A new titanium-bearing calcium aluminosilicate phase: I. Meteoritic occurrences and formation in synthetic systems

Abstract A new titanium-bearing calcium aluminosilicate mineral has been identified in coarse-grained calcium-aluminum-rich inclusions (CAIs) from carbonaceous chondrites. The formula for this phase, which we have temporarily termed “UNK,” is Ca₃Ti(Al, Ti)₂(Si, Al)₃O¹⁴, and it is present in at least 8 of the 20 coarse-grained CAIs from the Allende CV3 chondrite examined as part of this project. The phase occurs in Types A and B1 inclusions as small tabular crystals oriented along two mutually perpendicular planes in melilite. UNK crystallizes from melts in dynamic crystallization experiments conducted in air from four bulk compositions modeled after Types A, B1, B2 and C inclusions. Cooling rates resulting in crystallization of UNK ranged from 0.5 to 200 °C/h from maximum (initial) temperatures of 1375 to 1580 °C. Only below 1190 °C does UNK itself begin to crystallize. To first order, the presence or absence of UNK from individual experiments can be understood in terms of the compositions of residual melts and nucleation probabilities. Compositions of synthetic and meteoritic UNK are very similar in terms of major oxides, differing only in the small amounts of trivalent Ti (7–13% of total Ti) in meteoritic samples. UNK crystallized from the Type A analog is similar texturally to that found in CAIs, although glass, which is typically associated with synthetic UNK, is not observed in meteoritic occurrences. A low Ti end-member of UNK (“Si-UNK”) with a composition near that of Ca₃Al₂Si₄O₁₄ was produced in a few samples from the Type B1 analog. This phase has not been found in the meteoritic inclusions.     

Evidence of regional subsidence and associated interior wetland loss induced by hydrocarbon production, Gulf Coast region, USA

Analysis of remote images, elevation surveys, stratigraphic cross-sections, and hydrocarbon production data demonstrates that extensive areas of wetland loss in the northern Gulf Coast region of the United States were associated with large-volume fluid production from mature petroleum fields. Interior wetland losses at many sites in coastal Louisiana and Texas are attributed largely to accelerated land subsidence and fault reactivation induced by decreased reservoir pressures as a result of rapid or prolonged extraction of gas, oil, and associated brines. Evidence that moderately-deep hydrocarbon production has induced land-surface subsidence and reactivated faults that intersect the surface include: (1) close temporal and spatial correlation of fluid production with surficial changes including rapid subsidence of wetland sediments near producing fields, (2) measurable offsets of shallow strata across the zones of wetland loss, (3) large reductions in subsurface pressures where subsidence rates are high, (4) coincidence of orientation and direction of displacement between surface fault traces and faults that bound the reservoirs, and (5) accelerated subsidence rates near producing fields compared to subsidence rates in surrounding areas or compared to geological rates of subsidence. Based on historical trends, subsidence rates in the Gulf Coast region near producing fields most likely will decrease in the future because most petroleum fields are nearly depleted. Alternatively, continued extraction of conventional energy resources as well as potential production of alternative energy resources (geopressured-geothermal fluids) in the Gulf Coast region could increase subsidence and land losses and also contribute to inundation of areas of higher elevation.     

Quantifying Feeding Behavior of Ribbed Mussels (Geukensia demissa) in Two Urban Sites (Long Island Sound, USA) with Different Seston Characteristics

The Atlantic ribbed mussel, Geukensia demissa, is found in salt marshes along the North American Atlantic Coast. As a first step to study the possibility of future cultivation and harvest of ribbed mussels for nutrient removal from eutrophic urban environments, the feeding behavior of ribbed mussels in situ was studied from July to October 2011. Two locations approximately 80 km apart were used as study sites: Milford Harbor (Connecticut; 41°12′42.46″N, 73°3′7.75″W) and Hunts Point (Bronx, New York; 40°48′5.99″N, 73°52′17.76″W). Total particulate matter was higher at Hunts Point than at Milford Harbor, but the organic content was higher at Milford than at Hunts Point. The relatively low quantity of organic content in Hunts Point seston resulted in a much higher production of pseudofeces by mussels. Mussel clearance and absorption rates were higher at Milford Harbor than at Hunts Point. Nevertheless, mussels at both sites had the same absorption efficiency, suggesting that mussels are able to adapt to conditions at both locations. Ribbed mussels decreased clearance rate when the seston quantity was high at both sites. At Hunts Point, ribbed mussels increased the gut transit time of ingested particles when the amount of inorganic particulates in the water increased. This study does not quantify nutrient removal capacity of G. demissa; however, the environmental tolerance demonstrated here, and current lack of commercial harvest, suggests that this species may be a good candidate for nutrient bioextraction in highly impacted urban environments.     

