity greatly. The newly developed contact bioassay with B. cereus showed clearly higher toxicity of 2-naphthol estimated in soil suspension than did the comparable test system with the same bacteria using water soluble fractions only. The results stress the importance of including soil particles into bioassay procedures. It was shown that also water insoluble, bound contaminants can act as toxicants. For an estimation of toxicity under conditions more relevant for the environment, the suggested test system can provide useful information to bioavailability of bound contaminants.     

Anaerobic Metabolism in Tidal Freshwater Wetlands: I. Plant Removal Effects on Iron Reduction and Methanogenesis

For energetic reasons, iron reduction suppresses methanogenesis in tidal freshwater wetlands; however, when iron reduction is limited by iron oxide availability, methanogenesis dominates anaerobic carbon mineralization. Plants can mediate this microbial competition by releasing oxygen into the rhizosphere and supplying oxidized iron for iron reducers. We utilized a plant removal experiment in two wetland sites to test the hypothesis that, in the absence of plants, rates of iron reduction would be diminished, allowing methanogenesis to dominate anaerobic metabolism. In both sites, methanogenesis was the primary anaerobic mineralization pathway, with iron reduction dominating only early and late in the growing season in the site with a less organic soil. These patterns were not influenced by the presence of plants, demonstrating that plants were not a key control of microbial metabolism. Instead, we suggest that site conditions, including soil chemistry, and temperature are important controls of the pathways of anaerobic metabolism.     

Gamma-ray bursts: optical afterglows in the deep Newtonian phase

Gamma-ray burst remnants become trans-relativistic typically in days to tens of days, and they enter the deep Newtonian phase in tens of days to months, during which the majority of shock-accelerated electrons will no longer be highly relativistic. However, a small portion of electrons are still accelerated to ultra-relativistic speeds and are capable of emitting synchrotron radiation. The distribution function for electrons is re-derived here so that synchrotron emission from these relativistic electrons can be calculated. Based on the revised model, optical afterglows from both isotropic fireballs and highly collimated jets are studied numerically, and compared to analytical results. In the beamed cases, it is found that, in addition to the steepening due to the edge effect and the lateral expansion effect, the light curves are universally characterized by a flattening during the deep Newtonian phase.     

The Proterozoic,albitite-hosted,Valhalla uranium deposit,Queensland, Australia: a description of the alteration assemblage associated with uranium mineralisation in diamond drill hole V39

The Valhalla uranium deposit, located 40 km north of Mount Isa, Queensland, Australia, is an albitite-hosted, Mesoproterozoic U deposit similar to albitite-hosted uranium deposits in the Ukraine, Sweden, Brazil and Guyana. Uranium mineralisation is hosted by a thick package of interbedded fine-grained sandstones, arkoses and gritty siltstones that are bound by metabasalts belonging to the ca. 1,780 Ma Eastern Creek Volcanics in the Western Succession of the Mount Isa basin. Alteration associated with U mineralisation can be divided into an early, main and late stage. The early stage is dominated by laminated and intensely altered rock comprising albite, reibeckite, calcite, (titano)magnetite ± brannerite. The main stage of mineralisation is dominated by brecciated and intensely altered rocks that comprise laminated and intensely altered rock cemented by brannerite, apatite, (uranoan)-zircon, uraninite, anatase, albite, reibeckite, calcite and hematite. The late stage of mineralisation comprises uraninite, red hematite, dolomite, calcite, chlorite, quartz and Pb-, Fe-, Cu-sulfides. Brannerite has U–Pb and Pb–Pb ages that indicate formation between 1,555 and 1,510 Ma, with significant Pb loss evident at ca. 1,200 Ma, coincident with the assemblage of Rodinia. The oldest ages of the brannerite overlap with ⁴⁰Ar/³⁹Ar ages of 1,533 ± 9 Ma and 1,551 ± 7 Ma from early and main-stage reibeckite and are interpreted to represent the timing of formation of the deposit. These ages coincide with the timing of peak metamorphism in the Mount Isa area during the Isan Orogeny. Lithogeochemical assessment of whole rock data that includes mineralised and unmineralised samples from the greater Mount Isa district reveals that mineralisation involved the removal of K, Ba and Si and the addition of Na, Ca, U, V, Zr, P, Sr, F and Y. U/Th ratios indicate that the ore-forming fluid was oxidised, whereas the crystal chemistry of apatite and reibeckite within the ore zone suggests that F⁻ and were important ore-transporting complexes. δ¹⁸O values of co-existing calcite and reibeckite indicate that mineralisation occurred between 340 and 380°C and involved a fluid having δ¹⁸O_fluid values between 6.5 and 8.6‰. Reibeckite δD values reveal that the ore fluid had a δD_fluid value between −98 and −54‰. The mineral assemblages associated with early and main stages of alteration, plus δ¹⁸O_fluid and δD_fluid values, and timing of the U mineralisation are all very similar to those associated with Na–Ca alteration in the Eastern Succession of the Mount Isa basin, where a magmatic fluid is favoured for this style of alteration. However, isotopic data from Valhalla is also consistent with that from the nearby Mount Isa Cu deposit where a basinal brine is proposed for the transport of metals to the deposit. Based on the evidence to hand, the source fluids could have been derived from either or both the metasediments that underlie the Eastern Creek Volcanics or magmatism that is manifest in the Mount Isa area as small pegmatite dykes that intruded during the Isan Orogeny.     

