活性半焦低温催化氧化NO的研究

制备了活性半焦催化剂用于在低温下将NO氧化为NO2。通过水热活化、高温活化、酸活化、碱活化以及组合活化等多种活化方法对原半焦进行活化改性,以提高半焦的催化氧化性能。利用酸碱滴定、Boehm滴定、SEM、BET、FT-IR等方法对活性半焦的物化性质进行了表征。采用固定床反应器测定活性半焦催化氧化NO的能力,其反应条件为:温度70℃、空速600 h-1、O2和NO浓度分别为5%和443 mg/m3。将活性半焦催化氧化NO的催化性能与其物化性质进行了关联,结果表明:半焦上的羰基官能团和碱性官能团共同作用于NO的吸附氧化过程,NO在羰基上被吸附并氧化,碱性官能团则协助氧化产物NO2迁移出羰基活性位并将NO2储存在碱性官能团上,使羰基活性恢复。根据以上理论所制备的经过碱活化和高温活化的催化剂硝容最大,可达1.01%。     

含油多孔介质二维弥散特性初步研究

为了研究含油多孔介质的二维水动力弥散特性,控制砂土中柴油和机油含油率为0、1%、2%,作为供试的含油多孔介质,采用自己设计的二维水动力弥散试验装置测定示踪剂(氯化钙)的穿透曲线,并定量确定了含油砂土的有效孔隙度、纵向弥散度、横向弥散度以及砂土中孔隙水的流速。试验结果表明,有效孔隙度随石油含量的增加而减小,而且含柴油砂土的有效孔隙度减小比含机油砂土更加显著;在纵向上,示踪剂浓度峰值的到达时间和峰值浓度的大小主要取决于孔隙水流速的大小,孔隙水流速越大,示踪剂达到浓度峰值的时间越短,且峰值浓度越大;含机油砂土的纵向弥散度小于清洁砂土,而含柴油砂土的纵向弥散度大于清洁砂土;不同含油率砂土的纵向弥散度变化范围为0.133～0.370cm,横向弥散度变化范围为9.83×10-3～4.64×10-2 cm,纵向弥散度均大于其横向弥散度。     

赞比亚西北省索卢韦齐县铜钴多金属矿地质特征

赞比亚西北省索卢韦齐县铜钴多金属矿主要存在三种矿化类型,第一种是层控型铜矿,矿石矿物为黄铜矿、黝铜矿、辉铜矿,多呈条带状、透镜状等形态,平行黑云石英片岩和二云石英片岩的片理展布;第二种为沉积型铜矿,受到背斜和穹窿的控制,含矿岩系主要为加丹加超群(Katanga)下部罗安组(Roan)页岩、砂岩,金属矿物主要为水胆石、孔雀石、蓝铜矿,多呈星点状、浸染状、斑杂状、团块状等分布在含矿页岩、砂岩中;第三种是热液型铜矿,充填在加丹加超群及其更老的地层中,矿化类型为黄铜矿黄铁矿石英脉型,一般为小型脉状矿床。该类型矿床可与前两类矿床叠加,使矿石品位提高。     

古尔班通古特沙漠腹地土壤水分动态

采用土钻法对古尔班通古特沙漠腹地典型自然沙垄剖面土壤含水量进行长期监测.采取多重比较(LSD)、典型相关分析(MANOVA)、并在国内第一次采用季节交乘趋势等统计方法,对土壤水分与环境因子的关系进行分析,研究结果表明:土壤含水量时间变化规律分为补给期、失水期和冻结滞水期.土壤含水量均值为补给期>冻结滞水期>失水期,变异系数为补给期>冻结滞水期>失水期;土壤含水量空间变化规律表现为:阴阳坡间具有极显著差异(P<0.01,F=0.002 9).垄间分别与坡中、垄顶具有显著性差异(P<0.05).垂直变化分为活跃层、过渡层和稳定层,活跃层与其他土层间均有显著性差异(P<0.05),土壤含水量均值为阴坡>阳坡,垄顶>垄间>坡中.活跃层>过渡层和稳定层;变异系数为阴坡>阳坡,垄间>坡中>垄顶,活跃层>过渡层>稳定层;降雨量和温度是影响研究区土壤水分时间分布变化的重要影响因子,同时也是土壤含水量变化的决定性影响因子,与土壤含水量具有显著相关性(P<0.05,F=0.02).     

