E (B-V) determination from an UV-visual two-colour diagram: O and B stars in the catalogue of stellar ultraviolet fluxes

We present here, for the O and B type stars in the Catalogue of Stellar Ultraviolet Fluxes, an approach which does not require a precise knowledge of spectral type and luminosity class for derivingE(B-V) colour excesses. The method is based on the use of an UV-visual two-colour diagram; galactic variations in the interstellar extinction law are analyzed and fully taken into account. Our results have been compared with those derived by using the differences between observed and intrinsic colours for stars with known spectral classification. The very good agreement in a large number of cases (94 per cent) demonstrates that our approach permits the derivation of reliable colour excess values for early type stars even if only a rough spectral classification is available.     

The formation of porphyry copper deposits

Copper is a moderately incompatible chalcophile element. Its behavior is strongly controlled by sulfides. The speciation of sulfur is controlled by oxygen fugacity. Therefore, porphyry Cu deposits are usually oxidized (with oxygen fugacities > ΔFMQ +2) (Mungall 2002; Sun et al. 2015). The problem is that while most of the magmas at convergent margins are highly oxidized, porphyry Cu deposits are very rare, suggesting that high oxygen fugacity alone is not sufficient. Partial melting of mantle peridotite even at very high oxygen fugacities forms arc magmas with initial Cu contents too low to form porphyry Cu deposits directly (Lee et al. 2012; Wilkinson 2013). Here we show that partial melting of subducted young oceanic slabs at high oxygen fugacity (>ΔFMQ +2) may form magmas with initial Cu contents up to >500 ppm, favorable for porphyry mineralization. Pre-enrichment of Cu through sulfide saturation and accumulation is not necessarily beneficial to porphyry Cu mineralization. In contrast, re-melting of porphyritic hydrothermal sulfide associated with iron oxides may have major contributions to porphyry deposits. Thick overriding continental crust reduces the “leakage” of hydrothermal fluids, thereby promoting porphyry mineralization. Nevertheless, it is also more difficult for ore forming fluids to penetrate the thick continental crust to reach the depths of 2–4 km where porphyry deposits form.     

First Byurakan Spectral Sky Survey. Stars of Late Spectral Types. XI. Zone -7° ≤ δ ≤ -3°

The eleventh list of faint late M and carbon type stars detected on the plates of the First Byurakan Spectral Survey in zone -7° -3° and covering about 1000 square degrees is presented. From 126 detected stars, 88 are newly discovered objects: they are 6 carbon stars, 8 carbon star candidates, and 74 M-type stars; among the latter 38 (26 PSC + 12 FSC) are unclassified IRAS sources, and one object is an unclassified ROSAT source. Distances to the 6 newly discovered early-type carbon stars are estimated. Equatorial coordinates, red magnitudes, and spectral classes determined from the Palomar E-charts are provided. The lack of optical counterparts on Palomar O and E maps for two detected late M-type stars indicates a large variability in brightnesses of these objects (amplitude not smaller than 7.0 magnitude).     

Impacts of primary deforestation upon limestone slopes in northern Vancouver Island, British Columbia

Effects of deforestation upon slopes in limestones and in volcanic rocks in the Benson River valley, northern Vancouver Island, have been investigated quantitatively. Postlogging soil erosion and vegetal regeneration success were assessed by measuring soil depth, percent bare rock and moss cover, and the numbers and diversity of trees, shrubs, and plants on 25 sampling sites, each containing ten measuring quadrats selected at random. Sixteen sites were on the Quatsino Formation, a well-karstified limestone, and nine on the Karmutsen Formation of basaltic lavas. Eight sites were of virgin forest, 16 were logged between 1970 and 1983, and one (on limestone) was logged in 1911. Both bedrock types were significantly affected by the cutting. There was greater loss of soil and an increase in bare rock on the limestones. Erosion was increased significantly by burning on the limestones but not on the volcanics. Within-group comparisons on the limestones determined that steeper slopes and harder burned areas suffered the most and are slowest to regenerate. Volume of timber on the 1911 site was 19 percent of that in similar uncut forest sites. It appears that complete recovery on the barren limestone slopes will require at least some centuries.     

