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41.
Jos M. Marques Paula M. Carreira Maria Rosrio Carvalho Maria J. Matias Fraser E. Goff Maria J. Basto Rui C. Graa Luís Aires-Barros Luís Rocha 《Applied Geochemistry》2008,23(12):3278-3289
This paper reviews the geochemical, isotopic (2H, 18O, 13C, 3H and 14C) and numerical modelling approaches to evaluate possible geological sources of the high pH (11.5)/Na–Cl/Ca–OH mineral waters from the Cabeço de Vide region (Central-Portugal). Water–rock interaction studies have greatly contributed to a conceptual hydrogeological circulation model of the Cabeço de Vide mineral waters, which was corroborated by numerical modelling approaches. The local shallow groundwaters belong to the Mg–HCO3 type, and are derived by interaction with the local serpentinized rocks. At depth, these type waters evolve into the high pH/Na–Cl/Ca–OH mineral waters of Cabeço de Vide spas, issuing from the intrusive contact between mafic/ultramafic rocks and an older carbonate sequence. The Cabeço de Vide mineral waters are supersaturated with respect to serpentine indicating that they may cause serpentinization. Magnesium silicate phases (brucite and serpentine) seem to control Mg concentrations in Cabeço de Vide mineral waters. Similar δ2H and δ18O suggest a common meteoric origin and that the Mg–HCO3 type waters have evolved towards Cabeço de Vide mineral waters. The reaction path simulations show that the progressive evolution of the Ca–HCO3 to Mg–HCO3 waters can be attributed to the interaction of meteoric waters with serpentinites. The sequential dissolution at CO2 (g) closed system conditions leads to the precipitation of calcite, magnesite, amorphous silica, chrysotile and brucite, indicating that the waters would be responsible for the serpentinization of fresh ultramafic rocks (dunites) present at depth. The apparent age of Cabeço de Vide mineral waters was determined as 2790 ± 40 a BP, on the basis of 14C and 13C values, which is in agreement with the 3H concentrations being below the detection limit. 相似文献
42.
43.
Biaxial test simulations using a packing of polygonal particles 总被引:1,自引:0,他引:1
The mechanical response of cohesionless granular materials under monotonic loading is studied by performing molecular dynamic simulations. The diversity of shapes of soil grains is modelled by using randomly generated convex polygons as granular particles. Results of the biaxial test obtained for dense and loose media show that samples achieve the same void ratio at large strains independent of their initial density state. This limit state resembles the so‐called critical state of soil mechanics, except for some stress fluctuations, which remain for large deformations. These fluctuations are studied at the micro‐mechanical level, by following the evolution of the co‐ordination number, force chains and the fraction of the sliding contacts of the sample. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
44.
Mineralogy and geochemistry of El Dorado epithermal gold deposit, El Sauce district, central-northern Chile 总被引:1,自引:0,他引:1
J. Carrillo-Rosúa S. Morales-Ruano D. Morata A. J. Boyce M. Belmar A. E. Fallick P. Fenoll Hach-Alí 《Mineralogy and Petrology》2008,92(3-4):341-360
Summary The El Dorado Au-Cu deposit is located in an extensive intra-caldera zone of hydrothermal alteration affecting Upper Cretaceous
andesites of the Los Elquinos Formation at La Serena (≈ 29°47′S Lat., 70°43′W Long., Chile). Quartz-sulfide veins of economic potential are hosted by N25W and N20E
fault structures associated with quartz-illite alteration (+supergene kaolinite). The main ore minerals in the deposit are
pyrite, chalcopyrite ± fahlore (As/(As + Sb): 0.06−0.98), with electrum, sphalerite, galena, bournonite-seligmanite (As/(As
+ Sb): 0.21−0.31), marcasite, pyrrhotite being accessory phases. Electrum, with an Ag content between 32 and 37 at.%, occurs
interstitial to pyrite aggregates or along pyrite fractures. Pyrite commonly exhibits chemical zonation with some zones up
to 1.96 at.% As. Electron probe microanalyses of pyrite indicate that As-rich zones do not exhibit detectable Au values. Fluid
inclusion microthermometry shows homogenization temperatures between 130 and 352 °C and salinities between 1.6 and 6.9 wt.%
NaCl eq. Isotope data for quartz, ankerite and phyllosilicates and estimated temperatures show that δ18O and δD for the hydrothermal fluids were between 3 and 10‰ and between −95 and −75‰, respectively. These results suggest
the mineralizing fluids were a mixture of meteoric and magmatic waters. An epithermal intermediate-sulfidation model is proposed
for the formation of the El Dorado deposit.
