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291.
Mark A. Engle Michael T. Tate David P. Krabbenhoft Allan Kolker Mark L. Olson Eric S. Edgerton John F. DeWild Ann K. McPherson 《Applied Geochemistry》2008
Concentrations of atmospheric Hg species, elemental Hg (Hg°), reactive gaseous Hg (RGM), and fine particulate Hg (Hg-PM2.5) were measured at a coastal site near Weeks Bay, Alabama from April to August, 2005 and January to May, 2006. Mean concentrations of the species were 1.6 ± 0.3 ng m−3, 4.0 ± 7.5 pg m−3 and 2.7 ± 3.4 pg m−3, respectively. A strong diel pattern was observed for RGM (midday maximum concentrations were up to 92.7 pg m−3), but not for Hg° or Hg-PM2.5. Elevated RGM concentrations (>25 pg m−3) in April and May of 2005 correlated with elevated average daytime O3 concentrations (>55 ppbv) and high light intensity (>500 W m−2). These conditions generally corresponded with mixed continental-Gulf and exclusively continental air mass trajectories. Generally lower, but still elevated, RGM peaks observed in August, 2005 and January–March, 2006 correlated significantly (p < 0.05) with peaks in SO2 concentration and corresponded to periods of high light intensity and lower average daytime O3 concentrations. During these times air masses were dominated by trajectories that originated over the continent. Elevated RGM concentrations likely resulted from photochemical oxidation of Hg° by atmospheric oxidants. This process may have been enhanced in and by the near-shore environment relative to inland sites. The marine boundary layer itself was not found to be a significant source of RGM. 相似文献
292.
N. K. Lebedeva 《Stratigraphy and Geological Correlation》2008,16(2):182-197
The results of palynomorph biofacies analysis in the Upper Cretaceous deposits of the Ust-Yenisei region are presented. The established facies confinement and indicative features of separate palynomorph groups are used, along with identified dinocyst morphotypes and taxa, in paleogeographic reconstructions. Seven palynomorph associations characterizing continental, coastal-marine, shallow-and deep-water facies are distinguished based on quantitative proportions between morphological groupings and individual taxa. As boundaries between distinguishable biostratigraphic and facies subdivisions do not coincide, dinocysts were likely insignificantly dependent in distribution on facies in the West Siberian epicontinental basin at least. On the other hand, distribution trends of particular dinocyst morphotypes and other microphytofossils are correlative with transgressive-regressive cycles and can be used for reconstruction of paleoenvironments. 相似文献
293.
A. A. Nosova O. F. Kuz’menkova N. V. Veretennikov L. G. Petrova L. K. Levsky 《Petrology》2008,16(2):105-135
The reasons for the isotopic and geochemical heterogeneity of magmatism of the Neoproterozoic large Volhynia-Brest igneous province (VBP) are considered. The province was formed at 550 Ma in response to the break up of the Rodinia supercontinent and extends along the western margin of the East European craton, being discordant to the Paleoproterozoic mobile zone that separates Sarmatia and Fennoscandia and the Mesoproterozoic Volhynia-Orsha aulacogen. The basalts of VBP show prominent spatiotemporal geochemical zoning. Based on petrographic, mineralogical, geochemical, and isotopic data, the following types of basalts can be distinguished: olivine-normative subalkaline basalts consisting of low-Ti (sLT, < 1.10–2.0 wt % TiO2; εNd(550) from ?6.6 to ?2.7) and medium-Ti (sMT, 2.0–3.0 wt % TiO2, occasionally up to 3.6 wt % TiO2; εNd(550) from ?3.55 to + 0.6) varieties; normal quartz-normative basalts (tholeiites) including low-Ti (tLT, < 1.75–2.0 wt % TiO2) and medium-to-high-Ti (tHT1, 2.0–3.6 wt % TiO2, εNd(550) from ?1.3 to + 1.0) varieties. The hypabyssal bodies are made up of subalkaline low-Ti olivine dolerites (LT, 1.2–1.5 wt % TiO2; εNd(550) = ?5.8) and subalkaline high-Ti olivine gabbrodolerites (HT2, 3.0–4.5 wt % TiO2; εNd(550) = ?2.5). Felsic rocks of VBP are classed as volcanic rocks of normal (andesidacites, dacites, and rhyodacites) and subalkaline (trachyrhyodacites) series with TiO2 0.72–0.77 wt% and εNd(550) of ?12. The central part of VBP is underlain by a Paleoproterozoic domain formed by continent-arc accretion and contains widespread sills of HT2 dolerites and lavas of LT basalts; the northern part of the province is underlain by the juvenile Paleoproterozoic crust dominated by MT and HT1 basalts. MT and LT basalts underwent significant AFC-style upper crustal contamination. During their long residence in the upper crustal magmatic chambers, the basaltic melts fractionated and caused notable heating of the wall rocks and, correspondingly, nonmodal melting of the upper crustal protolith containing high-Rb phase (biotite), thus producing the most felsic rocks of the province. The basalts of VBP were derived from geochemically different sources: probably, the lithosphere and a deep-seated plume (PREMA type). The HT2 dolerites were generated mainly from a lithospheric source: by 3–4% melting of the geochemically enriched garnet lherzolite mantle. LT dolerites were obtained by partial melting of the modally metasomatized mantle containing volatile-bearing phases. The concepts of VBP formation were summarized in the model of three-stage plume-lithosphere interaction. 相似文献
294.
