Reaction-induced grain boundary cracking and anisotropic fluid flow during prograde devolatilization reactions within subduction zones

Devolatilization reactions during prograde metamorphism are a key control on the fluid distribution within subduction zones. Garnets in Mn-rich quartz schist within the Sanbagawa metamorphic belt of Japan are characterized by skeletal structures containing abundant quartz inclusions. Each quartz inclusion was angular-shaped, and showed random crystallographic orientations, suggesting that these quartz inclusions were trapped via grain boundary cracking during garnet growth. Such skeletal garnet within the quartz schist formed related to decarbonation reactions with a positive total volume change (?V _t > 0), whereas the euhedral garnet within the pelitic schists formed as a result of dehydration reaction with negative ?V _t values. Coupled hydrological–chemical–mechanical processes during metamorphic devolatilization reactions were investigated by a distinct element method (DEM) numerical simulation on a foliated rock that contained reactive minerals and non-reactive matrix minerals. Negative ?V _t reactions cause a decrease in fluid pressure and do not produce fractures within the matrix. In contrast, a fluid pressure increase by positive ?V _t reactions results in hydrofracturing of the matrix. This fracturing preferentially occurs along grain boundaries and causes episodic fluid pulses associated with the development of the fracture network. The precipitation of garnet within grain boundary fractures could explain the formation of the skeletal garnet. Our DEM model also suggests a strong influence of reaction-induced fracturing on anisotropic fluid flow, meaning that dominant fluid flow directions could easily change in response to changes in stress configuration and the magnitude of differential stress during prograde metamorphism within a subduction zone.     

Performance of dry-separation processes in the recovery of cenospheres from fly ash and their implementation in a recovery unit

Cenospheres recovery is one of the coal fly ash beneficiations, providing economic as well as environmental benefits. Current techniques, such as lagoon or other wet-separation processes, consume large amounts of water and add to water pollution due to leaching of toxic materials from fly ash. The other possible disadvantage is the need for a wide operational area, which is unsuitable for densely populated countries. As wet-separation processes have some disadvantages, an improved and/or sustainable alternative recovery technique is required. An air classifier is one of the alternative techniques. In this study, two types of air classifiers, namely a closed-type pneumatic separator and a micron separator, have been investigated. In terms of separation efficiency, it was found that the micron separator has the potential to be applied in cenospheres recovery from coal fly ash, giving a Newton's efficiency of 0.44, as compared to a value of about 0.26 for the closed-type pneumatic separator. The cenospheres recoveries of both pieces of equipment at their optimum Newton's efficiencies were similar at over 60 wt.%. The separation performance was further assessed from the particle distributions of the overflow and underflow products obtained from both pieces of equipment, as well as from SEM images. It was found that the lower Newton's efficiency of the closed-type pneumatic separator was due to the re-concentration of fine particles in the underflow product at air-flow rates higher than 2.2 m/s (the underflow product yield was about 55 wt.%).In order to further confirm the applicability of this technique, the micron separator, which had provided higher separation efficiency and cenospheres recovery, was deployed in a cenospheres recovery unit prior to the use of a wet-separation process (float and sink tank). About 80% of the cenospheres was recovered, with an 87.8% reduction in the total mass of fly ash to be separated in the float and sink tank. Consequently, much less water was needed for the process of cenospheres recovery. Moreover, it was also confirmed that the micron separator could yield higher quality fly ashes, that is, fly ash types I and II, from lower feed quality of fly ash type IV, which is the lowest category in commercial classification of fly ash according to JIS A6201.     

Chemostratigraphic documentation of a complete Miocene intermediate-depth section in the Southern Ocean: Ocean Drilling Program Site 1120, Campbell Plateau off New Zealand

An integrated chemostratigraphic (⁸⁷Sr/⁸⁶Sr, δ¹³C and δ¹⁸O) study of benthic foraminifera is presented for a 210 m-thick, intermediate depth (upper/middle bathyal transition), Miocene nannofossil ooze section of Ocean Drilling Program Site 1120, Campbell Plateau off New Zealand. Our results indicate that new ⁸⁷Sr/⁸⁶Sr, δ¹³C and δ¹⁸O profiles are wholly consistent with their respective Miocene reference curves. These observations facilitate identification of a total of five reliable chemostratigraphic datums, which are based on the fundamental structural changes in the ⁸⁷Sr/⁸⁶Sr curve and paired simultaneous δ¹³C and δ¹⁸O events. The resultant age–depth relationship clearly shows that the Miocene (20–5 Ma) biopelagic sedimentation on the Campbell Plateau was essentially continuous at a moderate to high, linear sedimentation rate (17.5 m/m.y. with an exception of the uppermost 13 m). Our findings do not support the shipboard biostratigraphic age model, which assumes that the critical early–middle Miocene transition was interrupted by a major hiatus (<~3 m.y.). Because of its unique bathymetric setting at a paleowater-depth of ~ 600 m, which is among the shallowest of the coeval isotopically studied deep-sea sections in the South Pacific/Southern Ocean, Site 1120 will serve as a reference section for surveying the evolution of intermediate-water paleoceanography in the Southern Hemisphere across the middle Miocene climatic transition.     