Distinct metamorphic evolution of alternating silica-saturated and silica-deficient microdomains within garnet in ultrahigh-temperature granulites: An example from Sri Lanka

Here we report the occurrence of garnet porphyroblasts that have overgrown alternating silica-saturated and silica deficient microdomains via different mineral reactions. The samples were collected from ultrahigh-temperature (UHT) metapelites in the Highland Complex, Sri Lanka. In some of the metapelites, garnet crystals have cores formed via a dehydration reaction, which had taken place at silica-saturated microdomains and mantle to rim areas formed via a dehydration reaction at silica-deficient microdomains. In contrast, some other garnets in the same rock cores had formed via a dehydration reaction which occurred at silica-deficient microdomains while mantle to rim areas formed via a dehydration reaction at silica-saturated microdomains. Based on the textural observations, we conclude that the studied garnets have grown across different effective bulk compositional microdomains during the prograde evolution. These microdomains could represent heterogeneous compositional layers (paleobedding/laminations) in the precursor sediments or differentiated crenulation cleavages that existed during prograde metamorphism. UHT metamorphism associated with strong ductile deformation, metamorphic differentiation and crystallization of locally produced melt may have obliterated the evidence for such microdomains in the matrix. The lack of significant compositional zoning in garnet probably due to self-diffusion during UHT metamorphism had left mineral inclusions as the sole evidence for earlier microdomains with contrasting chemistry.     

THREE-WAY METHODS FOR THE CALIBRATION OF CHROMATOGRAPHIC SYSTEMS:COMPARING PARAFAC AND THREE-WAY PLS

For the calibration of chromatographic systems,different methods can be used.One class of methodsutilizes three-way approaches.The calibration problem is stated in such a way that the decompositionof a three-way array can serve for the prediction of retention on new stationary phases.Two three-way approaches are presented:the Unfold-PCA and PARAFAC models.The theory ofboth methods is presented and the differences are highlighted,the main difference being that PARAFACis a trilinear decomposition whereas Unfold-PCA is not.Both three-way methods are evaluated on asmall data set consisting of retention measurements of eight solutes at six mobile phase compositions onsix stationary phases.The differences in performance of the two models are minor,For calibration purposes,two variants of the methods are discussed:three-way PLS and an extensionof PARAFAC.Again the theory and differences between the two methods are explained.The predictiveperformance of the two methods is compared using the same data set as earlier.The differences inpredictive performance,however,are minor.Both methods are capable of predicting 98% of thevariation in the test sets.Yet,there are other considerations when comparing methods than predictiveperformance,e.g.the quality of the predictions.     

Biogeochemical records of paleoenvironmental changes in Nainital Lake,Kumaun Himalayas,India

Rapid urbanization and increased tourism around Nainital Lake in the Kumaun Himalayan region in north India has raised concerns about sediment and water pollution. Lead-210 dated sediment cores from the lake represent ~95 years of accumulation and yield a mean sedimentation rate of ~4.7 mm year⁻¹. Total organic carbon (TOC), percent N and S and their atomic C/N and C/S ratios, stable isotopes (δ¹³C, δ¹⁵N, and δ³⁴S), and specific biomarkers (n-alkanes and pigments) were measured in the core. Organic matter is primarily derived from in-lake algal production and TOC flux varies from 1.0 to 3.5 g m⁻² year⁻¹. Sediments are anoxic (Eh −328 to −187 mV) and have low (0.10–0.30 g m⁻² year⁻¹) N, but high (0.37–1.0 g m⁻² year⁻¹) S flux. Shifts in δ¹³C, δ¹⁵N, and δ³⁴S suggest in-lake microbial processes dominated by denitrification and sulfate reduction. The sediments are dominated by short-chain hydrocarbons with low Carbon Preference Index values. The pigments indicate a gradual shift to cyanobacterial domination of the phytoplankton community in recent years. Despite an increase in external input of nutrients, the trophic state of the lake has remained largely unchanged, and the perceived human-induced impacts are limited.     

The development of three-dimensional current system during a magnetospheric substorm

It is suggested that the pattern of three-dimensional substorm current circuit varies significantly even during the lifetime of a single substorm. This gives rise to quite complex time variations of the magnetic field at low latitude stations even for relatively isolated substorms. To verify this, three-dimensional current models with time dependent spatial variations are used to simulate one type of complex low-latitude “substorm signature”. It is shown that the utmost care should be exercised in determining different substorm phases on the basis of such a signature. The results indicate also that, in certain longitudes in the evening sector, one should expect distinct differences in characteristics between positive bays observed on the ground and at the synchronous distance.