295.
F. Parello A. Aiuppa H. Calderon F. Calvi D. Cellura V. Martinez M. Militello K. Vammen D. Vinti 《Applied Geochemistry》2008
This paper reports new geochemical data on dissolved major and minor constituents in surface waters and ground waters collected in the Managua region (Nicaragua), and provides a preliminary characterization of the hydrogeochemical processes governing the natural water evolution in this area. The peculiar geological features of the study site, an active tectonic region (Nicaragua Depression) characterized by active volcanism and thermalism, combined with significant anthropogenic pressure, contribute to a complex evolution of water chemistry, which results from the simultaneous action of several geochemical processes such as evaporation, rock leaching, mixing with saline brines of natural or anthropogenic origin. The effect of active thermalism on both surface waters (e.g., saline volcanic lakes) and groundwaters, as a result of mixing with variable proportions of hyper-saline geothermal Na–Cl brines (e.g., Momotombo geothermal plant), accounts for the high salinities and high concentrations of many environmentally-relevant trace elements (As, B, Fe and Mn) in the waters. At the same time the active extensional tectonics of the Managua area favour the interaction with acidic, reduced thermal fluids, followed by extensive leaching of the host rock and the groundwater release of toxic metals (e.g., Ni, Cu). The significant pollution in the area, deriving principally from urban and industrial waste-water, probably also contributes to the aquatic cycling of many trace elements, which attain concentrations above the WHO recommended limits for the elements Ni (∼40 μg/l) and Cu (∼10 μg/l) limiting the potential utilisation of Lake Xolotlan for nearby Managua. 相似文献
296.
297.
J.A. Saunders M.-K. Lee M. Shamsudduha P. Dhakal A. Uddin M.T. Chowdury K.M. Ahmed 《Applied Geochemistry》2008
Here new data from field bioremediation experiments and geochemical modeling are reported to illustrate the principal geochemical behavior of As in anaerobic groundwaters. In the field bioremediation experiments, groundwater in Holocene alluvial aquifers in Bangladesh was amended with labile water-soluble organic C (molasses) and MgSO4 to stimulate metabolism of indigenous SO4-reducing bacteria (SRB). In the USA, the groundwater was contaminated by Zn, Cd and SO4, and contained <10 μg/L As under oxidized conditions, and a mixture of sucrose and methanol were injected to stimulate SRB metabolism. In Bangladesh, groundwater was under moderately reducing conditions and contained ∼10 mg/L Fe and ∼100 μg/L As. In the USA experiment, groundwater rapidly became anaerobic, and dissolved Fe and As increased dramatically (As > 1000 μg/L) under geochemical conditions consistent with bacterial Fe-reducing conditions. With time, groundwater became more reducing and biogenic SO4 reduction began, and Cd and Zn were virtually completely removed due to precipitation of sphalerite (ZnS) and other metal sulfide mineral(s). Following precipitation of chalcophile elements Zn and Cd, the concentrations of Fe and As both began to decrease in groundwater, presumably due to formation of As-bearing FeS/FeS2. By the end of the six-month experiment, dissolved As had returned to below background levels. In the initial Bangladesh experiment, As decreased to virtually zero once biogenic SO4 reduction commenced but increased to pre-experiment level once SO4 reduction ended. In the ongoing experiment, both SO4 and Fe(II) were amended to groundwater to evaluate if FeS/FeS2 formation causes longer-lived As removal. Because As-bearing pyrite is the common product of SRB metabolism in Holocene alluvial aquifers in both the USA and Southeast Asia, it was endeavored to derive thermodynamic data for arsenian pyrite to better predict geochemical processes in naturally reducing groundwaters. Including the new data for arsenian pyrite into Geochemist’s Workbench, its stability field completely dominates in reducing Eh–pH space and “displaces” other As-sulfides (orpiment, realgar) that have been implied to be important in previous modeling exercises and reported in rare field conditions. 相似文献
298.
