Positional isomer composition of monounsaturated fatty acids from a lacustrine sediment

From the surface sediment of a eutrophic lake (Japan), the double bond position in the monounsaturated fatty acids (C₁₅-C₂₆) has been determined by combined gas chromatography-mass spectrometry of the methoxylated derivatives. The relative abundance of 11-octadecenoic acid, suggested to be of bacterial origin, is higher in the chloroform-methanol extract than the extract by saponification.     

Timing of rotational motion of Southwest Japan inferred from paleomagnetism

Paleomagnetic field directions for the period younger than 35 Ma are obtained from igneous rocks distributed in the San'in district, Inner Zone of Southwest Japan. The remanent magnetization of samples between 30 and 35 Ma old are fairly well grouped with a mean direction of D = 65.9°, I = 48.6°, and ₉₅ = 6.5°. This result establishes that Southwest Japan rotated clockwise 56 ± 12° during the past 30 m.y. A declination value of about 60° is observed in the rocks of 28 Ma ( D = 52.2°, I = 33.5°) and 21 Ma (D = 69.9°, I = 49.5°). Comparing this with results from dacitic rocks with an age of 15 Ma in other areas of Southwest Japan suggests that rotational motion did not occur possibly until 15 Ma. These results require that the rotation of Southwest Japan occurred just after the Shikoku Basin had been created.     

Amount of clockwise rotation of Southwest Japan — fan shape opening of the southwestern part of the Japan Sea

Paleomagnetic measurements have been carried out on welded tuffs ranging in age between 58 Ma and 112 Ma from Yamaguchi and Go¯river areas in the central part of Southwest Japan. The new data, together with those of younger igneous rocks published previously, define the change of paleomagnetic field direction during the late Mesozoic/ Cenozoic period for Southwest Japan. The paleomagnetic direction from this area has pointed 56 ± 3° clockwise from the expected field direction estimated from APWP (apparent polar wandering path) of the whole of Eurasia during the period between 100 and 20 Ma. In comparison with the expected one from the eastern margin of Eurasia (Korea, China, Siberia), the Cretaceous field direction of Southwest Japan shows the clockwise deflection by 44–49°. These results establish that while the eastern margin of Eurasia, including Southwest Japan, was rotated more or less with respect to the main part of Eurasia during last 100 Ma, Southwest Japan was rotated clockwise through more than 40° with respect to the eastern margin of Eurasia since 20 Ma. The large amount of rotation for Southwest Japan implies that it is rotated by an opening of the southwestern part of the Japan Sea, which widens northeastward (fan shape opening). The tectonic feature of Southwest Japan and the Japan Sea is analogous to that of Corso-Sardinia and the Ligurian Sea in the Mediterranean, indicating that the fan shape opening is a specific feature of the rifting of the continental sliver at the continental rim.     

Early tholeiitic and calc-alkaline arc magmatism of middle to Late Eocene Age in the southern Ogasawara (Bonin) forearc

Analysis of middle and upper Eocene rocks from the IBM forearc, including the Ogasawara and Mariana Islands, help illuminate early arc volcanism of the proto-IBM arc. Dredged volcanic rocks from the forearc are two-pyroxene basalt to andesite, and may be divided into two groups, tholeiite and calc-alkaline, on the basis of mineralogy, petrography, and bulk chemistry. Tholeiites are characterized by high HFSE contents, high crystallization temperatures, and low water contents. In contrast, the calc-alkaline rocks are characterized by low HFSE contents, low crystallization temperatures, and higher water contents. These characteristics indicate that magma genesis for the two series differed. The tholeiites resulted from high degrees of partial melting of slightly depleted mantle under anhydrous conditions, whereas the calc-alkaline rocks were generated by low degrees of melting of depleted mantle under hydrous conditions. We believe that differences in mantle depletion arose from compositional layering and fluid zonations caused by MORB volcanism and slab dehydration, respectively. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Acceleration through X-type coalescence in a small energetic flare

We studied the acceleration conditions in the small but fairly energetic flare of May 21, 1984 at 1326 UT. The most pronounced aspect of this flare was a series of 13 microwave/X-ray spikes, each lasting for about 0.1 s. A previous study has shown that each of these was due to a series of successive sudden formations of small plasma knots of high-energy particles. Each of these knots lost its energy in about 50 ms. In the present study we show that these knots can originate by the process of X-type (3-D) flux tube coalescence. The predicted rise time (30 to 50 ms) and energy are in good agreement with the observationally derived parameters.     

