Fluid production and isograd reactions at contacts of carbonate-rich and carbonate-poor layers during progressive metamorphism

ABSTRACT With increasing temperature during prograde metamorphism reactions will occur first at the lithological contacts of mixed pelite and calcsilicate terranes. At these interfaces, a fluid of lower chemical potential of H₂O and CO₂ than that required to produce a fluid in either layer can be produced whether reaction is caused by fluid infiltration or is initially fluid absent. If the interface region does not allow fluid transport then as temperature increases, a fluid pressure greater than lithostatic can develop. At some degree of over-pressure relative to rock pressure, the fluid hydraulically fractures the rock and a gradient in fluid composition away from the contact can be produced. These phenomena occur at the compositional interfaces whenever univariant reactions in the differing layers cross on a temperature vs. mole fraction of CO₂ diagram with slopes of opposite sign. The first occurrence of these reaction products at lithological contacts delineates an isograd that defines temperature as well as the mole fraction of CO₂ at constant pressure in systems open to fluid transport. These isograds can be contrasted with fluid-producing isograds in closed systems. As an illustration of possible effects, the reactions quartz + clinozoisite + muscovite = anorthite + K-feldspar + H₂O and phlogopite + quartz + calcite = tremolite + K-feldspar + H₂O + CO₂ at 4 kbar are analysed and equations for fluid production and transport are developed.     

Fayalitic olivine in matrix of the Krymka LL3.1 chondrite: Vapor-solid growth in the solar nebula

Abstract— Fayalitic olivine (Fa_54–94) is a ubiquitous component in the matrix of Krymka (LL3.1) as well as in other highly unequilibrated chondrites (ordinary and carbonaceous). In Krymka, the fayalitic olivine has an unusual anisotropic platy morphology that occurs in at least five types of textural settings that can be characterized as: (1) isolated platelets, (2) clusters of platelets, (3) euhedral to subhedral crystals, (4) overgrowths of platelets on forsteritic olivine, and (5) fluffy (porous) aggregates. From transmission electron microscope (TEM) investigation, the direction of elongation of the platy olivine overgrowths on forsteritic olivine substrates is along the c axis and in most cases it corresponds with the c axis of the substrate olivine, which suggests that the fayalitic olivine grew in this unusual morphology and is not a replacement product of preexisting material. The fayalitic olivine in the matrix of Krymka is compositionally similar to olivine with platy morphology in the matrix of some CV3 chondrites and both have similar Fe/Mn ratios, but important morphological differences indicate that their relationship needs to be explored further. Textural and compositional data indicate that the fayalitic olivine in the matrix of Krymka, as well as in some other unequilibrated ordinary chondrites, formed prior to final lithification of the meteorite and probably prior to parent body accretion. We find that formation of the fayalitic olivine by vapor-solid growth provides the best explanation for our observations and data and is the only feasible mechanism for the formation of fayalitic olivine in the matrix of Krymka. We propose that the fayalitic olivine formed by vaporization and recondensation of olivine rich-dust, during a period of enhanced dust/gas ratio in the nebula.     

Climatic changes in central and eastern Canada inferred from deep borehole temperature data

We analyzed data from 23 boreholes at 19 sites in central and eastern Canada, for the purpose of estimating ground surface temperature (GST) histories. These boreholes were logged down to at least 550 m depth with thermistor probes. Thermal conductivity measurements had been previously made at small depth intervals for the entire depth ranges of most of the boreholes. The temperature profiles of these boreholes do not indicate water disturbance. We estimated terrain effects for each borehole using a time dependent solid-angle method. The thermal perturbations caused by lakes or deforestation near the borehole sites are insignificant in most cases. However, four of the holes were found to be severely influenced by terrain effects. GSTs estimated from the borehole data less influenced by the terraineffects form two groups. The first group, which are generally from data of better quality, show a cold period near the end of the last century before the recent warming trend; the second show it 80–100 years earlier. We consider the former typical of the climate of the Boreal climatic region of Canada. The difference between the two groups may reflect the spacial variability of the climate. Four GST estimates do not belong to either type, and the reasons are discussed.     

SHRIMP U–Pb ages of diagenetic and hydrothermal xenotime from the Archaean Witwatersrand Supergroup of South Africa

SHRIMP dating of xenotime overgrowths on detrital zircon grains can constrain maximum durations since diagenesis and therefore provide minimum dates of sediment deposition. Thus, xenotime dating has significant economic application to Precambrian sediment-hosted ore deposits, such as Witwatersrand Au–U, for which there are no precise depositional ages. The growth history of xenotime in the Witwatersrand Supergroup is texturally complex, with several phases evident. The oldest authigenic xenotime ²⁰⁷Pb/²⁰⁶Pb age obtained in sandstone underlying the Vaal Reef is 2764 ± 5 Myr (1 σ), and most likely represents a mixture of diagenetic and hydrothermal growth. Nevertheless, this represents the oldest authigenic mineral age yet recorded in the sequence and provides a minimum age of deposition. Other xenotime data record a spread of ages that correspond to numerous post-diagenetic thermotectonic events (including a Ventersdorp event at ≈ 2720 Ma) up to the ≈2020 Ma Vredefort event.     

A study on quality of aquatic environment in Tumen River Area

After the survey of pollution sources, a study on surface water quality assessment and forecast is given by means of grey system method, fuzzy mathematical method and multiple-index method. Based on it, aquatic environment quality features, treatment measures and environmental strategies of the area are proposed. The quality of aquatic environment of 5 rivers in the Tumen River area is studied. The results show that the pollution of surface water is serious; water quality of most rivers is between grade IV and V except the Hunchun River, being higher than grade IV standard; pollution levels of most rivers have been basically controlled except the of Burhatong River, which is deteriorating gradually. Pollutants of the rivers are comparatively regular, mainly are SS, COD, BOD, AR-OH, NH₃-N. The main pollution trades are chemical fibre industry, pulp and paper making industry and mining industry. If the growth rate of gross industrial product is higher than 25 percent under the encouraging-model of regional exploitation, the pollutants’ load will overtake the bearing capacity of aquatic environment. Thus some protection program against pollution must be worked out in order to achieve the harmonious development of economy society and environment. A project from “Studies on Earlier Stage of Regional Development” of the Chinese Academy of Sciences     

The mass ratio of Nova Muscae 1991

We report intermediate resolution H spectroscopy of the black hole candidate Nova Muscae 1991 during quiescence. We classify the companion star as a K3-K4V which contributes 85±6 percent to the total flux from the binary. The photospheric absorption lines are broadened by 106±13 kms⁻¹ with respect to template field stars, leading to a system mass ratio of q =M₁/M₂ = 7.8_−2.0^+3.4. Doppler imaging of the H line shows strong emission coming from the secondary star (EW=3.1±0.6Å) which we associate with chromospheric activity. However, the hot-spot is not detected and this may indicate a lower mass transfer rate than in other X-ray transients of comparable orbital periods. The surface brightness distribution of the accretion disk in H follows a relation I∝R^−1.1, less steep than typically observed in cataclysmic variables. Updated system parameters are also presented.