Research on comprehensive carrying capacity of Beijing–Tianjin–Hebei region based on state-space method

Based on state-space method and component analysis, this paper builds a comprehensive evaluation system of carrying capacity for the Beijing–Tianjin–Hebei region from four aspects, namely economy, environment, ecology and energy. The results show that the comprehensive carrying capacity in this region gradually rises in recent years and the economic carrying capacity plays an important role in this situation. Ecological and environmental carrying capacity are gradually enhanced but still affected by water shortages. The energy carrying capacity of this region is low, which is the major factor restricting its sustainable development. Based on the empirical results, following policy suggestions should be adopted: Firstly, local government should accelerate technological progress, promoting the optimization and upgrading of industrial structure; Secondly, the contradiction between supply and demand of water resource should be solved gradually; thirdly, government should develop recycling economy, realizing the coordinated development of economy and environment; last but not least, saving energy and improving energy efficiency.     

Modification of strain wedge method for lateral soil-pile interaction in sandEI北大核心CSCD

A modified strain wedge (SW) method for analyzing the behavior of laterally loaded single piles in sand is proposed. The modified model assumes that the lateral displacements of a pile behind the three-dimensional passive soil wedge are nonlinear, which makes the horizontal soil strain variable with depths instead of a constant value in the original strain wedge model, and also employs two different hyperbolic models, one for describing horizontal stress increment-strain behavior of soil in the wedge, and the other for describing the shear stress-displacement property at the interface between soil and pile shafts. An example is analyzed to demonstrate the effectiveness of the modified method, and a good agreement is obtained. Finally, the effects of modifications on the lateral bearing capacity of pile shafts are discussed. The results show that the problem of overestimating the lateral bearing capacity of piles with strain wedge method can be ameliorated by introducing the assumption of nonlinear lateral displacements of piles. It makes the SW method more convenient and effective in analyzing the behavior of laterally loaded piles by introducing the new relationships of horizontal stress increment-strain and shear stress-displacement.     

底水油层水平井产液剖面均衡性评价

胜利油田开采底水特征高含水油层的水平井数量多,其中油层向水平井非均衡供液现象普遍。为评价此类水平井产液剖面均衡性,量化其生产动态改善潜力,定义了产液剖面基尼系数GN,并结合现场案例介绍其计算方法,随后统计胜利油田60口样本井,分析GN对见水时间tRL和底水突破前累积产油量QRL的影响,最后据此对GN分级。计算和分析结果表明:GN可以整体表征实际非均衡产液剖面偏离理想均衡产液剖面的程度,通常取值0~1之间,数值越大,均衡性越差;划分GN0.1为产液剖面不均衡,其样本井数54口,占比90%,以理想均衡产液状态为基准,tRL和QRL分别至少有100%和69.5%的提升潜力。     

The effect of slight to minor biodegradation on C<Subscript>6</Subscript> to C<Subscript>7</Subscript> light hydrocarbons in crude oils: a case study from Dawanqi Oilfield in the Tarim Basin,NW China