Development of a GPGPU-parallelized hybrid finite-discrete element method for modeling rock fracture

The hybrid finite-discrete element method (FDEM) is widely used for engineering applications, which, however, is computationally expensive and needs further development, especially when rock fracture process is modeled. This study aims to further develop a sequential hybrid FDEM code formerly proposed by the authors and parallelize it using compute unified device architecture (CUDA) C/C++ on the basis of a general-purpose graphics processing unit (GPGPU) for rock engineering applications. Because the contact detection algorithm in the sequential code is not suitable for GPGPU parallelization, a different contact detection algorithm is implemented in the GPGPU-parallelized hybrid FDEM. Moreover, a number of new features are implemented in the hybrid FDEM code, including the local damping technique for efficient geostatic stress analysis, contact damping, contact friction, and the absorbing boundary. Then, a number of simulations with both quasi-static and dynamic loading conditions are conducted using the GPGPU-parallelized hybrid FDEM, and the obtained results are compared both quantitatively and qualitatively with those from either theoretical analysis or the literature to calibrate the implementations. Finally, the speed-up performance of the hybrid FDEM is discussed in terms of its performance on various GPGPU accelerators and a comparison with the sequential code, which reveals that the GPGPU-parallelized hybrid FDEM can run more than 128 times faster than the sequential code if it is run on appropriate GPGPU accelerators, such as the Quadro GP100. It is concluded that the GPGPU-parallelized hybrid FDEM developed in this study is a valuable and powerful numerical tool for rock engineering applications.     

Elementary flare bursts explained by explosive coalescence

The observed burst durations of Elementary Flare Bursts (5–25 s), as well as the related other flare characteristics, such as the temperature (30–50 MK), the electron density (log ne = 10 to 11) and the magnetic field strengths (100 G to 200 G) can be explained quantitatively by the mechanism of explosive coalescence.     

Noble gases in metal and schreibersite of the Acuña (IIIAB) iron meteorite

Abstract— We measured abundances and isotopic compositions of noble gases in metal and schreibersite of the Acuña (IIIAB) iron meteorite. The concentrations of noble gases in Acuña metal are very low compared to those reported so far for other iron meteorites. The isotopic ratios of He, Ne and Ar indicate that they are mostly of cosmogenic origin. Cosmogenic components are even present in Kr and Xe, which could not have been produced from Fe, Ni and P and are probably due to the spallation of trace elements of higher masses. The high ⁴He/²¹Ne ratio of 420 in Acuña metal indicates that the samples were at a deep position within a very large meteoroid. The exposure ages of Acuña were estimated to be 50–200 Ma from ³He, ²¹Ne and ³⁸Ar abundances and by utilizing the diagrams of production rates vs. the ⁴He/²¹Ne ratio based on the Signer-Nier model. The low exposure age of Acuña may indicate a history different from that of other IIIAB irons whose exposure ages cluster at ～670 Ma. Otherwise, Acuña may be one of the samples with the low production rate, which can not be estimated from the diagrams of the Signer-Nier model.     

Review on observational studies of western tropical Pacific Ocean circulation and climate

The Western Tropical Pacific(WTP) Ocean holds the largest area of warm water(28℃) in the world ocean referred to as the Western Pacific Warm Pool(WPWP),which modulates the regional and global climate through strong atmospheric convection and its variability.The WTP is unique in terms of its complex 3-D ocean circulation system and intensive multiscale variability,making it crucial in the water and energy cycle of the global ocean.Great advances have been made in understanding the complexity of the WTP ocean circulation and associated climate impact by the international scientific community since the 1960 s through field experiments.In this study,we review the evolving insight to the 3-D structure and multi-scale variability of the ocean circulation in the WTP and their climatic impacts based on in-situ ocean observations in the past decades,with emphasis on the achievements since 2000.The challenges and open que stions remaining are reviewed as well as future plan for international study of the WTP ocean circulation and climate.     

Preliminary study of light variations of the eclipsing binary AB Cassiopeiae

Preliminary study of the eclipsing binary AB Cas is presented here by using the photometric observational data. The primary component is one of the Sct variables with period of 0^d.054, and whether the oscillation is of a radial mode or of a non-radial one is discussed. Two colour indices (B-V andU-B) data and the light curve analysis suggest that this binary system is a typical Algol type binary system, in which the primary component is near the ZAMS with about 2.3M and the secondary one is a subgiant star with about 0.5M .