Impacts of regional warming on long‐term hypolimnetic anoxia and dissolved oxygen concentration in a deep lake

Although few reports have described long‐term continuous anoxia in aquatic systems, Lake Ikeda in Japan experienced such conditions in the hypolimnion from 1990 to 2010. The present study aimed to assess temporal fluctuations in the lake's thermal stability from 1978 to 2011 to understand the influence of regional climate change on hypolimnetic anoxia in this lake. Because complete vertical mixing, which supplies dissolved oxygen (DO) to the hypolimnion, potentially occurs on February, we calculated the Schmidt stability index (S) in February and compared it with hypolimnetic DO dynamics. Vertical water temperature profiles were calculated using a one‐dimensional model, and calculated temperatures and meteorological data were used to analyse annual fluctuations in water temperatures, thermocline depth, meteorological variables and S. We estimated that mean annual air and volume‐weighted water temperatures increased by 0.028 and 0.033 °C year^?1, respectively, from 1978 to 2011. Between 1986 and 1990, S and water temperature increased abruptly, probably due to a large upwards trend in air temperature (+0.239 °C year^?1). We hypothesize that a mixing regime that lacked overturn took effect at this time and that this regime lasted until 2011, when S was particularly small. These results demonstrate that abrupt climate warming in the late 1980s likely triggered the termination of complete mixing and caused the 21‐year period of successive anoxia in Lake Ikeda. We conclude that the lake response to a rapid shift in regional climate conditions was a key factor in changing the hypolimnetic water environment and that thermal stability in winter is a critical environmental factor controlling the mixing regime and anoxic conditions in deep lakes. Copyright © 2014 John Wiley & Sons, Ltd.     

http://www.sciencedirect.com/science/article/pii/S167498711000037X

The tried and tested multianvil apparatus has been widely used for high-pressure and high-temperature experimental studies in Earth science. As a result, many important results have been obtained for a better understanding of the components, structure and evolution of the Earth. Due to the strength limitation of materials, the attainable multianvil pressure is generally limited to about 30 GPa (corresponding to about 900 km of the depth in the Earth) when tungsten carbide cubes are adopted as second-stage anvils. Compared with tungsten carbide, the sintered diamond is a much harder material. The sintered diamond cubes were introduced as second-stage anvils in a 6–8 type multianvil apparatus in the 1980s, which largely enhanced the capacity of pressure generation in a large volume press. With the development of material synthesis and processing techniques, a large sintered diamond cube (14 mm) is now available. Recently, maximum attainable pressures reaching higher than 90 GPa (corresponding to about 2700 km of the depth in the Earth) have been generated at room temperature by adopting 14-mm sintered diamond anvils. Using this technique, a few researches have been carried out by the quenched method or combined with synchrotron radiation in situ observation. In this paper we review the properties of sintered diamond and the evolution of pressure generation using sintered diamond anvils. As-yet unsolved problems and perspectives for uses in Earth Science are also discussed.     

Characteristics of evapotranspiration from a permafrost black spruce forest in interior Alaska

Here, the year 2011 characteristics of evapotranspiration and the energy budget of a black spruce forest underlain by permafrost in interior Alaska were explored. Energy balance was nearly closed during summer, and the mean value of the daily energy balance ratio (the ratio of turbulent energy fluxes to available energy) from June to August was 1.00, though a large energy balance deficit was observed in the spring. Such a deficit was explained partly by the energy consumed by snowmelt. Ground heat flux played an important role in the energy balance, explaining 26.5% of net radiation during summer. The mean daily evapotranspiration of this forest during summer was 1.37 mm day^?1 – considered typical for boreal forests. The annual evapotranspiration and sublimation yielded 207.3 mm year^?1, a value much smaller than the annual precipitation. Sublimation accounted for 8.8% (18.2 mm year^?1) of the annual evapotranspiration and sublimation; thus, the sublimation is not negligible in the annual water balance in boreal forests. The daytime average decoupling coefficient was very small, and the mean value was 0.05 during summer. Thus, evapotranspiration from this forest was mostly explained by the component from the dryness of the air, resulting from the aerodynamically rough surface of this forest.     

Dynamic analysis of ground with rigorous use of strain dependency and its application to seismic microzonation of alluvial plane

Seismic microzonation is one of the most important measures to mitigate earthquake hazards in urban areas. Because the ground motion varies significantly with the subsurface geology, it is needed for microzonation to account as much as possible for the local soil conditions. Noteworthy is that nonlinear deformation properties of soil play essential roles in amplification of strong ground motion. It is desired furthermore to focus on the expected damage extent in addition to the calculated maximum acceleration and/or velocity. The present study first developed a computer code for one-dimensional response analysis of ground that reasonably takes into account nonlinear dynamic soil properties. Second, correlations between the calculated ground motion and damage extent were obtained by examining seismic damages during the past earthquakes. By combining these two issues, seismic microzonation was carried out, and detailed damage distribution was assessed. The product of this study covers not only the damage caused by ground shaking but also liquefaction problem and lifeline damage.     

Structural changes of synthetic opal by heat treatment

The structural changes of synthetic opal by heat treatment up to 1,400 °C were investigated using scanning electron microscopy, X-ray diffraction, and Fourier transform infrared and Raman spectroscopies. The results indicate that the dehydration and condensation of silanol in opal are very important factors in the structural evolution of heat-treated synthetic opal. Synthetic opal releases water molecules and silanols by heat treatment up to 400 °C, where the dehydration of silanol may lead to the condensation of a new Si–O–Si network comprising a four-membered ring structure of SiO₄ tetrahedra, even at 400 °C. Above 600 °C, water molecules are lost and the opal surface and internal silanol molecules are completely dehydrated by heat effect, and the medium-temperature range structure of opal may begin to thermally reconstruct to six-membered rings of SiO₄ tetrahedra. Above 1,000 °C, the opal structure almost approaches that of silica glass with an average structure of six-membered rings. Above 1,200 °C, the opal changes to low-cristobalite; however, minor evidence of low-tridymite stacking was evident after heat treatment at 1,400 °C.     

Phase boundary between ilmenite and perovskite structures in MnGeO3 determined by in situ X-ray diffraction measurements

In situ X-ray observations of the phase transition from ilmenite to perovskite structure in MnGeO₃ were carried out in a Kawai-type high-pressure apparatus interfaced with synchrotron radiation. The phase boundary between the ilmenite and perovskite structures in the temperature range of 700–1,400°C was determined to be P (GPa) = 16.5(±0.6) − 0.0034(±0.0006)T (°C) based on Anderson’s gold pressure scale. The Clapeyron slope, dP/dT, determined in this study is consistent with that for the transition boundary between the ilmenite and the perovskite structure in MgSiO₃.