Photoelectron fluxes in cometary atmospheres

The photoelectron fluxes in cometary atmospheres are calculated by a Monte Carlo method. This is the first quantitative model calculation of this kind. A pure H₂O atmosphere is assumed with a sublimation rate of 10³⁰ molecules sec^?1 at 1 AU. Discussions of the energetics of electron gas and of the elementary collisional processes in determining the fluxes largely concern this water atmosphere. Influences on the photoelectron fluxes are also investigated for CO, another possible constituent. The excitation rate of the ${}^1\text{D}$ level of atomic oxygen in electron impacts is evaluated. It is highly improbable that the photoelectrons are responsible for the observed 6300 Å emission of the order of 1 kR at a heliocentric distance of 1 AU. The structure of the heat equation for thermal electrons is analyzed and a drastic change of the plasma behavior within the coma region is expected.     

A surface complexation model for cadmium and lead adsorption onto diatom surface

This work is devoted to the physico-chemical study of cadmium and lead interaction with diatom–water interfaces for two marine planktonic (Thalassiosira weissflogii = TW, Skeletonema costatum = SC) and two freshwater periphytic species (Achnanthidium minutissimum = AMIN, Navicula minima = NMIN) by combining adsorption measurements with surface complexation modeling. Reversible adsorption experiments were performed at 20 °C after 3 h of exposure as a function of pH, metal concentration in solution, and ionic strength. While the shape of pH-dependent adsorption edge is similar among all four diatom species, the constant-pH adsorption isotherm and maximal binding capacities differ. These observations allowed us to construct a surface complexation model for cadmium and lead binding by diatom surfaces that postulates the constant capacitance of the electric double layer and considers Cd and Pb complexation with mainly carboxylic and, partially, silanol groups. Parameters of this model are in agreement with previous acid–base titration results and allow quantitative reproduction of all adsorption experiments.     

Controls on low-pressure anatexis

Low-pressure anatexis, whereby rocks melt in place after passing through the andalusite stability field, develops under more restricted conditions than does low-pressure metamorphism. Our thermal modelling and review of published work indicate that the following mechanisms, operating alone, may induce anatexis in typical pelitic rocks without inducing wholesale melting in the lower crust: (i) magmatic advection by pervasive flow; (ii) crustal-scale detachment faulting; and (iii) the presence of a high heat-producing layer. Of these, only magmatic advection by pervasive flow and crustal-scale detachment faulting have been shown quantitatively to provide sufficient heat to cause widespread melting. Combinations of the above mechanisms with pluton-scale magmatic advection, shear heating, removal of the lithospheric mantle, or with each other provide additional means of developing suitable high temperatures at shallow crustal levels to generate low-pressure anatexis.