四酸溶矿——电感偶合等离子体发射光谱法测定钼矿中的钼

为了适应地质找矿和地质大普查工作对矿样测定速度和正确度的要求,对钼矿样品中的钼的测定方法进行试验,探讨在敞开体系中用盐酸+硝酸+氢氟酸+高氯酸的四酸溶矿体系消解钼矿样品,使用电感耦合等离子发射光谱仪(ICP-AES)测定钼的方法。     

煤矿塌陷区复垦土壤环境质量评价

通过对煤矿塌陷区复垦土壤采样测试,研究土壤中重金属铜、锌、镉、汞、砷、铅、铬的含量对土壤环境的影响。研究结果表明:按单因子污染指数法和内梅罗综合污染指数法,结合国家土壤环境质量标准对复垦土壤的质量进行评价:研究区内土壤环境质量良好,基本上可以达到国家土壤环境质量二级标准,安全清洁级别;参照《无公害食品蔬菜产地环境条件标准》、《绿色食品产地环境质量标准》和《有机农业生产基地环境质量标准》,对复垦土壤的农用环境进行评价:研究区内土壤全部达到绿色食品产地环境质量标准,如果选择合理的修复方法,对部分有轻微污染的土壤进行,则可以达到有机农业生产基地环境质量标准;以潜在生态危害指数RI分析,复垦区内土壤重金属潜在生态危害指数相对较低,复垦区农业生产具有良好的发展前景。     

西藏某铅多金属矿土壤地球化学特征及找矿

通过西藏芒康某铅多金属矿土壤地球化学元素变异系数、富集系数、叠加强度、蚀变-矿化强度、致矿因素等五个方面进行综合研究,结合区内已有地质、矿产资料分析认为测区内主成矿元素为Pb、Zn、Ag、Cu,重要伴(共)生元素或指示元素为Cd、Hg、W、As、Zn、Sb、Mo、Au、Sn。该次土壤测量在区内共圈定元素综合异常23个,通过对找矿潜力较大的异常进行推断解释,同时结合区域成矿规律,对区内铅多金属找矿方向进行了初步探讨。     

山西王莽岭国家地质公园地貌景观特征及其成因研究

王莽岭国家地质公园位于太行山南段,地质遗迹资源丰富、类型多样,具有重要的美学及科学价值。本文以王莽岭地质公园为研究区,通过野外调查并依据地质遗迹的成因、形态及规模、自然属性及分布特征,将地质遗迹资源划分为地貌景观、沉积构造、构造形迹、古生物化石四类,系统地研究了峡谷、岩溶、夷平面、河流阶地、瀑布等地貌的成因,为太行山的形成演化研究提供了资料,对提升研究区地质遗迹资源的科学价值具有重要意义。     

新疆谢米斯台地区小岩体型矿化遥感探测

中酸性小岩体易被地质填图遗漏,严重制约了该类型矿化的发现。在新疆西准噶尔谢米斯台地区找矿工作中,首先利用ETM+数据进行小岩体扫面,进而选取重点区采用ETM+和中巴资源卫星02B HR数据进行分辨率融合后解译、识别中酸性小岩体,并利用主成分分析法提取蚀变遥感异常,结合地质、化探信息综合分析后确定重点检查区域。利用此方法共解译出14个钾质花岗岩和3个黑云母花岗岩小岩体,这些小岩体大多被野外检查所证实。经野外检查发现了5处铜、金矿化点,证实了该方法的有效性。本研究中采用的方法可以为西部地区地质填图和中酸性小岩体型矿产资源勘查提供借鉴。     

西藏措勤打加错地区上三叠统江让组的发现及其地质意义

在西藏措勤打加错地区新发现上三叠统江让组,其为一套海相碎屑岩及碳酸盐岩沉积建造,岩性主要为不等厚层状石英质砾岩、深灰色薄层状—块状生物碎屑微晶灰岩、含砂粉砂质微晶灰岩、含石英砾质生物碎屑灰岩、砂屑灰岩夹钙质细砂岩,产珊瑚Distichophyllia sp.,Volzeia sp.,Montlivaltia sp.,M.cf.xainzaensis、海绵:Hartmanina sp.和双壳类Xenocardita?sp.,时代为晚三叠世卡尼期-诺利期,与下二叠统昂杰组呈角度不整合接触。江让组在该地区的发现,完善了冈底斯西部三叠纪的地层系统,为研究印支运动对冈底斯西部的影响和古特提斯洋的演化提供了依据。     

江汉平原西部浅层孔隙水水文地球化学特征

为了揭示地下水由江汉平原周缘向中心径流过程中的水质演化和复杂的水文地球化学作用,以江汉平原西部地区为例,通过数理统计、水化学、同位素地球化学、离子比值关系等方法,开展了江汉平原西部边缘地带浅层孔隙地下水的水文地球化学特征研究。结果表明: 平原区孔隙水以HCO₃-Ca·Mg型为主,丘岗区(丘陵和岗地)主要是HCO₃-Ca·Mg型,少量为HCO₃·SO₄-Ca·Mg型,还出现了HCO₃·NO₃-Ca·Mg型水,总溶解固体(total dissolved solids,TDS)升高主要是由于碳酸盐岩的溶解; 浅层孔隙水均来源于大气降水,蒸发作用对该地区孔隙水的影响较小; 方解石、白云石和石膏的溶解主导研究区的水文地球化学过程,也是孔隙水中Ca²⁺、Mg²⁺的主要来源,Na⁺和K⁺的主要来源是阳离子交换吸附。     