Author’s present address: J. Carrillo-Rosúa, Dpto. de Didáctica de las Ciencias Experimentales, Universidad de Granada, Campus de Cartuja, 18071, Granada, Spain 相似文献
45.
Summary The Aguablanca Ni-Cu-(PGE) magmatic sulphide deposit is associated with a magmatic breccia located in the northern part of
the Aguablanca gabbro (SW, Iberia). Three types of ores are present: semi-massive, disseminated, and chalcopyrite-rich veined
ore. The principal ore minerals are pyrrhotite, pentlandite and chalcopyrite. A relatively abundant platinum-group mineral
(PGM) assemblage is present and includes merenskyite, melonite, michenerite, moncheite and sperrylite. Moreover, concentrations
of base and precious metals and micro-PIXE analyses were obtained for the three ore-types. The mineralogy and the mantle-normalised
chalcophile element profiles strongly suggest that semi-massive ore represents mss crystallisation, whereas the disseminated ore represents an unfractionated sulphide liquid and the chalcopyrite-rich veined
ore a Cu-rich sulphide liquid. Palladium-bearing minerals occur commonly enclosed within sulphides, indicating a magmatic
origin rather than hydrothermal. The occurrences and the composition of these minerals suggest that Pd was initially dissolved
in the sulphides and subsequently exsolved at low temperatures to form bismutotellurides. Negative Pt and Au anomalies in
the mantle-normalised chalcophile element profiles, a lack of Cu-S correlation and textural observations (such as sperrylite
losing its euhedral shape when in contact with altered minerals) suggest partial remobilisation of Pt, Au and Cu by postmagmatic
hydrothermal fluids after the sulphide crystallisation.
Authors’ addresses: R. Pi?a, L. Ortega, R. Lunar, Departamento de Cristalografía y Mineralogía, Facultad de Geología, Universidad Complutense de Madrid, ES-28040 Madrid,
Spain; F. Gervilla, Facultad de Ciencias, Instituto Andaluz de Ciencias de la Tierra, Universidad de Granada-CSIC, Avda. Fuentenueva, s/n, ES-18002
Granada, Spain 相似文献
46.
National flood discharge mapping in Austria 总被引:5,自引:0,他引:5
This article presents the approach and the results of a study in which 30, 100 and 200 year return period flood discharges
were estimated for 26,000 km of Austrian streams. Three guiding principles were adopted: combination of automatic methods
and manual assessments by hydrologists to allow speedy processing and account for the local hydrological situation; combination
of various sources of information including flood peak samples, rainfall data, runoff coefficients and historical flood data;
and involvement of the Hydrographic Services to increase the accuracy and enhance the acceptance of results. The flood discharges
for ungauged catchments were estimated by the Top-kriging approach with manual adjustment to the local flood characteristics.
The adopted combination approach proved to be very efficient both in terms of the project time required and in terms of the
accuracy and acceptability of the estimated flood discharges of given return periods. 相似文献
47.
B. Bühn 《Mineralogy and Petrology》2008,92(3-4):453-470
Summary Two bimodal carbonatite complexes in Namibia of Cretaceous age are explored as to the presence and composition of a coexisting
carbonatitic fluid. The Kalkfeld and Ondurakorume complexes contain both Ca- and Mg/Fe-carbonatites, composed of calcite alone
or calcite with ferroan dolomite, fluorapatite and strontianite. The major element evolution in the bulk rocks from s?vites
to beforsites is due to crystallization of calcite and fluorapatite. All carbonatites show a negative Y anomaly in normalised
REE plots. Fractionation is accompanied by successively lower HREE contents between Tb and Yb, expressed by the ratios Nd/Ho
and Ho/Lu. The evolution of this downward-facing hump goes along with decreasing Y contents in bulk rocks and minerals. All
this requires an additional phase coexisting with the carbonate liquid during fractionation. Comparison between the bulk rocks
and the expelled fluid shows that the latter had preferentially accumulated the HREE and Y. Further evidence for this process
are hydrothermal, HREE, Y-rich fluorites in other carbonatite complexes which reflect the composition of the expelled fluid.
