‘Evolution of a Storm-driven Cloudy Boundary Layer in the Arctic’

To investigate the processes of development and maintenance of low-level clouds during major synoptic events, the cloudy boundary layer under stormy conditions during the summertime Arctic has been studied using observations from the Surface Heat Budget of the Arctic Ocean (SHEBA) experiment and large-eddy simulations (LES). On 29 July 1998, a stable Arctic cloudy boundary-layer event was observed after the passage of a synoptic low pressure system. The local dynamic and thermodynamic structure of the boundary layer was determined from aircraft measurements including the analysis of turbulence, cloud microphysics and radiative properties. After the upper cloud layer advected over the existing cloud layer, the turbulent kinetic energy (TKE) budget indicated that the cloud layer below 200 m was maintained predominantly by shear production. Observations of longwave radiation showed that cloud-top cooling at the lower cloud top has been suppressed by radiative effects of the upper cloud layer. Our LES results demonstrate the importance of the combination of shear mixing near the surface and radiative cooling at the cloud top in the storm-driven cloudy boundary layer. Once the low-level cloud reaches a certain height, depending on the amount of cloud-top cooling, the two sources of TKE production begin to separate in space under continuous stormy conditions, suggesting one possible mechanism for the cloud layering. The sensitivity tests suggest that the storm-driven cloudy boundary layer is possibly switched to the shear-driven system due to the advection of upper clouds or to the buoyantly driven system due to the lack of wind shear. A comparison is made of this storm-driven boundary layer with the buoyantly driven boundary layer previously described in the literature.     

Chemical Characteristics of Carbonaceous Aerosols During Dust Storms over Xi'an in China

Characterization of carbonaceous aerosols including CC （carbonate carbon）, OC （organic carbon）, and EC （elemental carbon） were investigated at Xi＇an, China, near Asian dust source regions in spring 2002. OC varied between 8.2 and 63.7μgm^- 3, while EC ranged between 2.4 and 17.2 μ m^-3 during the observation period. OC variations followed a similar pattern to EC and the correlation coefficient between OC and EC is 0.89 （n=31）. The average percentage of total carbon （TC, sum of CC, OC, and EC） in PM2.5 during dust storm （DS） events was 13.6%, which is lower than that during non-dust storm （NDS） periods （22.7%）. CC, OC, and EC accounted for 12.9%, 70.7%, and 16.4% of TC during DS events, respectively. The average ratio of OC/EC was 5.0 in DS events and 3.3 in NDS periods. The OC-EC correlation （R^2=0.76, n=6） was good in DS events, while it was stronger （R^2=0.90, n=25） in NDS periods. The percentage of watersoluble OC （WSOC） in TC accounted for 15.7%, and varied between 13.3% and 22.3% during DS events. The distribution of eight carbon fractions indicated that local emissions such as motor vehicle exhaust were the dominant contributors to carbonaceous particles. During DS events, soil dust dominated the chemical composition, contributing 69% to the PM2.5 mass, followed by organic matter （12.8%）, sulfate （4%）, EC （2.2%）, and chloride （1.6%）. Consequently, CC was mainly entrained by Asian dust. However, even in the atmosphere near Asian dust source regions, OC and EC in atmospheric dust were controlled by local emission rather titan the transport of Asian dust.     

Localized ductile thrusting north of the Variscan Front,Ross Island,southwest Ireland