Prakash C. Sinha Indu Jain Neetu Bhardwaj Ambarukhana D. Rao Shishir K. Dube 《Natural Hazards》2008,45(3):413-427
The Orissa coast of India is one of the most vulnerable regions of extreme sea levels associated with severe tropical cyclones.
There was extensive loss of life and property due to the October 1999 super cyclone, which devastated large part of the Orissa
coast. The shallow nature of the head bay, presence of a large number of deltas formed by major rivers of Orissa such as Mahanadi
and Dhamra, and high tidal range are responsible for storm surge flooding in the region. Specifically, rising and falling
tidal phases influence the height, duration, and arrival time of peak surge along the coast. The objective of the present
study is to evaluate the tide-surge interaction during the 1999 Orissa cyclone by using nonlinear vertically integrated numerical
models. The pure tidal solution for the head bay region of the Bay of Bengal provides the initial condition for the fine resolution
nested grid Orissa model. However, the feedback from the Orissa model does not affect the head bay model as the study provides
a one-way interaction. Numerical experiments are performed to study the tide-surge interaction by considering various relative
phases of the tidal waves with the surge-wave produced by 1999 Orissa cyclone. The comparison, although utilizing only the
limited estimates of tidal data, appears adequate to assert that the principal features are reproduced correctly. 相似文献
299.
The Nordic geological surveys: Geology for society in practice 总被引:1,自引:0,他引:1
Morten Smelror Andreas AhlstrФm Lena Ekelund Jens Morten Hansen Keijo Nenonen Anette K. Mortensen 《《幕》》2008,31(1):193-200
Since the mid-nineteenth century., when the first of the Nordic Geological Surveys were established, they have generated a substantial amount of information on the Earth's crust, its natural resources, its processes, and on the geological history of Nordic areas. The collective mission of the geological surveys is to carry out "Geology for Society", by doing research and providing services, and by making geological information and data easily accessible to all the varied end users in industry, government agencies, government institutes, public administrations, technical offices, academia and research institutes, as well as for private individuals. The present paper gives a brief overview of a few, selected, research areas and projects currently undertaken by the Nordic geological surveys. These serve as practical examples of how the Nordic geological surveys address important societal problems and challenges that require geological input for their solution. 相似文献
300.
H. M. Hussein K. M. Abou Elenean I. A. Marzouk A. Peresan I. M. Korrat E. Abu El-Nader G. F. Panza M. N. El-Gabry 《Natural Hazards》2008,47(3):525-546
The aim of the present work is to compile and update a catalogue of the instrumentally recorded earthquakes in Egypt, with
uniform and homogeneous source parameters as required for the analysis of seismicity and seismic hazard assessment. This in
turn requires a detailed analysis and comparison of the properties of different available sources, including the distribution
of events with time, the magnitude completeness, and the scaling relations between different kinds of magnitude reported by
different agencies. The observational data cover the time interval 1900–2004 and an area between 22°–33.5° N and 25°–36° E.
The linear regressions between various magnitude types have been evaluated for different magnitude ranges. Using the best
linear relationship determined for each available pair of magnitudes, as well as those identified between the magnitudes and
the seismic moment, we convert the different magnitude types into moment magnitudes M
W, through a multi-step conversion process. Analysis of the catalogue completeness, based on the M
W thus estimated, allows us to identify two different time intervals with homogeneous properties. The first one (1900–1984)
appears to be complete for M
W ≥ 4.5, while the second one (1985–2004) can be considered complete for magnitudes M
W ≥ 3. 相似文献