The high strength of fluoride complexes suggests that fluoride complexing in the carbonatitic fluid is the process responsible
for extracting HREE and Y from the carbonatite magma, leaving fractionated carbonatite rocks depleted in these elements. The
geochemical evolution of carbonatite magmas along fractionation has therefore to be considered in a melt-mineral-fluid system.
Correspondence: B. Bühn, Instituto de Geociências, Universidade de Brasilia, Campus Universitário Darcy Ribeiro, Brasilia
70910-900, Brazil 相似文献
48.
49.
Zusammenfassung Die Davoser Windverh?ltnisse werden in ihrem tages- und jahreszeitlichen Ablauf sowie in ihrer Abh?ngigkeit von verschiedenen
typischen Wetterlagen untersucht. Neben den ungest?rten Sch?nwetterlagen mit ihrem ausgepr?gten Talwind, der wie der Malojawind
talabw?rts weht, werden die F?hnstr?mung aus Südwest und die Nordoststr?mung bei Staulagen und Bise kurz besprochen. Gegenüber
dem benachbarten Dischmatal zeigt sich ein sp?terer Beginn des Talwindes bei Sch?nwetterlagen, w?hrend im Vergleich zu anderen
T?lern, z. B. zum Wallis, ein früheres und schw?cheres nachmitt?gliches Windmaximum auftritt.
Mit 6 Textabbildungen
Herrn Dr.W. M?rikofer zu seinem 70. Geburtstag gewidmet. 相似文献
Summary The wind at Davos is analysed in his diurnal and annual variation and in the depence on the different weather types. The fair and undisturbed weather shows a typical valley breeze during the day, but not in the normal direction towards the higher part of the valley, but downstream, similar to the Malojawind in the Engadine. The opposite wind direction, from southwest, characterises the foehn-situation. Northeasterly winds develop in the case of higher pressure north of the Alps (e. g. in situations of barrage). The valley-breeze begins later than in the adjacent Dischma Valley, but it is weaker and reaches the highest intensity earlier than in other valleys, as e. g. in the Valais.
Résumé Les vents de Davos sont analysés selon leurs variations diurnes et annuelles et selon des types de temps caractéristiques. La situation de beau temps montre un vent de vallée assez accentué, soufflant du haut en bas, donc dans une direction anormale, mais analogue au vent de la Maloja en Engadine. En cas de ?foehn? le vent souffle du sud-ouest tandis qu'un vent du nord-est se manifeste par situations de surpression au nord des Alpes. Le vent de vallée se met à souffler plus tard à Davos que dans la vallée de Dischma toute proche. Il y atteint par contre sa vitesse maximale plus t?t que les vents correspondants d'autres vallées p. ex. du Valais. Le maximum y est cependant moins élevé.
Mit 6 Textabbildungen
Herrn Dr.W. M?rikofer zu seinem 70. Geburtstag gewidmet. 相似文献
50.
Alberto C. Montefinale Liliana A. Masironi Henry M. Papée 《Pure and Applied Geophysics》1963,54(1):207-211
Summary Correlation between some physical and chemical variables, measured at 28 stations of the United States Weather Bureau Network, and seasonal and annual frequencies of precipitation, has been attempted with the aim of gaining insight into the bearing of such variables, on occurrence of precipitation. — Concurrent trends of frequencies with local temperature functions, altitude parameters, precipitable water vapour increments, and some chemical species have been found.Contribution of the «Centro Nucleazione Aerosoli» of the National Research Council of Italy, Via Vettore 4 (Monte Sacro),Roma. 相似文献