单体分子放射性碳同位素分析在海洋科学及环境科学研究中的应用

单体分子放射性碳同位素分析(CSRA)是近十几年来发展起来的一项新兴的分析手段,将所需的单体分子(生物标志物)从复杂的环境样品基质中分离并富集,再进行加速质谱仪(AMS)的放射性碳(14C)测定。这种分子水平的放射性碳同位素测定技术能够揭示出总有机质同位素组成的异质性,为解释有机碳的来源、迁移和转化等提供了新型的手段。在海洋科学研究中,单体分子放射性碳同位素分析已应用于计算碳在全球各储库的逗留时间并揭示和定量估算化石源有机碳的输入、指示沉积物的搬运过程、示踪微生物的代谢途径、改进沉积物年代学等;在环境科学研究中,单体分子放射性碳同位素分析可用于有毒物质(如多环芳烃)的源解析,示踪有机污染环境中微生物的代谢途径等。伴随着单体分子分离技术的改进及AMS灵敏度的提高,CSRA技术的应用会更加广泛。     

Defining the geochemical baseline: a case of Hong Kong soils

A geochemical baseline provides the means to distinguish between the pedogenic origin and the anthropogenic origin of the trace element in the environmental compartments. We collected 271 soil samples representative of different parent rocks and soil types from the whole territory of Hong Kong and analyzed the composition of clay mineralogy and the contents of 15 chemical elements (Fe, Cd, As, etc.) for these samples. The baseline was predicted with the method of the normalization procedure combined with the relative cumulative frequency curve. The result indicated that Fe was the best reference element for the normalization procedure among the five potential reference elements (Fe, Al, Sc, Ti, and Mn), followed by Sc and Ti. A poor correlation was found between Sc, Ti, and Cu. The predicted baseline was much lower than the A-value of the Dutch List used usually in screening the polluted soil of Hong Kong, implying that the extent of heavy metal pollution might have been underestimated with respect to local lands. We also applied the cluster analysis to distinguish the geochemical associations of the trace elements due to its importance to the baseline. Approximately three major associations including the Fe–Mn-oxides related, Al oxides or Al-bearing-clay-mineralogy related and sulfide- related associations were observed from the dendrogram.     

青岛榴辉岩及胶南群片麻岩的锆石U-Pb 年龄——胶南群中晋宁期岩浆事件的证据

研究表明，苏鲁地体是扬子与华北陆-陆碰撞造山带的一部分（东段）。其主要变质岩系——胶南群，是扬子陆块北缘俯冲陆壳的基底。在已有的文献中，人们均将胶南群划为早、中元古代地体。组成胶南群的主要岩石是长英质片麻岩，在其中间包含有少量斜长角闪岩、大理岩、超镁铁岩和榴辉岩。大量的Sm-Nd 及 40Ar/39Ar 同位素定年已证明了，胶南群在三叠纪时，经历了与华北和扬子陆块碰撞有关的高压或超高压变质作用，原岩的时代缺乏可靠的年龄测定，被认为是早、中元古代岩石。然而最近我们对青岛附近仰口的退变质榴辉岩及胶南群片麻岩的     

云南省新平县哀牢山地区富硒土壤成因及其影响因素研究

以云南省新平县者竜—戛洒地区1∶5万土地质量地球化学调查评价结果为基础,对该地区富硒土壤的成因及其影响因素进行分析,结果表明,研究区土壤硒平均含量为0.38 mg/kg,高于全国土壤硒平均含量0.29 mg/kg,按0.4 mg/kg相似文献   

猪野泽记录的季风边缘区全新世中期 气候环境演化历史*

通过季风边缘区石羊河古终端湖猪野泽QTL剖面年代学及沉积物粒度、碳酸盐、有机碳、碳氮比和有机质稳定同位素等多项气候代用指标的综合分析,建立了季风边缘区9~3cal.kaB.P. 的古气候演化序列。结果表明,9cal.kaB.P. 到7.8cal.kaB.P. 期间,流域的水分条件和温度逐渐上升,植被状况好转,此时气候逐渐转暖湿;而在7.8~7.5cal.kaB.P. 出现了显著的百年尺度的干旱事件,沉积物主要以砂质沉积为主,此时湖泊生产力显著下降;全新世期间最为暖湿的气候适宜期出现在7.5~5.0cal.kaB.P.;约5.0cal.kaB.P. 以来,该区域出现了较为明显的干旱化趋势。另外,对猪野泽地区的白碱湖的湖泊地貌学和年代学研究表明该区域在7.5~5.0cal.kaB.P. 出现了3次高湖面,并且湖岸堤时序变化指示了全新世后半期湖泊逐渐退缩的过程进而指示该区域出现了显著的干旱化趋势。     

不同采样点数量下土壤有机质含量空间预测方法对比

运用普通克里格、泛克里格、协同克里格和回归克里格4种方法,结合由DEM获取的高程因子以及土壤全氮和阳离子交换量（CEC）,预测了黑龙江省海伦市耕地有机质含量的空间分布。不同样点数量下海伦市土壤有机质含量的空间变异结构分析表明,样点数量多并不一定能够识别土壤有机质含量的结构性连续组分,最优化的布置采样点位置可能比单纯增加...     

2017年九寨沟地震前重力场异常特征提取

2017年8月8日九寨沟发生7.0级地震,此次地震发生在塔藏断裂、岷江断裂和虎牙断裂附近,震源机制为走滑型。重力场静态异常和动态异常变化可为研究深地壳结构性质提供重要的物理场信息。本文利用WGM计算的布格重力异常数据及实测流动重力数据进行小波多尺度分解,分离得到不同深度场源特征的地壳介质横向不均匀性。结果表明,WGM布格重力异常数据和实测重力数据的小波多尺度结果较为一致,通过对比分析发现,九寨沟地震发生在区域重力场的四象限分布中心位置,不同时空尺度的重力场变化对于深入认识潜在地震危险性趋势具有一定的科学意义。     

1989 Datong-Yanggao Earthquake with Ms=6.1

In this paper,the basic conditions and characteristics of the Datong-Yanggao earthquake are described in detail.The type of the earthquake,the aftershock activity,the earthquake trend,the characteristics of damage are analyzed and discussed.This earthquake belongs to a sequence of earthquake swarm type and is of the concentratedly occurring characteristics of several main shocks in a time sequence,and the aftershock activity was normally attenuated.Because of the unreasonable design of buildings and repeated vibration by several destructive main shocks within a short period,the damage in the high intensity region was aggravated.The analysis and the prediction procedure of the 1991 Datong-Yanggao earthquake(Ms=5.8)are also briefly given.