Two thrusts occur on Ross Island: the Head of Ross Thrust and the more southerly Ross Island Thrust. These lie to the north of the Killarney–Mallow Fault (KMF), the boundary frequently interpreted as the Variscan Front. The Ross Island Thrust, exposed in outcrop and in seven borehole cores, has emplaced dark blue–grey limestones of the Courceyan Ballysteen Formation over pale grey–brown Rockfield Limestone Formation of Chadian–Holkerian age. These lithologies at Ross Island exhibit a continuum of deformation at both the micro‐ and macro‐scale, beginning with the generation of a spaced cleavage, formed during layer parallel shortening, that was subsequently rotated into parallelism with fold axial planes. Extensional microstructures are predominant in thin section and are associated with attenuation of the fold limb. Calcite veins are also attenuated and lie parallel to a mylonitic fabric close to the thrust plane. Lithological boundaries, the prominent pressure solution cleavage and the southerly dipping limb of an asymmetrical antiform are all parallel and form a composite planar anisotropy. This has controlled the location of the ductile Ross Island Thrust, which formed during the attenuation and shearing of a common fold limb. Ductile thrusts within the limestones at Ross Island contrast with the reactivation of basin‐margin extensional faults further to the south along the major KMF. The Ross Island Thrust is considered to result from deformation ahead of the major northerly propagating Variscan décollement thrust and does not necessitate a continuous décollement structure north of the KMF. Mineralization at Ross Island exhibits remobilization associated with the formation of a pressure‐solution cleavage and probably pre‐dates thrusting. Copyright © 2003 John Wiley & Sons, Ltd.     

3D model of fracture zones at Soultz-sous-Forêts based on geological data,image logs,induced microseismicity and vertical seismic profiles

This study presents a new deterministic 3D model of the fracture zones observed in the granitic reservoir of the Soultz European geothermal project. The major fracture zones encountered around 6 wells (4550, EPS1, GPK1, GPK2, GPK3 and GPK4) consist in 53 main structures that are located and characterized in terms of size and orientation: 39 fracture zones, 8 microseismic structures and 6 structures derived from vertical seismic profiles are represented in the 3D model using Discrete Fracture Network tools of the gOcad modelling platform (Paradigm?, Earth Decision?). This work illustrates the complexity of 3D fracture zone correlation and interpretation in crystalline rock masses characterized at meter scale (borehole) and at the reservoir scale (kilometer) thanks to geophysical imaging techniques.     

The deep geothermal potential of the Berlin area

In this study, we model the geothermal potential of deep geological formations located in the Berlin region in Germany. Berlin is situated in a sedimentary geological setting (northeastern German basin), comprising low-enthalpic aquifers at horizons down to 4–5 km depth. In the Berlin region, the temperature increases almost linearly with depth by about 30 K per kilometer, thus allowing for direct heating from deep aquifer reservoirs in principle. Our model incorporates eight major sedimentary units (Jurassic, Keuper, Muschelkalk, Upper/Middle/Lower Buntsandstein, Zechstein Salt and Sedimentary Rotliegend). Owing to lack of available petro-physical rock data for the Berlin region, we have evaluated literature data for the larger northeastern German basin to develop a thermodynamic field model which regards depth-corrected equations of state within statistical intervals of confidence. Integration over the thicknesses of the respective structural units yields their “heat in place”—energy densities associated with the pore fluid and the rock matrix under local conditions in Joule per unit area at the surface. The model predicts that aquifers in the Middle Buntsandstein and in the Sedimentary Rotliegend may well exhibit energy densities about 10 GJ m^?2 for the pore fluids and 20 GJ m^?2 to 40 GJ m^?2 for the rock matrices on average. Referring these figures to the city area of Berlin (about 892 km²), a significant hydrothermal potential results, which however remained undeveloped until today for the reason of present development risks. The model accounts for these risks through statistical intervals of confidence which are in the order of ±60 to ±80 % of the trend figures. To minimize these uncertainties, scientific field explorations were required in order to assess the petro-physical aquifer properties locally.     

Imaging Pathways in Fractured Rock Using Three‐Dimensional Electrical Resistivity Tomography