Late Cenozoic magnetostratigraphy (11 – 0 Ma) of the Dongshanding and Wangjiashan sections in the Longzhong Basin,western China

A paleomagnetic study of the 510-m-thick Wangjiashan section of Late Miocene and Pliocene terrestrial sediments reveals a fairly complete reversal record with ages from 11 to 1.8 Ma. The magnetostratigraphy of the Dongshanding section, located nearby, reveals a partially overlapping reversal record with ages from 2.2 to 0 Ma, and facilitates correlation of the Wangjiashan section with the global polarity time scale. A new stratigraphic division of the Wangjiashan section replaces the name Linxia formation by five new formation names, based on lithologic variation and mammalian fossil finds. The new formations and their magnetostratigraphically determined ages are: Dongshan Formation (c. 1.75–2.6 Ma), Jishi Fm. (c. 2.6–3.6 Ma), Hewangjia Fm. (4.5–6.0 Ma), Liushu Fm. (6.0–7.6 Ma), and Dongxiang Fm. (7.6–c. 12 Ma). The Neogene stratigraphy and fossil mammals suggest that the nearby part of the Tibetan Plateau experienced a persistent denudation during the Late Miocene and Early Pliocene, but that it was uplifted more rapidly at about 3.6 Ma.     

Strength behavior of dredged mud slurry treated jointly by cement,flocculant and vacuum preloading

Acta Geotechnica - Application of the flocculation–solidification combined method (FSCM) is a rational option for treatment and recycling of dredged mud slurry at extra high water content...     

Analytical model for two-dimensional electro-osmosis-enhanced preloading consolidation of unsaturated soil

Acta Geotechnica - Electro-osmotic consolidation is taken as a valid and practical approach for soft ground improvement, and it is of vital significance to study the consolidation behaviour of...     

Submillimeter/millimeter observations of the high-mass star forming region IRAS 22506+5944

The mapping observations of CO J = 2-1, CO J = 3-2, 13 CO J = 2-1 and 13 CO J = 3-2 lines in the direction of IRAS 22506+5944 have been made. The results show that the cores in the J = 2-1 transition lines have a similar morphology to those in the J = 3-2 transition lines. Bipolar molecular outflows are verified. The prior IRAS 22506+5944 observations indicated that two IRAS sources and three H 2 O masers were located close to the peak position of the core. One of the IRAS sources may be the driving source ...     

上海三维城市地质信息系统优化

本文在简要论述上海三维地质系统建设现状的基础上,对系统存在的主要问题进行了分析,提出了系统升级的目标、升级的主要功能。重点对系统升级过程中涉及的海量数据管理、三维建模技术、地上与地下一体化集成、4D模拟、三维模型的发布等关键技术进行了剖析,并提出了相应的解决方案。     

Effects of periodic saturation on stress–strain relationship of a sandstone mixture

While a crushed sandstone particle mixture, usually used as an engineering fill, is filled along bank of or in a large reservoir, it is subjected to periodic saturation induced by filling-drawdown cycles of reservoir water. The periodic saturation may induce post-construction settlement, and reduce stability of the filled body. In order to evaluate the effects of periodic saturation on stress–strain relationship of the mixture, several triaxial tests are carried out. According to experimental data, the periodic saturation may induce an increment of axial strain (Δε; <0.226%), a decrement of crest of deviator stress (Δ(σ₁?σ₃)_f; <0.192?MPa) and a decrement of angle of shearing resistance (Δφ; <3.70°). With increment of the number of periodic saturation cycles, the variations of the three parameters may be fitted by logarithmic curves. And with increase in the stress level for periodic saturation, the variations of the three parameters may be fitted by straight lines. Three fitting equations to predict the three parameters’ values, and an equation to calculate the settlement induced by the periodic saturation of a large-area filled foundation, are suggested.