Paragenesis and geochemistry of ore minerals in the epizonal gold deposits of the Yangshan gold belt,West Qinling,China

Six epizonal gold deposits in the 30-km-long Yangshan gold belt, Gansu Province are estimated to contain more than 300 t of gold at an average grade of 4.76 g/t and thus define one of China's largest gold resources. Detailed paragenetic studies have recognized five stages of sulfide mineral precipitation in the deposits of the belt. Syngenetic/diagenetic pyrite (Py₀) has a framboidal or colloform texture and is disseminated in the metasedimentary host rocks. Early hydrothermal pyrite (Py₁) in quartz veins is disseminated in metasedimentary rocks and dikes and also occurs as semi-massive pyrite aggregates or bedding-parallel pyrite bands in phyllite. The main ore stage pyrite (Py₂) commonly overgrows Py₁ and is typically associated with main ore stage arsenopyrite (Apy₂). Late ore stage pyrite (Py₃), arsenopyrite (Apy₃), and stibnite occur in quartz ± calcite veins or are disseminated in country rocks. Post-ore stage pyrite (Py₄) occurs in quartz ± calcite veins that cut all earlier formed mineralization. Electron probe microanalyses and laser ablation-inductively coupled plasma mass spectrometry analyses reveal that different generations of sulfides have characteristic of major and trace element patterns, which can be used as a proxy for the distinct hydrothermal events. Syngenetic/diagenetic pyrite has high concentrations of As, Au, Bi, Co, Cu, Mn, Ni, Pb, Sb, and Zn. The Py₀ also retains a sedimentary Co/Ni ratio, which is distinct from hydrothermal ore-related pyrite. Early hydrothermal Py₁ has high contents of Ag, As, Au, Bi, Cu, Fe, Sb, and V, and it reflects elevated levels of these elements in the earliest mineralizing metamorphic fluids. The main ore stage Py₂ has a very high content of As (median value of 2.96 wt%) and Au (median value of 47.5 ppm) and slightly elevated Cu, but relatively low values for other trace elements. Arsenic in the main ore stage Py₂ occurs in solid solution. Late ore stage Py₃, formed coevally with stibnite, contains relatively high As (median value of 1.44 wt%), Au, Fe, Mn, Mo, Sb, and Zn and low Bi, Co, Ni, and Pb. The main ore stage Apy₂, compared to late ore stage arsenopyrite, is relatively enriched in As, whereas the later Apy₃ has high concentrations of S, Fe, and Sb, which is consistent with element patterns in associated main and late ore stage pyrite generations. Compared with pyrite from other stages, the post-ore stage Py₄ has relatively low concentrations of Fe and S, whereas As remains elevated (2.05～3.20 wt%), which could be interpreted by the substitution of As^? for S in the pyrite structure. These results suggest that syngenetic/diagenetic pyrite is the main metal source for the Yangshan gold deposits where such pyrite was metamorphosed at depth below presently exposed levels. The ore-forming elements were concentrated into the hydrothermal fluids during metamorphic devolatilization, and subsequently, during extensive fluid–rock interaction at shallower levels, these elements were precipitated via widespread sulfidation during the main ore stage.     

Discrete element modelling of material non‐coaxiality in simple shear flows

We investigate the quasi‐static simple shear flow of a two‐dimensional assembly of cohesionless particles using discrete element method (DEM) simulations. We focus on the unsteady flow regime where the solid would experience significant evolution of stresses, mobilised shear strength and dilation. We construct the DEM model using a discretised‐wall confined granular cell where the apparent boundary is allowed to dilate or contract synchronously with the confined solid. A rather uniform simple shear field is achieved across the whole assembly, which benefits rheological studies in generalising constitutive laws for continuum methods. We examine two aspects of the simple shear behaviour: macroscopic stress and strain rate evolution, particularly the non‐coaxiality between the principal directions of the two; and micromechanics such as evolution of fabric. For an initially anisotropic specimen sheared under constant normal pressure, the direction of principal stress rotates towards that of the principal strain rate, gradually reducing the degree of non‐coaxiality from about 45° to fluctuating around 0°. The rate in approaching coaxiality is slower in samples with larger initial porosity, stress ratio and mean stress. Generally, a faster rate in approaching coaxiality in simple shear is observed in a more dilatant sample, which often shows a larger degree of mobilised fabric anisotropy, suggesting the possible important role of instantaneous internal friction angle. The evolution of principal fabric direction resembles that of the principal stress direction. © 2013 The Authors. International Journal for Numerical and Analytical Methods in Geomechanics published by John Wiley & Sons, Ltd.     

青海西部尕斯库勒盐湖沉积物中铀和钍地球化学特征探讨

文章以柴达木盆地西部尕斯库勒盐湖沉积物为研究对象,通过对钻孔沉积物和地表沉积物中铀和钍含量的研究,探讨了盐湖沉积物中铀和钍的地球化学特征。分析表明,钻孔沉积物中铀和钍之间存在明显的正相关关系。在横向上,随地表取样点逐渐远离湖表卤水,沉积物中铀和钍的含量先增高后又急剧降低,且受补给水铀含量影响大;在纵向上,同一个晶间卤水层或者碎屑物沉积层内铀含量垂直分异明显,铀含量随深度增加而递增。就沉积物中铀和钍的赋存形式而言,2/3的铀被黏土质点吸附,1/3的铀夹杂在盐类矿物中;而90%以上的钍被黏土质点吸附,10%以下的钍夹杂在盐类矿物中。干盐滩中毛细蒸发和淋滤等化学沉积分异作用造成盐湖沉积中心的沉积物铀含量相对较高。