Timing of rockfalls in the Mont Blanc massif (Western Alps): evidence from surface exposure dating with cosmogenic <Superscript>10</Superscript>Be

Rockfalls and rock avalanches are a recurrent process in high mountain areas like the Mont Blanc massif. These processes are surveyed due to the hazard they present for infrastructure and alpinists. While rockfalls and rock avalanches have been documented for the last 150 years, we know very little about their frequency since the Last Glacial Maximum (LGM). In order to improve our understanding, it is imperative to date them on a longer timescale. A pilot campaign using Terrestrial Cosmogenic Nuclide (TCN) dating of five samples was carried out in 2006 at the Aiguille du Midi (3842 m a.s.l.). In 2011, a larger scale study (20 samples) was carried out in five other test sites in the Mont Blanc massif. This paper presents the exposure ages of the 2011 TCN study as well as the updated exposure ages of the 2006 study using newer TCN dating parameters. Most of these exposure ages lie within the Holocene but three ages are Pleistocene (59.87?±?6.10 ka for the oldest). A comparison of these ages with air temperature and glacier cover proxies explored the possible relationship between the most active rockfall periods and the warmest periods of the Holocene: two clusters of exposure ages have been detected, corresponding to the Middle Holocene (8.2–4.2 ka) and the Roman Warm Period (c. 2 ka) climate periods. Some recent rockfalls have also been dated (<?0.56 ka).     

Projecting future drought in Mediterranean forests: bias correction of climate models matters!

Global and regional climate models (GCM and RCM) are generally biased and cannot be used as forcing variables in ecological impact models without some form of prior bias correction. In this study, we investigated the influence of the bias correction method on drought projections in Mediterranean forests in southern France for the end of the twenty-first century (2071–2100). We used a water balance model with two different atmospheric climate forcings built from the same RCM simulations but using two different correction methods (quantile mapping or anomaly method). Drought, defined here as periods when vegetation functioning is affected by water deficit, was described in terms of intensity, duration and timing. Our results showed that the choice of the bias correction method had little effects on temperature and global radiation projections. However, although both methods led to similar predictions of precipitation amount, they induced strong differences in their temporal distribution, especially during summer. These differences were amplified when the climatic data were used to force the water balance model. On average, the choice of bias correction leads to 45 % uncertainty in the predicted anomalies in drought intensity along with discrepancies in the spatial pattern of the predicted changes and changes in the year-to-year variability in drought characteristics. We conclude that the choice of a bias correction method might have a significant impact on the projections of forest response to climate change.     

Progressive glacial retreat in the Southern Altiplano (Uturuncu volcano, 22°S) between 65 and 14 ka constrained by cosmogenic He dating

This work presents the first reconstruction of late Pleistocene glacier fluctuations on Uturuncu volcano, in the Southern Tropical Andes. Cosmogenic ³He dating of glacial landforms provides constraints on ancient glacier position between 65 and 14 ka. Despite important scatter in the exposure ages on the oldest moraines, probably resulting from pre-exposure, these ³He data constrain the timing of the moraine deposits and subsequent glacier recessions: the Uturuncu glacier may have reached its maximum extent much before the global LGM, maybe as early as 65 ka, with an equilibrium line altitude (ELA) at 5280 m. Then, the glacier remained close to its maximum position, with a main stillstand identified around 40 ka, and another one between 35 and 17 ka, followed by a limited recession at 17 ka. Then, another glacial stillstand is identified upstream during the late glacial period, probably between 16 and 14 ka, with an ELA standing at 5350 m. This stillstand is synchronous with the paleolake Tauca highstand. This result indicates that this regionally wet and cold episode, during the Heinrich 1 event, also impacted the Southern Altiplano. The ELA rose above 5450 m after 14 ka, synchronously with the Bolling–Allerod.     

Variscan orogeny in Corsica: new structural and geochronological insights,and its place in the Variscan geodynamic framework