Light hydrocarbons (LHs) are one of the main petroleum fractions in crude oils, and carry much information regarding the genetic origin and alteration of crude oils. But secondary alterations—especially biodegradation—have a significant effect on the composition of LHs in crude oils. Because most of the LHs affected in oils underwent only slight biodegradation (rank 1 on the biodegradation scale), the variation of LHs can be used to describe more the refined features of biodegradation. Here, 23 crude oils from the Dawanqi Oilfield in the Tarim Basin, NW China, eleven of which have been biodegraded to different extents, were analyzed in order to investigate the effect of slight to minor biodegradation on C₆–C₇ LHs. The study results showed that biodegradation resulted in the prior depletion of straight-chained alkanes, followed by branched alkanes. In slight and minor biodegraded oils, such biodegradation scale could not sufficiently affect C₆–C₇ cycloalkanes. For branched C₆–C₇ alkanes, generally, monomethylalkanes are biodegraded earlier than dimethylalkanes and trimethylalkanes, which indicates that branched alkanes are more resistant to biodegradation, with the increase of substituted methyl groups on parent rings. The degree of alkylation is one of the primary controlling factors on the biodegradation of C₆–C₇ LHs. There is a particular case: although 2,2,3-trimethylbutane has a relative higher alkylation degree, 2,2-dimethylpentane is more resistant to biodegradation than 2,2,3-trimethylbutane. 2,2-Dimethylpentane is the most resistant to biodegradation in branched C₆–C₇ alkanes. Furthermore, the 2-methylpentane/3-methylpentane and 2-methylhexane/3-methylhexane ratios decreased steadily with increasing biodegradation, which implies that isomers of bilateral methyl groups are more prone to bacterial attack relative to mid-chain isomers. The position of the alkyls on the carbon skeleton is also one of the critical factors controlling the rate of biodegradation. With increasing biodegradation, Mango’s LH parameters K1 values decrease and K2 values increase, the values of n-heptane and isoheptane decrease, and the indices of methylcyclohexane and cyclohexane increase. LH parameters should be applied cautiously for the biodegraded oils. Because biodegraded samples belong to slight or minor biodegraded oils, the values of n-heptane and isoheptane from Dawanqi Oilfield can better reflect and determine the “Biodegraded” zone. When the heptane value is 0–21 and the isoheptane value is 0–2.6, the crude oil in Dawanqi Oilfield is defined as the “Biodegraded” zone.     

Nuclear field shift effects on stable isotope fractionation: a review

An anomalous isotope effect exists in many heavy element isotope systems (e.g., Sr, Gd, Zn, U). This effect used to be called the “odd–even isotope effect” because the odd mass number isotopes behave differently from the even mass number isotopes. This mass-independent isotope fractionation driving force, which originates from the difference in the ground-state electronic energies caused by differences in nuclear size and shape, is currently denoted as the nuclear field shift effect (NFSE). It is found that the NFSE can drive isotope fractionation of some heavy elements (e.g., Hg, Tl, U) to an astonishing degree, far more than the magnitude caused by the conventional mass-dependent effect (MDE). For light elements, the MDE is the dominant factor in isotope fractionation, while the NFSE is neglectable. Furthermore, the MDE and the NFSE both decrease as temperatures increase, though at different rates. The MDE decreases rapidly with a factor of 1/T², while the NFSE decreases slowly with a factor of 1/T. As a result, even at high temperatures, the NFSE is still significant for many heavy element isotope systems. In this review paper, we begin with an introduction of the basic concept of the NSFE, including its history and recent progress, and follow with the potential implications of the inclusion of the NFSE into the kinetic isotope fractionation effect (KIE) and heavy isotope geochronology.     

昭通示范区黄金坝气田五峰—龙马溪组页岩气储层地质特征

昭通国家级页岩气示范区黄金坝气田是继礁石坝和长宁—威远之后中国又一个在页岩气勘探、开发领域实现重大突破的地区,为了系统地展示黄金坝气田页岩气资源富集的储层条件,为未来的勘探工作提供参考,以五峰—龙马溪组页岩气储层为研究对象,从区域地质条件、储层岩石学、物性和地球化学4个方面对该页岩气储层进行了综合研究。结果表明稳定的区域构造和良好的顶底板条件是黄金坝地区页岩气资源富集的关键,良好的保存条件使储层维持了较高的压力(压力系数1);较高的孔隙度(平均4%)和TOC含量(目的层2%)提供了良好的储集空间,使储层具有较高的含气量(1.35~3.48 cm3/g,平均2.50 cm3/g);天然气地球化学数据表明,区内天然气主要成分为CH4(97%),其次还含有少量的C2H6、C3H8和CO2;天然气同位素数据表明烃类C同位素组成发生了倒转,表明储层具有良好的封闭性。但储层孔隙系统较为复杂,且非均质性极强,从而导致渗透率较低,在储层改造施工过程中应予以充分考虑。总体上,黄金坝气田具有较好的开发前景,生产测试表明,区内直井压裂产量为0.5×104~3.5×104m3/d/井,水平井压裂产量可达12×104~40×104m3/d/井。     

