Effect of atmospheric pressure and temperature on entrapped gas content in peat

Entrapped biogenic gas in peat can greatly affect peatland biogeochemical and hydrological processes by altering volumetric water content, peat buoyancy, and ‘saturated’ hydraulic conductivity, and by generating over‐pressure zones. These over‐pressure zones further affect hydraulic gradients which influence water and nutrient flow direction and rate. The dynamics of entrapped gas are of global interest because the loss of this gas to the atmosphere via ebullition (bubbling) is likely the dominant transport mechanism of methane (CH₄) to the atmosphere from peatlands, which are the largest natural terrestrial source per annum of atmospheric CH₄. We investigated the relationship between atmospheric pressure and temperature on volumetric gas content (VGC) and CH₄ ebullition using a laboratory peat core incubation experiment. Peat cores were incubated at three temperatures (one core at 4 °C, three cores at 11 °C, and one core at 20 °C) in sealed PVC cylinders, instrumented to measure VGC, pore‐water CH₄ concentrations, and ebullition (volume and CH₄ concentrations). Ebullition events primarily occurred (71% of the time) during periods of falling atmospheric pressure. The duration of the drop in atmospheric pressure had a larger control on ebullition volume than the magnitude of the drop. VGC in the 20 °C core increased from the onset of the experiment and reached a fluctuating but time‐averaged constant level between experiment day 30 and 115. The change in VGC was low for the 11 °C cores for the initial period of the experiment but showed large increases when the growth chamber temperature increased to 20 °C due to a malfunction. The core maintained at 4 °C showed only a small increase in entrapped gas content throughout the experiment. The 20 °C core showed the largest increase in VGC. The increases in VGC occurred despite pore‐water concentrations of CH₄ being below the equilibrium solubility level. Copyright © 2009 John Wiley & Sons, Ltd.     

Data collection methodology for dynamic temperature model testing and corroboration

This article describes a data collection approach for determining the significance of individual heat fluxes within streams with an emphasis on testing (i.e. identification of possible missing heat fluxes), development, calibration and corroboration of a dynamic temperature model. The basis for developing this approach was a preliminary temperature modelling effort on the Virgin River in southwestern Utah during a low‐flow period that suggested important components of the energy balance might be missing in the original standard surface‐flux temperature model. Possible missing heat fluxes were identified as bed conduction, hyporheic exchange, dead zone warming and exchange and poor representation of the amount of solar radiation entering the water column. To identify and estimate the relative importance of the missing components, a comprehensive data collection effort was developed and implemented. In particular, a method for measuring shortwave radiation behaviour in the water column and an in situ method for separating out bed conduction and hyporheic influences were established. The resulting data and subsequent modelling effort indicate that hyporheic and dead zone heat fluxes are important, whereas solar radiation reflection at the water surface was found to be insignificant. Although bed conduction can be significant in certain rivers, it was found to have little effect on the overall heat budget for this section of the Virgin River. Copyright © 2009 John Wiley & Sons, Ltd.     

Large scale failure of the external waste dump at the “South Field” lignite mine, Northern Greece

This paper presents the failure process of the external waste dump of the South Field Mine, the major open pit mine in Greece. The waste materials of the mine were deposited in three phases, forming an average inclination slope 10% and a total height of 110 m from the ground surface. The failure occurred when the third phase of the deposit was initiated. The high moisture content of the waste materials and their deposition over a spring, choking its flow, had as a result the development of high pore water pressure in clayey and marly materials in the base of the deposit. As a consequence, a large scale slope failure incident occurred. The landslide involved the mobilization of waste material in the order of 40 Mm³, while the material that moved outside the boundaries of the waste dump was in the order of 2.5 Mm³. The stability of the waste dump was investigated using the limit equilibrium analysis and different types of models.Limit equilibrium analyses were performed using different methods and considering the clay layer of small shear resistance that exists in the base of the deposit. They do not indicate activation of failure mechanism, only that there is a combination of high pore water pressure that developed in the deposit because the covering of the spring with the clayey materials of the dump.     

