Isoprene and Its Oxidation Products Methyl Vinyl Ketone, Methacrolein, and Isoprene Related Peroxides Measured Online over the Tropical Rain Forest of Surinam in March 1998

Airborne measurements of volatile organic compounds (VOC) were performed overthe tropical rainforest in Surinam (0–12 km altitude,2°–7° N, 54°–58° W) using the proton transferreaction mass spectrometry (PTR-MS) technique, which allows online monitoringof compounds like isoprene, its oxidation products methyl vinyl ketone,methacrolein, tentatively identified hydroxy-isoprene-hydroperoxides, andseveral other organic compounds. Isoprene volume mixing ratios (VMR) variedfrom below the detection limit at the highest altitudes to about 7 nmol/molin the planetary boundary layer shortly before sunset. Correlations betweenisoprene and its product compounds were made for different times of day andaltitudes, with the isoprene-hydroperoxides showing the highest correlation.Model calculated mixing ratios of the isoprene oxidation products using adetailed hydrocarbon oxidation mechanism, as well as the intercomparisonmeasurement with air samples collected during the flights in canisters andlater analysed with a GC-FID, showed good agreement with the PTR-MSmeasurements, in particular at the higher mixing ratios.Low OH concentrations in the range of 1–3 × 10⁵molecules cm^-3 averaged over 24 hours were calculated due to lossof OH and HO₂ in the isoprene oxidation chain, thereby stronglyenhancing the lifetime of gases in the forest boundary layer.     

The post-depositional reactivity of iron and managanese in the sediments of a macrotidal estuarine system

Four cores of anoxic sediments were collected from the Seine estuary to assess the early diagenesis pathways leading to the formation of previously reactive phase. Pore waters were analyzed for dissolved iron (Fe) and manganese (Mn) and different ligands (e.g., sulfate, chloride, total inorganic carbon). The anoxic zone is present up to the first centimeter depth, in these conditions the reduction of Mn and Fe oxides and SO₄ ²⁻ was verified. The sulfate reduction was well established with a subsequent carbon mineralization in the NORMAI94 core. The chemical speciation of Mn and Fe in the dissolved and solid phases was determined. For the dissolved phase, thermodynamic calculations were used to characterize and illustrate the importance of carbonate and phosphate phases as sinks for Fe and Mn. The ion activity product (IAP) of Fe and Mn species was compared to the solubility products (Ks) of these species. In the solid phase, the presence of higher concentration of calcium carbonate in the Seine sediments is an important factor controlling Mn cycle. The carbonate-bound Mn can reach more than 75% of the total concentration. This result is confirmed by the use of electron spin resonance (ESR) spectroscopy. The reduction of Fe is closely coupled to the sulfate reduction by the formation of new solid phases such as FeS and FeS₂, which can be regarded as temporal sinks for sulfides. These forms were quantified in all cores as acid volatile sulfide (AVS: FeS+ free sulfide) and chromium reducible sulfide (CRS: FeS₂+elemental sulfur S⁰).     

Epiphytic orchids and their ecological niche under anthropogenic influence in central Himalayas,Nepal

The survival chance of epiphytic orchids today not only depends on the natural site conditions required by the orchids but also on anthropogenic changes in site conditions.This study answers two questions:(1) What is the ecological niche of the different epiphytic orchid species?(2) What are the ecological factors that threaten epiphytic orchid's population under anthropogenic disturbances? Our study area was the Kathmandu valley,Nepal,with its subtropical forest.We established 156 systematically selected sampling points in the Kathmandu area covering different types of ecosystems under human impacts such as densely populated area,agricultural land,mixed agricultural and settled area,old tree patches,and a natural forest in a national park.The ecological niche of the orchid species was analyzed with a principal component analysis(PCA).The correlations between the different site factors were statistically significant.Spearman's rank correlation matrices showed that the variables land-use intensities with altitude,and height with diameter in breast height(dbh) of host had the highest significant positive correlation coefficient(0.67 and 0.64 respectively).On the other hand,host bark p H and altitude as well as land use had a significantly strong negative correlation coefficient(-0.80 and-0.61,respectively).Different epiphytic orchid species interact differently with the given set ofenvironmental factors:for occurrence of Vanda cristata there is no single environmental factor of special influence,while for Rhynchostylis retusa high bark p H and high light availability are important.First two axis of the PCA explained more than 50% of the total variance.Most orchid species occupy a specific,narrow niche in this ecological space.The main causes of anthropogenic influence of orchid population in the Kathmandu Valley are loss of adequate host trees(species and size) and increasing air pollution,resulting in increasing host bark p H.     