Solar system X‐rays from charge exchange processes

While X‐ray astronomy began in 1962 and has made fast progress since then in expanding our knowledge about where in the Universe X‐rays are generated by which processes, it took one generation before the importance of a fundamentally different process was recognized. This happened in our immediate neighborhood, when in 1996 comets were discovered as a new class of X‐ray sources, directing our attention to charge exchange reactions. Charge exchange is fundamentally different from other processes which lead to the generation of X‐rays, because the X‐rays are not produced by hot electrons, but by ions picking up electrons from cold gas. Thus it opens up a new window, making it possible to detect cool gas in X‐rays (like in comets), while all the other processes require extremely high temperatures or otherwise extreme conditions. After having been overlooked for a long time, the astrophysical importance of charge exchange for the generation of X‐rays is now receiving increased general attention. In our solar system, charge exchange induced X‐rays have now been established to originate in comets, in all the planets from Venus to Jupiter, and even in the heliosphere itself. In addition to that, evidence for this X‐ray emission mechanism has been found at various locations across the Universe. Here we summarize the current knowledge about solar system X‐rays resulting from charge exchange processes (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

The development of the Space Environment Viability of Organics (SEVO) experiment aboard the Organism/Organic Exposure to Orbital Stresses (O/OREOS) satellite

The Space Environment Viability of Organics (SEVO) experiment is one of two scientific payloads aboard the triple-cube satellite Organism/ORganic Exposure to Orbital Stresses (O/OREOS). O/OREOS is the first technology demonstration mission of the NASA Astrobiology Small Payloads Program. The 1-kg, 1000-cm³ SEVO cube is investigating the chemical evolution of organic materials in interstellar space and planetary environments by exposing organic molecules under controlled conditions directly to the low-Earth orbit (LEO) particle and electromagnetic radiation environment. O/OREOS was launched on November 19, 2010 into a 650-km, 72°-inclination orbit and has a nominal operational lifetime of six months. Four classes of organic compounds, namely an amino acid, a quinone, a polycyclic aromatic hydrocarbon (PAH), and a metallo-porphyrin are being studied. Initial reaction conditions were established by hermetically sealing the thin-film organic samples in self-contained micro-environments. Chemical changes in the samples caused by direct exposure to LEO radiation and by interactions with the irradiated microenvironments are monitored in situ by ultraviolet/visible/near-infrared (UV/VIS/NIR) absorption spectroscopy using a novel compact fixed-grating CCD spectrometer with the Sun as its light source. The goals of the O/OREOS mission include: (1) demonstrating key small satellite technologies that can enable future low-cost astrobiology experiments, (2) deploying a miniature UV/VIS/NIR spectrometer suitable for in-situ astrobiology and other scientific investigations, (3) testing the capability to establish a variety of experimental reaction conditions to enable the study of astrobiological processes on small satellites, and (4) measuring the chemical evolution of organic molecules in LEO under conditions that can be extrapolated to interstellar and planetary environments. In this paper, the science and technology development of the SEVO instrument payload and its measurements are described.     