In Western Corsica, remnants of pre-batholitic lithological and metamorphic assemblages are preserved as km-scale septa enclosed within Lower Carboniferous to Early Permian plutons. Two groups of septa were recognized: (1) the Argentella and Agriates-Tenda fragments correspond to Neoproterozoic rocks deformed and metamorphosed during the Cadomian–Panafrican orogeny, and (2) the Zicavo, Porto-Vecchio, Solenzara–Fautea, Belgodère, Topiti, and Vignola fragments consist of Variscan metamorphic rocks. The lithological content and the main ductile deformation events for each septum are presented. In the Zicavo, Porto-Vecchio, and Topiti septa, a top-to-the-SW ductile shearing (D1 event) coeval with an amphibolite facies metamorphism is responsible for crustal thickening at ca 360 Ma. This main event was preceded by eclogite and granulite facies metamorphic events preserved as restites within migmatites dated at ca 345–330 Ma. A top-to-the-SE ductile shearing (D2 event) coeval with the crustal melting accommodated the exhumation of the D1 event. In contrast, the Belgodère segment is peculiar as it exhibits a top-to-the-E vergence, although retrogressed high-pressure rocks are also recognized. The pre-Permian fragments are arranged in four NW–SE-striking stripes that define a SW–NE zoning with (1) a Western domain in Topiti, Vignola, Zicavo, Porto-Vecchio, and Solenzara–Fautea; (2) a Neoproterozoic basement with its unconformable Early Paleozoic sedimentary cover in Argentella; (3) an Eastern metamorphic domain in Belgodère; (4) another Neoproterozoic basement with its Upper Paleozoic sedimentary cover in Agriates-Tenda. The Argentella basement is separated from the Western and Eastern domains by two sutures: S1 and S2. The Variscan Corsica represents the Eastern part of the Sardinia–Corsica–Maures segment. The comparison of this segment with other Variscan domains allows us to propose some possible correlations. We argue that the Western domain, Argentella, Belgodère, and Agriates-Tenda domains can be compared with the Southern Variscan belt exposed in French Massif Central–Southern Massif Armoricain, Armorica microblock, Léon block, respectively.     

Field evidence of hydraulic connections between bedrock aquifers and overlying granular aquifers: examples from the Grenville Province of the Canadian Shield

Field evidence of hydraulic connections between a bedrock aquifer and an overlying granular aquifer in the Canadian Shield (Grenville Province) is presented. This issue is rarely considered and investigated despite its important hydraulic and chemical consequences and its widespread occurrence worldwide. The methodology employed is based on complementary field tests conducted at specific experimental sites instrumented both in the rock and in the overlying deposits. One of the bedrock sites revealed a natural hydraulic connection with the overlying granular aquifer caused by the weathered surface of the uppermost bedrock. Another site revealed an artificial hydraulic connection between the bedrock and the granular aquifer created by an improperly sealed casing. A regional study showed that hydraulic connections yield an erroneous interpretation of the true hydraulic properties of the tested aquifer. The detection of hydraulic connections is therefore essential to properly define well-capture areas and contamination conditions. It is recommended to practitioners that pumping tests be performed as well as hydrochemical comparisons of each existing aquifer unit. Falling-head permeability tests are also helpful in verifying the quality of the seal at the bedrock–casing contact. More effective procedural controls and better well-construction practices are necessary to reduce the risks of cross-contamination induced by defective seals.     

Constraints on the formation environment of two chondrule‐like igneous particles from comet 81P/Wild 2

Using chemical and petrologic evidence and modeling, we deduce that two chondrule‐like particles named Iris and Callie, from Stardust cometary track C2052,12,74, formed in an environment very similar to that seen for type II chondrules in meteorites. Iris was heated near liquidus, equilibrated, and cooled at ≤100 °C h^‐1 and within ≈2 log units of the IW buffer with a high partial pressure of Na such as would be present with dust enrichments of ≈10³. There was no detectable metamorphic, nebular, or aqueous alteration. In previous work, Ogliore et al. (2012) reported that Iris formed late, >3 Myr after CAIs, assuming ²⁶Al was homogenously distributed, and was rich in heavy oxygen. Iris may be similar to assemblages found only in interplanetary dust particles and Stardust cometary samples called Kool particles. Callie is chemically and isotopically very similar, but not identical to Iris.     

Large spinel grains in a CM chondrite (Acfer 331): Implications for reconstructions of ancient meteorite fluxes

By dissolving 30–400 kg of marine limestone in HCl and HF acid, our group has previously recovered common relict chromite grains (approximately 63–250 μm) from ordinary chondritic micrometeorites that fell on ancient sea floors, up to 500 Myr old. Here, we evaluate if CM group carbonaceous chondritic material, which makes up an important fraction of the micrometeorite flux today, contains analogous grains that can be searched for in acid residues. We dissolved 8 g of CM2 meteorite Acfer 331 in HF, which yielded a characteristic assemblage of both transparent Mg‐Al‐ and opaque Cr‐spinels >28 μm. We find on average 4.6 and 130 Mg‐Al‐spinel grains per gram in the 63–250 and 28–63 μm size fractions, respectively. These grains are mostly pink or colorless, and often characterized by heterogeneous Cr‐content. Black, opaque Cr‐spinel grains are absent from the >63 μm fraction, but in the 28–63 μm fraction we find approximately 65 such grains per gram meteorite. The individual grains have a characteristic composition, with heterogeneous major element compositions (e.g., 44.4–61.7 wt% Cr₂O₃), but narrow ranges for maximum TiO₂ (0.6–1.6 wt%) and V₂O₃ (0.5–1.0 wt%) concentrations. The content of spinel grains in the 28–63 μm fraction of CM meteorites appears comparable at the order of magnitude level with the content of >63 μm sized chromite grains in fossil L‐chondrites from Ordovician limestone. Our approach of recovering meteoritic spinel from sediment may thus be extended to include CM meteorites, but the smaller size fraction of the acid residues should be searched.     