An analysis of climatic and human induced determinants of agricultural land use changes in Shupiyan area of Jammu and Kashmir state,India

The economy of the Jammu and Kashmir state depends mostly on traditional forms of occupation. Unaffected and unaltered by modern day industrial developments and changing times, the indigenous traditional occupations of farming, animal husbandry and horticulture forms the backbone of the state economy. But in the last few decades, Agriculture in the state as well as the study area is receiving a set back and Horticulture is flourishing leaps and bounds. The present study aims to analyze various determinants responsible for this change. Climatic as well as field data was thoroughly analyzed to comprehend the situation. A Mann–Kendall test was done on the climatic data to support the hypotheses. It was observed that initially changing climatic trends proved to be the triggering factor supporting this change, but in due course of time, the determinants took an economic and psychological turn. The perusal of Indian Meteorological Data reveals an increasing trend of annual mean maximum temperature from 16.78 °C in 1985 to 17.58 °C in 1995 and an increase from 5.30 °C to 7.00 °C in the annual mean minimum temperature, and as such acting as a triggering factor for the land use conversion. Further, the mean annual rainfall shows a decrease from 100.75 mm in 1981 to 79.43 mm in 1991. The greater economic returns from horticulture as well as the changing behavioral patterns of people over the time further cemented its growth. The farmers have since persisted with the horticulture activity as it has proven to be an economically a much better lucrative enterprise.     

Electrical and electromagnetic surveys to locate possible causes of water seepage to ground surface at a quarry open pit near Helwan city,Egypt

Water seepage to ground surface at a limestone quarry located at Wadi Garawy about 20 km south-east of Helwan city in Egypt posed a real threat to the mining activity at the quarry. The quarry area is known to be very dry for decades and away from water utilities and infrastructures that may cause water leaks to the quarry. Geophysical investigation including 1D Vertical Electrical Sounding (VES), 2D Electrical Resistivity Tomography (ERT) and 1D Transient Electromagnetic (TEM) surveys were conducted to characterize the rock sequence and locate what could be a possible source of water seepage to the quarry. The resistivity profiles generated from the VES and TEM surveys mapped the rock units in the area down to depths exceeded 100 m. The ERT profiles acquired from the quarrying zone close to the water seepage spot have imaged the top of groundwater level at few meters below the ground surface at the quarry open pit. The spot of groundwater seepage seemed to occur at an area of limestone dissolution that were filled by finer sediments. The finer sediments acted as a hydrological conduit that allowed an upward seepage of groundwater to ground surface under the capillary action effect.