A history of violence: magma incubation,timing and tephra distribution of the Los Chocoyos supereruption (Atitlán Caldera,Guatemala)

The climactic Los Chocoyos (LCY) eruption from Atitlán caldera (Guatemala) is a key chronostratigraphic marker for the Quaternary period given the extensive distribution of its deposits that reached both the Pacific and Atlantic Oceans. Despite LCY tephra being an important marker horizon, a radioisotopic age for this eruption has remained elusive. Using zircon (U–Th)/He geochronology, we present the first radioisotopically determined eruption age for the LCY of 75 ± 2 ka. Additionally, the youngest zircon crystallization ²³⁸U–²³⁰Th rim ages in their respective samples constrain eruption age maxima for two other tephra units that erupted from Atitlán caldera, W-Fall (130 ⁺¹⁶/₋₁₄ ka) and I-Fall eruptions (56 ^+8.2/_−7.7 ka), which under- and overlie LCY tephra, respectively. Moreover, rim and interior zircon dating and glass chemistry suggest that before eruption silicic magma was stored for >80 kyr, with magma accumulation peaking within ca. 35 kyr before the LCY eruption during which the system may have developed into a vertically zoned magma chamber. Based on an updated distribution of LCY pyroclastic deposits, a new conservatively estimated volume of ~1220 ± 150 km³ is obtained (volcanic explosivity index VEI > 8), which confirms the LCY eruption as the first-ever recognized supereruption in Central America.     

Facing climatic and anthropogenic changes in the Mediterranean basin: What will be the medium-term impact on water stress?

The Mediterranean basin has been identified as one of the world's most vulnerable regions to climatic and anthropogenic changes. A methodology accounting for the basin specific conditions is developed to assess the current and future water stress state of this region. The medium-term evolution of water stress is investigated using climatic scenarios and a water-use scenario based on efficiency improvements following the recommendations of the Mediterranean Strategy for Sustainable Development. Currently, the southern and eastern rims are experiencing high to severe water stress. By the 2050 horizon, a 30–50% decline in freshwater resources is simulated over most of the Mediterranean basin. While total water withdrawals would stabilize, or even decrease (10–40%), in several northern catchments, they would double in southern and eastern catchments. These changes should significantly increase water stress over the Mediterranean basin and exacerbate the disparities between rims.     

Bacterial abundance and production in different water masses around South Island,New Zealand

Abstract

Bacterial numbers and production were measured in the upper water column in the winter and spring of 1993 in five water masses surrounding the South Island of New Zealand. Average bacterial numbers and production were found to be higher in spring (8.5 × 10⁵ cells ml^?1 and 0.20 mg m³ h^?1, respectively) than winter (5.5 × 10⁵ cells ml^?1 and 0.05 mg C m³ h^?1 respectively). Bacterial production was strongly correlated with chlorophyll a and primary production (P < 0.001) in spring but not in winter. Spring bacterial production and at 10 m depth averaged across 28 stations was 23% of primary production, and with a growth efficency of 40%, may have consumed up to 57% of primary production. Bacterial biomass was greater than phytoplankton biomass for 75% of the 10 m depth comparisons during winter sampling and 44% during the spring sampling. The bacterial biomass was found to represent 24.6–33.5% of the nitrogen in particulate organic matter (<200 μm) supporting the concept that in New Zealand oceanic water masses bacteria are of significant biogeochemical importance.     

War on Terror,work in progress: security,surveillance and the configuration of the US workfare state

This paper evaluates the impact of recent shifts in the geopolitical outlook of the United States—specifically the ‘Global War on Terror’ and its domestic ramifications—on the prior project of reconfiguring the US state to an after-Fordist ‘workfare’ paradigm. In particular, the paper attempts to situate recent developments in the reconfiguration of the American welfare state within the context of debates over the ‘exceptional’ nature of US politics post-9/11. The extent to which this has had a bearing on work practices, welfare provision and workfarism is investigated, citing examples from the post-9/11 era. On the basis of such examples it has been suggested that the project of reconfiguring the US welfare state and labour relations does overlap and intersect with the emergency practices that the US state has instituted domestically as part of the War on Terror. However, the reconfiguration of the US welfare state towards a neoliberal or workfarist paradigm is, we argue, largely part of the ‘normal’ (as opposed to exceptional) fabric of US politics. The project of reconfiguring the US welfare state is ongoing and largely autonomous (although not entirely removed) from the use of exceptional practices in relation to the US security state. Investigation of this relationship, we assert, provides a potentially fruitful ‘new direction’ for both critical geopolitics and political economic geography, and grounds for interaction between the two.