Accessory mineral U–Th–Pb ages and <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar eruption chronology,and their bearing on rhyolitic magma evolution in the Pleistocene Coso volcanic field,California

We determined Ar/Ar eruption ages of eight extrusions from the Pleistocene Coso volcanic field, a long-lived series of small volume rhyolitic domes in eastern California. Combined with ion-microprobe dating of crystal ages of zircon and allanite from these lavas and from granophyre geothermal well cuttings, we were able to track the range of magma-production rates over the past 650 ka at Coso. In ≤230 ka rhyolites we find no evidence of protracted magma residence or recycled zircon (or allanite) from Pleistocene predecessors. A significant subset of zircon in the ~85 ka rhyolites yielded ages between ~100 and 200 Ma, requiring that generation of at least some rhyolites involves material from Mesozoic basement. Similar zircon xenocrysts are found in an ~200 ka granophyre. The new age constraints imply that magma evolution at Coso can occur rapidly as demonstrated by significant changes in rhyolite composition over short time intervals (≤10’s to 100’s ka). In conjunction with radioisotopic age constraints from other young silicic volcanic fields, dating of Coso rhyolites highlights the fact that at least some (and often the more voluminous) rhyolites are produced relatively rapidly, but that many small-volume rhyolites likely represent separation from long-lived mushy magma bodies.     

Thermodynamic functions of eskolaite Cr<Subscript>2</Subscript>O<Subscript>3</Subscript>(c) at 0–1800 K

The heat capacity of eskolaite Cr₂O₃(c) was determined by adiabatic vacuum calorimetry at 11.99–355.83 K and by differential calorimetry at 320–480 K. Experimental data of the authors and data compiled from the literature were applied to calculate the heat capacity, entropy, and the enthalpy change of Cr₂O₃ within the temperature range of 0–1800 K. These functions have the following values at 298.15 K: C _p ⁰ (298.15) = 121.5 ± 0.2 J K⁻¹mol⁻¹, S ⁰(298.15) = 80.95 ± 0.14 J K⁻¹mol⁻¹, and H ⁰(298.15)-H ⁰(0) = 15.30±0.02 kJ mol⁻¹. Data were obtained on the transitions from the antiferromagnetic to paramagnetic states at 228–457 K; it was determined that this transition has the following parameters: Neel temperature T _N = 307 K, Δ _tr S = 6.11 ± 0.12 J K⁻¹mol⁻¹ and δ _tr H = 1.87 ± 0.04 kJ mol⁻¹.     

Resource Flows of Villages with Contrasting Lifestyles in Nanda Devi Biosphere Reserve, Central Himalaya, India

Resource use efficiency analyses of village ecosystem are necessary for effective and efficient planning of resource utilization. This paper deals with economic and energy input-output analyses of different components of village ecosystem in representative buffer zone villages, which are practicing transhumance and settled way of lifestyles in Nanda Devi Biosphere Reserve （NDBR） of Garhwal Himalaya. While the villages practicing transhumance used various natural resources spatially segregated,the villages practicing settled way of lifestyle have to manage resources from a limited spatial area through rotation and varied extraction intensities. Forests subsidized the production activity in both type of villages and the per capita resource extractions were found to be greater in tran~humance village than settled village. Though crops provided maximum energy, in terms of economic criteria, animal husbandry played important role in both settled and transhumance villages. As villages representing both the situations showed different ways of adjustments to the conservation oriented land use changes, management authority needs to address the eco-development plans fulfilling the aspirations of all people traditionally using the resources of the Reserve to reduce the conflicts and encourage their participation in the conservation of the area.     

Riparian vegetation dynamics across two different landscapes along the river Cauvery in the Kodagu region of Western Ghats

Decades of commercial planting and other anthropogenic processes are posing a threat to the riparian landscapes of the Cauvery river basin, which supports a high floral diversity. Despite this, the habitats in the upstream sections of the River Cauvery are still intact, as they are located in sacred groves. To understand the dynamism of riparian forests exposed to anthropogenic pressures, the upstream stretch of Cauvery extending from Kushalanagara to Talacauvery (~102 km) was categorized into two landscapes: agro ecosystem and sacred (i.e. preserved). The tree species were sampled using belt transects at 5 km intervals and the regeneration status of endemic species assessed using quadrats. A total of 128 species belonging to 47 families, and representing 1,590 individuals, was observed. Amongst them, 65% of unique species were exclusive to sacred landscapes. A rarefaction plot confirmed higher species richness for the sacred compared to the agro ecosystem landscapes, and diversity indices with more evenness in distribution were evident in sacred landscapes. A significant loss of endemic tree species in the agro ecosystem landscapes was found. Overall, this study demonstrates that an intense biotic pressure in terms of plantations and other anthropogenic activities have altered the species composition of the riparian zone in non-sacred areas. A permanent policy implication is required for the conservation of riparian buffers to avoid further ecosystem degradation and loss of biodiversity.     