Bodenkundliche Probleme in ihrer Bedeutung für die Geologie

Ohne Zusammenfassung     

Marine Minerals in the Mexican Pacific: Toward Efficient Resource Management

Vast reserves of marine minerals are known to occur within the Mexican Exclusive Economic Zone. These reserves include: (1) heavy mineral placers rich in titanium and iron along the coast of San Antonio del Mar, Baja California and the southern States of Oaxaca and Guerrero; (2) phosphorites, which represent the only source for superphosphate fertilizers along the Pacific coast off the Baja California peninsula and the Gulf of Tehuantepec; and (3) manganese oxide deposits in nodule and crusts located adjacent to the Clarion-Clipperton Zone and containing high concentrations of Cu + Ni + Co (up to 1.9%), which are essential for the steel and super-alloy industries. Few but important efforts toward surveying these deposits have been carried out by Mexican and international researchers. Relevant data generated by these investigations are reviewed here and put together in a single document. Adequate knowledge of Mexican mineral resources is essential for the development of management strategies when offshore mining starts during this century. Thus, the review discusses the economics inherent to ocean mining in Mexico, setting baselines for future exploration and development activities in the Mexican Exclusive Economic Zone.     

A Custom Chip Set for a Frequency-Agile High-Resolution Sonar Array

This paper describes two custom-integrated circuits, which form the core building blocks of a versatile wideband sonar array. An analog 0.5-mum complementary metal-oxide-semiconductor (CMOS) chip houses a preamplifier, an antialias filter, and a high-resolution (14-16 b) data converter based on delta-sigma modulation techniques. A complementary 0.35-mum digital CMOS chip incorporates a four-stage multirate filter cascade, which provides a wideband and two narrowband outputs. The complex narrowband outputs are obtained via a subsampling mixer and span over the top 15% or the top 10%, respectively, of the original band. The system sampling clock can vary from 2 to 10 MHz to enable tuning to a specific frequency window located anywhere between 30 and 150 kHz. Both chips process four sonar channels in parallel and, when clocked at 10 MHz, dissipate a combined power of 416 mW (104 mW per channel).     

Ice thawing,mountains falling—are alpine rock slope failures increasing?

Many high‐mountain environments of the world have seen dramatic changes in the past years and decades. Glaciers are retreating and downwasting, often at a dramatically fast pace, leaving large amounts of potentially unstable debris, moraines and rock slopes behind. Although in the main invisible to the eye of an observer, permafrost, i.e. rock and debris with permanent zero or subzero temperatures, is thawing. Several slopes have become unstable and landslides potentially related to permafrost degradation have received wide‐ranging attention from both scientists and the media. A number of those landslides can be related to the effects of recent changes in the cryosphere, which are ultimately driven by changes in climatic parameters, in particular temperature and precipitation.     

Doing community geography

Community Geography offers researchers, community groups, and students opportunities to engage in action oriented applied geographical research. Creating and sustaining these research programs can be challenging, programs can involve many partners from both academic and the community, have different goals and purposes, and utilize a variety of methods to perform research. In this paper we offer a framework of three primary overarching principles for implementing CG projects; (1) Who, (2) Why, and (3) How. (1) “Who” describes who is involved in CG, including researchers, community partners, academic institutions, (2) “Why” describes the justifications and benefits of taking this approach. (3) “How” explains how CG borrows methodologies from many disciplines within geography and beyond. Our examples are not exhaustive; rather, they serve as starting points to inspire researchers interested in CG.