Migration of brines in the basement rocks of the Athabasca Basin through microfracture networks (P-Patch U deposit,Canada)

The unconformity-type uranium deposits of the Athabasca Basin (Saskatchewan, Canada) are hosted near the unconformity between a middle Proterozoic intracratonic sedimentary basin and an Archean to Paleo-Proterozoic metamorphic and plutonic basement. These deposits, which are considered to be the richest U deposits in the world, are the result of massive basinal fluid migrations in the basement rocks.This study shows that basinal brines have strongly penetrated into the basement not only through faults and major pathways but also by way of dense networks of microfractures which favoured the percolation of fluids down to considerable depths (hundred metres below the unconformity) and their chemical modification (salinity increase) by interaction with basement lithologies. These processes are one of the major causes of uranium mobility within the basement rocks and the formation of unconformity-type mineralization.Microfracture networks, which opened during the basinal brine stage (ca. 1600–1400 Ma) are interpreted as sets of mode I cracks corresponding to a specific stage of deformation and occur as fluid inclusion planes after healing. The stress field at that stage (σ₁ = N130–150 °E, subvertical) partly reopened the earlier microcrack networks (σ₁ = N80–110 °E and N130–150 °E, subvertical) issued from the Trans-Hudson Orogeny late retrograde metamorphic stage (ca. 1795–1720 Ma). The circulation of the two types of fluids (carbonic and brines) occurs thus at two distinct events (Trans-Hudson Orogeny late retrograde metamorphism for carbonic fluids and maximal burial diagenesis for brines) but the same main microfissure geometry was used by the fluids. This demonstrates the existence of a similar stress field direction acting before and after the basin formation. Moreover, the brine circulations in the basement acted in a wider volume than the clay-rich alteration halo surrounding the U-ores, generally considered as the main envelope of fluid percolation outside the fault systems. The data on the chemistry of the fluids and on the geometry of their migration at various scales emphasise the fundamental role of the basement in the chemical evolution of highly saline brines linked to unconformity-related uranium mineralization in the Athabasca Basin.     

Correlative and comparative characterization of main ion concentrations in laterite groundwater in semi-arid northern Burkina Faso

About 24 samples from hand-dug wells and boreholes were used to characterize concentrations of the main inorganic ions in a laterite environment under semi-arid climatic conditions in Tikaré, northern Burkina Faso. It was found that the most represented groundwater anion in groundwater was HCO₃ ⁻ with average levels of 49.1 mg/L in the dry season and 33.5 mg/L in the rainy season. The most represented cation was Ca²⁺ with mean concentrations of 13.7 and 9.5 mg/L, respectively. The main processes, which influence the concentrations of these ions, are evaporation (dry season), local enrichment of recharge water in some elements, ion exchange and fixation by clay minerals (in case of K⁺). The best correlations were found between Ca²⁺ and Mg²⁺ (r = 0.95), Cl⁻ and Na⁺ (r = 0.95), HCO₃ ⁻ and Mg²⁺ (r = 0.89), HCO₃ ⁻ and Ca²⁺ (r = 0.89), and between HCO₃ ⁻ and Na⁺ (r = 0.80). In general, the quality of the groundwater from the different wells sampled for this study was good enough to serve as drinking water. However, there were situations where the quality of water was polluted because of anthropogenic contaminants (mainly NO₃ ⁻, K⁺, Cl⁻) from septic tanks and manure pits located in the vicinity of some sampled wells. In addition, application of fertilizers also represents a potential anthropogenic contamination source with regard to SO₄ ²⁻, Ca²⁺, K⁺, Na⁺, and Mg²⁺. Considering the high concentrations of SO₄ ²⁻, Mg²⁺, Na⁺ and Ca²⁺ found in one borehole, the deeper, fractured aquifers were also likely to be enriched in these elements. In contrast, the shallow aquifers are likely to be contaminated with Cl⁻, NO₃ ⁻ and K⁺. Cl⁻ and K⁺ seem to be locally present in recharge water as shown by their relative higher mean concentrations in the rainy season samples.