Metabolic plasticity of nitrogen assimilation by Porphyra umbilicalis (Linnaeus) Kützing

The physical stresses associated with emersion have long been considered major factors determining the vertical zonation of intertidal seaweeds.We examined Porphyra umbilicalis(Linnaeus) Kützing thalli from the vertical extremes in elevation of an intertidal population(i.e.upper and lower intertidal zones) to determine whether Porphyra thalli acclimate to different vertical elevations on the shore with different patterns of nitrate uptake and nitrate reductase(NR) and glutamine synthetase(GS) activities in response to different degrees of emersion stress.We found that the nitrate uptake and NR recovery in the emersed tissues took longer in lower intertidal sub-population than in upper intertidal sub-population;and GS activity was also significantly affected by emersion and,interestingly,such an activity was enhanced by emersion of thalli from both upper and lower intertidal zones.These results suggested that intra-population variability in post-emersion recovery of physiological functions such as nutrient uptake and NR activity enables local adaptation and contributes to the wide vertical distribution of P.umbilicalis.The high GS activity during periodic emersion stress may be a protective mechanism enabling P.umbilicalis to assimilate nitrogen quickly when it again becomes available,and may also be an evidence of photorespiration during emersion.     

Petrography and mineral chemistry of neovolcanics occurring between Pacific and Nazca Plate boundaries

Mid-Oceanic Ridge Basalt (MORB) samples collected from southern East Pacific Rise (SEPR) have been investigated. These highly phyric plagioclase basalts (HPPB) and moderately phyric plagioclase basalts (MOPB) show rare cumulate and vitrophyric textures with plagioclase (>10% as phenocryst) and abundant glass (>72%). Electron Probe Micro Analysis (EPMA) showed large compositional variations in the megacrysts as well as microcrysts of plagioclase (An₆₂ to An₈₂), olivine (Fo₇₈ to Fo₈₇), pyroxene (ferroaugite to augite) and iron oxides, mostly titaniferous magnetite. Olivine grains show high Mg# (>80%) and distinctly low in NiO (0.01–0.2%). Ferroan trevorite (NiO =16.22 and FeO_(t) =83.06) a characteristic meteoritic mineral has been identified from the olivine megacrysts of MORB, possibly attributed to Ni-enrichment, resulted from heterogeneity of the lower mantle. Wide range of An composition in plagioclase is indicative of large pressure range of crystal nucleation under decompression at a depth of ∼70 km (An₈₂) up to the ocean spreading centre. Absence of zoning observed in all the minerals present in the MORB samples, possibly attributed to unmixing and dominant fractionation process.     

Exhumation during oblique transpression: The Feiran–Solaf region, Egypt

The Feiran–Solaf metamorphic complex of Sinai, Egypt, is one of the highest grade metamorphic complexes of a series of basement domes that crop out throughout the Arabian-Nubian Shield. In the Eastern Desert of Egypt these basement domes have been interpreted as metamorphic core complexes exhumed in extensional settings. For the Feiran–Solaf complex an interpretation of the exhumation mechanism is difficult to obtain with structural arguments as all of its margins are obliterated by post-tectonic granites. Here, metamorphic methods are used to investigate its tectonic history and show that the complex was characterized by a single metamorphic cycle experiencing peak metamorphism at ∼700–750 °C and 7–8 kbar and subsequent isothermal decompression to ∼4–5 kbar, followed by near isobaric cooling to 450 °C. Correlation of this metamorphic evolution with the deformation history shows that peak metamorphism occurred prior to the compressive deformation phase D ₂, while the compressive D ₂ and D ₃ deformation occurred during the near isothermal decompression phase of the P–T loop. We interpret the concurrence of decompression of the P–T path and compression by structural shortening as evidence for the Najd fault system exhuming the complex in an oblique transpressive regime. However, final exhumation from ∼15 km depth must have occurred due to an unrelated mechanism.