涉及埃达克岩实验的若干基本概念与问题辨析

根据热力学原理,部分熔融是相变的一种表现形式。当岩石沿p-T轨迹穿过固相线时即可发生熔融。自然界岩石常见的不一致熔融行为可以导致残留相具有不同于源岩的整体成分与矿物组合。残留相与源岩可以属于不同的变质相,岩性也可以不同。"C型埃达克岩"含有含水矿物,它们不是干体系熔融的产物。实验岩石学研究表明,基性成分(SiO_250%)体系较中性、酸性体系在1.0~2.0 GPa压力条件下失水熔融时更易于形成"榴辉岩质"的残留相。源岩除SiO_2以外的其它主要氧化物会影响残留相中各矿物的比例,进而影响熔体的Sr、Y及HREE含量。因此,"C型埃达克岩"高Sr低HREE特征的形成取决于熔融温压条件以及源岩的主量元素、微量元素组成等多重因素。高钾含量(K_2O≈1.0%)的基性、中基性源岩形成的熔体成分与"C型埃达克岩"相比过于富Al或富Na。中等富钾的基性源岩的低程度熔融可以形成高硅的"C型埃达克岩",但无法形成中性的"C型埃达克岩"。     

云南建水煌斑岩年代学和地球化学及其构造意义

华南大陆内部燕山期的岩浆事件可分为2期:燕山早期180~150 Ma,燕山晚期140~80 Ma。而处于扬子板块西南缘的滇黔贵等地,仅见有第二期晚白垩世中酸性侵入岩与相关成矿作用,缺乏第一期岩浆活动的时间记录。本文在滇东建水地区首次发现了麦地村煌斑岩,对其进行高精度LA-ICP-MS锆石U-Pb定年和主微量元素测试分析。结果显示煌斑岩的锆石U-Pb年龄为(158.4±2.4)Ma(MSWD=4.2),为晚侏罗世的产物,补充了该区较为空白的第一期岩浆热事件。麦地村煌斑岩不相容元素明显高于原始地幔,表现出不同程度的富集,大离子亲石元素Rb、Ba、Ce等富集程度不明显,高场强元素中U、Ta、Pb等表现出一定程度富集,LREE相对富集,HREE相对亏损,不具有Nb-Ta-Ti负异常的俯冲型配分曲线特征,具有明显的OIB型洋岛玄武岩稀土元素配分特征,为板内伸展环境下的产物。滇东地区发育中生代时期的NNE构造,早期NNE向褶皱叠加有后期同方向正断层。早期褶皱表现为SEE-NWW挤压应力作用下的构造特征,后期断层表现出同方向张应力作用下的特征。煌斑岩正是由于该区发生挤压之后伴随着一期应力松弛调整,伸展减压作用诱发地幔物质部分融熔,来自于深处的软流圈地幔流体与岩石圈地幔发生交代作用,形成富集型地幔,交代富集的岩石圈地幔局部受热、部分熔融,发生上升侵位。煌斑岩的侵位时间即是滇东地区中生代从挤压向伸展转换的起始时间。     

Recognition of the early permian volcanic rocks and Its geological significance in chifeng region of inner Mongolia北大核心CSCD

In order to investigate the geological significance of the large area of volcanics in the Uplift bell of Mingshan in western Chifeng,When carrying out the I :5 million regional mineral geological survey in the area,Through the research work of field geology investigation, petrology, LA-1CP-MS zircon U-Pb isotopic dating and regional stratigraphic correlation and so on.Found that the volcano rocks in the area is different from the Late Jurassic-Early Cretaceous volcanic rocks. And the obvious green alteration phenomenon was developed : The dating results of the Hornblende andesite in the lower parts is 273. 6±2. 2 Ma,it should belong to the Permian Elitu formation^ The Volcanics in the area belong to Calc-Alkaline-high-k calc-Alkaline series volcanic rocks. And volcanic magma experienced the separation and crystallization of minerals, it was the product of the continuous evolution of cognate magma, having the Characteristics that from bottom to top Intermediate-Mafic to Acidic magmatic evolution and the REE content increased gradually 0 Studies suggest that the Formation of volcanic rocks in the area is related to the ancient Asian Ocean to the North China block subduction in the Late Paleozoic period . It should be formed in the Archean to Proterozoic crystalline basement and late devonian magma Kemelting eruption, the tectonic environment formation of the volcanics in this area was andreessen arcc.