Major challenges exist in delineating bedrock fracture zones because these cause abrupt changes in geological and hydrogeological properties over small distances. Borehole observations cannot sufficiently capture heterogeneity in these systems. Geophysical techniques offer the potential to image properties and processes in between boreholes. We used three‐dimensional cross borehole electrical resistivity tomography (ERT) in a 9 m (diameter) × 15 m well field to capture high‐resolution flow and transport processes in a fractured mudstone contaminated by chlorinated solvents, primarily trichloroethylene. Conductive (sodium bromide) and resistive (deionized water) injections were monitored in seven boreholes. Electrode arrays with isolation packers and fluid sampling ports were designed to enable acquisition of ERT measurements during pulsed tracer injections. Fracture zone locations and hydraulic pathways inferred from hydraulic head drawdown data were compared with electrical conductivity distributions from ERT measurements. Static ERT imaging has limited resolution to decipher individual fractures; however, these images showed alternating conductive and resistive zones, consistent with alternating laminated and massive mudstone units at the site. Tracer evolution and migration was clearly revealed in time‐lapse ERT images and supported by in situ borehole vertical apparent conductivity profiles collected during the pulsed tracer test. While water samples provided important local information at the extraction borehole, ERT delineated tracer migration over spatial scales capturing the primary hydrogeological heterogeneity controlling flow and transport. The fate of these tracer injections at this scale could not have been quantified using borehole logging and/or borehole sampling methods alone.     

Vertical mixing of gravel over a long flood series

Vertical sediment exchange is a fundamental component of bedload transport in gravel‐bed channels. This paper describes the characteristic depth of exchange achieved over a long flood series. Analysis is based on 11 recoveries of magnetically tagged gravels deployed in Carnation Creek, Canada, completed between 1990 and 2008. Vertical grain exchange mixes gravels throughout the streambed relatively rapidly. Within one to eight floods the mean burial depth approaches two times the surface layer thickness, quantified by the 90th percentile of the size distribution. Finer gravels are mixed more rapidly into the bed than coarser gravels. Both active and passive grain exchanges throughout most of the bed produce the overall vertical distribution of marked grains. Gravel exchanges exhibit fairly consistent patterns once tracers are well mixed by large floods. Results highlight the role of flood sequence in determining exchange depths, support the notion of an upper limit to exchange, and underscore the importance of passive grain exchange. Copyright © 2011 John Wiley & Sons, Ltd.     

Selecting parameters for the environmental interpretation of peat molecular chemistry – A pyrolysis-GC/MS study

A number of samples from a deep peat bog in Tierra del Fuego were analyzed using pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) in order to extract parameters that might be used to interpret the peat chemistry in terms of vegetation change, anaerobic and aerobic decomposition, and fire incidence. The choice of parameters was based on factor analysis of 177 pyrolysis products, quantified for 13 samples, separated into extract and residue, as well as the total samples. Factor analysis of extracts, residues and total samples yielded similar classifications in terms of vegetation and decomposition. Pyrolysis products and ratios that most clearly differentiated samples were used to interpret the depth profile. Although interpretation was not always straightforward, indications of parameters to describe vegetation shifts, aerobic and anaerobic decomposition, and fire largely coincided. These parameters will be used in a forthcoming study for a more complete interpretation of the peat profile.     

Nitrogen, phosphorus, silica, and carbon in Moreton Bay, Queensland, Australia: Differential limitation of phytoplankton biomass and production

Subtropical estuaries have received comparatively little attention in the study of nutrient loading and subsequent nutrient processing relative to temperate estuaries. Australian estuaries are particularly susceptible to increased nutrient loading and eutrophication, as 75% of the population resides within 200 km of the coastline. We assessed the factors potentially limiting both biomass and production in one Australian estuary, Moreton Bay, through stoichiometric comparisons of nitrogen (N), phosphorus (P), silicon (Si), and carbon (C) concentrations, particulate compositions, and rates of uptake. Samples were collected over 3 seasons in 1997–1998 at stations located throughout the bay system, including one riverine endmember site. Concentrations of all dissolved nutrients, as well as particulate nutrients and chlorophyll, declined 10-fold to 100-fold from the impacted western embayments to the eastern, more oceanic-influenced regions of the bay during all seasons. For all seasons and all regions, both the dissolved nutrients and particulate biomass yielded N:P ratios <6 and N:Si ratios <1. Both relationships suggest strong limitation of biomass by N throughout the bay. Limitation of rates of nutrient uptake and productivity were more complex. Low C:N and C:P uptake ratios at the riverine site suggested light limitation at all seasons, low N:P ratios suggested some degree of N limitation and high N:Si uptake ratios in austral winter suggested Si limitation of uptake during that season only. No evidence of P limitation of biomass or productivity was evident.