Heat capacity, entropy, and magnetic properties of jarosite-group compounds

Jarosite phases are common minerals in acidic, sulfate-rich environments. Here, we report heat capacities (C _p) and standard entropies (S°) for a number of jarosite samples. Most samples are close to the nominal composition AFe₃(SO₄)₂(OH)₆, where A = K, Na, Rb, and NH₄. One of the samples has a significant number of defects on the Fe sites and is called the defect jarosite; others are referred to as A-jarosite. The samples, their compositions, and the entropies at T = 298.15 K are:

Assessment of uncertainties in the response of the African monsoon precipitation to land use change simulated by a regional model

Land use and land cover (LULC) over Africa have changed substantially over the last 60 years and this change has been proposed to affect monsoon circulation and precipitation. This study examines the uncertainties of model simulated response in the African monsoon system and Sahel precipitation due to LULC change using a set of regional model simulations with different combinations of land surface and cumulus parameterization schemes. Although the magnitude of the response covers a broad range of values, most of the simulations show a decline in Sahel precipitation due to the expansion of pasture and croplands at the expense of trees and shrubs and an increase in surface air temperature. The relationship between the model responses to LULC change and the climatologists of the control simulations is also examined. Simulations that are climatologically too dry or too wet compared to observations and reanalyses have weak response to land use change because they are in moisture or energy limited regimes respectively. The ones that lie in between have stronger response to the LULC changes, showing a more significant role in land–atmosphere interactions. Much of the change in precipitation is related to changes in circulation, particularly to the response of the intensity and latitudinal position of the African Easterly Jet, which varies with the changes in meridional surface temperature gradients. The study highlights the need for measurements of the surface fluxes across the meridional cross-section of the Sahel to evaluate models and thereby allowing human impacts such as land use change on the monsoon to be projected more realistically.     

Climate change projections of the North American Regional Climate Change Assessment Program (NARCCAP)

We investigate major results of the NARCCAP multiple regional climate model (RCM) experiments driven by multiple global climate models (GCMs) regarding climate change for seasonal temperature and precipitation over North America. We focus on two major questions: How do the RCM simulated climate changes differ from those of the parent GCMs and thus affect our perception of climate change over North America, and how important are the relative contributions of RCMs and GCMs to the uncertainty (variance explained) for different seasons and variables? The RCMs tend to produce stronger climate changes for precipitation: larger increases in the northern part of the domain in winter and greater decreases across a swath of the central part in summer, compared to the four GCMs driving the regional models as well as to the full set of CMIP3 GCM results. We pose some possible process-level mechanisms for the difference in intensity of change, particularly for summer. Detailed process-level studies will be necessary to establish mechanisms and credibility of these results. The GCMs explain more variance for winter temperature and the RCMs for summer temperature. The same is true for precipitation patterns. Thus, we recommend that future RCM-GCM experiments over this region include a balanced number of GCMs and RCMs.     

Special features of cyclotron radiation in anisotropic plasmas

We analyze the special features of cyclotron radiation in four different modes radiated by a mildly relativistic electron current in an anisotropic plasma, taking into consideration that the radiation is transmitted along the group velocity, rather than the wave normal direction. A systematic series of numerical analysis is carried out, to demonstrate the characteristics of the focussing effect and Doppler effect of the radiation, arising from anisotropy. The parameters used pertain to plasmas and radiators of the types encountered in the terrestrial upper atmosphere and the solar corona.