Plasma jet and shock formation during current loop coalescence in solar flares

We report on the results of plasma jet and shock formation during the current loop coalescence in solar flares. It is shown by a theoretical model based on the ideal MHD equation that the spiral, two-sided plasma jet can be explosively driven by the plasma rotational motion induced during the two current loop coalescence process. The maximum velocity of the jet can exceed the Alfvén velocity, depending on the plasma (= c _s ² v _A ² ) ratio. The acceleration time getting to the maximum jet velocity is quite short and le than 1 s. The rebound following the plasma collapse driven by magnetic pinch effect can strongly induce super-Alfvénic flow. We present the condition of the shock formation. We briefly discuss the high-energy particle acceleration during the plasma collapse as well as by the shocks.     

Prompt high-energy particle acceleration during two-current-loop collisions

We present a model of prompt high-energy particle acceleration during two-current-loop collisions. By investigating test proton and test electron motions in the electromagnetic field derived from the MHD equations, we found that high-energy particle acceleration occurs only in the case ofY-type, loop-loop collisions. The results depend strongly on the plasma and initial position of the test particle. When the plasma increases, the particle acceleration rate decreases. The particles near the edge of the collision region can be accelerated to higher energy than the ones inside it. It has been shown that both protons and electrons can be accelerated to 10 GeV within 0.001 s and 5 MeV within 10^–6 s, respectively. In the case ofY-type loop-loop collisions, one may expect that high-energy gamma-ray and neutrons will be generated from interaction between high-energy particles and the low atmospheric plasma.     

Characterizing Content Distributions of Impurities in a Limestone Mine Using a Feedforward Neural Network

The factors determining the suitability of limestone for industrial use and its commercial value are the amounts of calcium oxide (CaO) and impurities. From 244 sample points in 18 drillhole sites in a limestone mine, southwestern Japan, data on four impurity elements, SiO₂, Fe₂O₃, MnO, and P₂O₅ were collected. It generally is difficult to estimate spatial distributions of these contents, because most of the limestone bodies in Japan are located in the accretionary complex lithologies of Paleozoic and Mesozoic age. Because the spatial correlations of content data are not clearly shown by variogram analysis, a feedforward neural network was applied to estimate the content distributions. The network structure consists of three layers: input, middle, and output. The input layer has 17 neurons and the output layer four. Three neurons in the input layer correspond with x, y, z coordinates of a sample point and the others are rock types such as crystalline and conglomeratic limestones, and fossil types related to the geologic age of the limestone. Four neurons in the output layer correspond to the amounts of SiO₂, Fe₂O₃, MnO, and P₂O₅. Numbers of neurons in the middle layer and training data differ with each estimation point to avoid the overfitting of the network. We could detect several important characteristics of the three-dimensional content distributions through the network such as a continuity of low content zones of SiO₂ along a Lower Permian fossil zone trending NE-SW, and low-quality zones located in depths shallower than 50 m. The capability of the neural network-based method compared with the geostatistical method is demonstrated from the viewpoints of estimation errors and spatial characteristics of multivariate data. To evaluate the uncertainty of estimates, a method that draws several outputs by changing coordinates slightly from the target point and inputting them to the same trained network is proposed. Uncertainty differs with impurity elements, and is not based on just the spatial arrangement of data points.     

An attempt to separate Q from the Allende meteorite by physical methods

In order to characterize the planetary noble gas carrier Q, we separated a Q-rich floating fraction from the Allende meteorite into ten fractions by a combination of colloidal and density separations. All five noble gases in the separated fractions were analyzed by pyrolysis in 600 and 1600°C temperature steps. Half of Q in the floating fraction is concentrated in the fraction C1-8D with the density of 1.65 ± 0.04 g/cm³. All the separated fractions show similar isotopic ratios except for ⁴⁰Ar/³⁶Ar ratios. C1-8D has the lowest ³⁸Ar/³⁶Ar and ⁴⁰Ar/³⁶Ar ratios (0.18784 ± 0.00020 and 4.36 ± 0.15, respectively) in the 1600°C fraction, confirming that the fraction is enriched in Q. Most grains in C1-8D are carbonaceous with small amounts of F and O. These results imply either that the density of Q is 1.65 ± 0.04 g/cm³ or that Q preferentially sticks to matter of that density. All the separates have similar Q to diamond ratios, indicating that Q and diamond are closely associated.     

Processes causing the chlorophylla maximum in the tidal front in Iyo-nada,japan

A field survey was undertaken to reveal the structure of the tidal front in Iyo-nada. An obvious tidal front was found between the mixed region around Hayasui Straits and the stratified region in Iyo-Nada. Its structure was typical in the eastern part and was influenced by the river discharge in the western part. An intense chlorophylla maximum was found in the subsurface layer of the eastern typical front. Analysis using TS diagram suggested that, around the eastern front, there was an intrusion from the mixed water to the middle layer of the stratified water. This intrusion was supposed to be an important process supplying nutrients from the mixed water to the subsurface of the frontal region and causing the intense chlorophylla maximum.