Aerosol light absorption, black carbon, and elemental carbon at the Fresno Supersite, California

Particle light absorption (b_ap), black carbon (BC), and elemental carbon (EC) measurements at the Fresno Supersite during the summer of 2005 were compared to examine the equivalency of current techniques, evaluate filter-based b_ap correction methods, and determine the EC mass absorption efficiency (σ_ap) and the spectral dependence of b_ap. The photoacoustic analyzer (PA) was used as a benchmark for in-situ b_ap. Most b_ap measurement techniques were well correlated (r ≥ 0.95). Unadjusted Aethalometer (AE) and Particle Soot Absorption Photometer (PSAP) b_ap were up to seven times higher than PA b_ap at similar wavelengths because of absorption enhancement by backscattering and multiple scattering. Applying published algorithms to correct for these effects reduced the differences to 24 and 17% for the AE and PSAP, respectively, at 532 nm. The Multi-Angle Absorption Photometer (MAAP), which accounts for backscattering effects, overestimated b_ap relative to the PA by 51%. BC concentrations determined by the AE, MAAP, and Sunset Laboratory semi-continuous carbon analyzer were also highly correlated (r ≥ 0.93) but differed by up to 57%. EC measured with the IMPROVE/STN thermal/optical protocols, and the French two-step thermal protocol agreed to within 29%. Absorption efficiencies determined from PA b_ap and EC measured with different analytical protocols averaged 7.9 ± 1.5, 5.4 ± 1.1, and 2.8 ± 0.6 m²/g at 532, 670, and 1047 nm, respectively. The Angström exponent (α) determined from adjusted AE and PA b_ap ranged from 1.19 to 1.46. The largest values of α occurred during the afternoon hours when the organic fraction of total carbon was highest. Significant biases associated with filter-based measurements of b_ap, BC, and EC are method-specific. Correcting for these biases must take into account differences in aerosol concentration, composition, and sources.     

Connexion porphyre cuprifère–épithermaux de type low-sulfidation : analyse structurale et représentation 3D du secteur de Bolcana,monts Apuseni,Roumanie

The AuPbZn low-sulfidation epithermal ore deposits of Troita, Trestia, and Magura (Apuseni Mountains, Romania) are spatially related to the Bolcana Cu-porphyry. In an attempt to demonstrate the connection between these mineralizations, a geometric study was made based on structural measurements and GOCAD^© geomodeller 3D representation of deposits. This study indicates that a specific spatial distribution of the different Au and PbZn veins of the epithermal deposits occurs around the Cu-porphyry, which cannot result from telescoped systems. To cite this article: O. Cardon et al., C. R. Geoscience 337 (2005).     

Diffusion And Flow In Gravel,Soil, And Whole Rock

Transport parameters (diffusion coefficients, D(/), hydraulic conductivities, K(/), and retardation factors, R_f were experimentally determined in unsaturated soil, gravel, bentonite, and whole rock over a wide range of water contents, fixed at desired levels using the Unsaturated Flow Apparatus (UFA^TM). Effective diffusion coefficients in all media were found primarily to be a function of volumeric water cintent (/) and not material characteristics, except where the characteristics affect or determine water content. At high water contents, D(/) gradually declines as water content decreases, from 10^-5cm²/s at a / of about 50% to 10^-7cm²/s at a / of about 5%, followed by a sharp decline as surface films become thin and discontinuous, and pendular water elements become very small, from 10^-7cm²/s at a / of about 5% to 10^-10cm²/s at a / of about 0,5%. The several whole rock cores studied behaved similary. In aggregate material such as gravel and soil where the particles themselves have significant porosity, only the surface water content, not the internal water of the particles, contributes to the diffusion coefficient and hydraulic conductivity under unsaturated conditions, although the internal water is very important in retardation and other chemical effects. Experimentally determined K(/) compares favorably to van Genuchten/Mualem relationships calculated from laboratory-determined water retention versus matric potential data obtained on the same soils. Experimentally determined K(/) for whole rock appears to validate capillary bundle theory. Résumé. Diffusion et écoulement dans les graviers, les sols et les roches. Les paramètres de flux (coefficient de diffusion, D(‹), conductivité hydraulique, K(‹), et facteur de retard, R_f) ont été déterminés expérimentalement dans des formations non saturées (sol, gravier, benthonite et roche consolidée) pour une large gamme de tenneurs en eau (‹); ces teneurs en eau ont été ajustées aux valeurs désirées grâce à un dispositif spécial fournissant un écoulement non saturé (UFATM). Les résultats montrent que les coefficients de diffusion efficace de tous ces milieux sont d'abord fonction de la teneur volumique en eau et non des caractéristiques du matéeriau, sauf lorsque ces caractéristiques affectent ou déterminent la teneur en eau. Pour les fortes teneurs en eau, D(‹) décroit progressivement avec la teneur en eau, de 10 ^ч cm²/s pour un ‹ de 50% jusqu'à 10^щ cm²/s pour environ 5%. Lorsque les films d'eau deviennent minces et discontinus et lorsque la fraction d'eau gravitaire devient trop faible, D(‹) diminue très brutalement de 10^щ cm²/s pour un ‹ de 5% à 10^⪞ cm²/s pour un ‹ de 0,5%. Plusieurs roches consolidées, testées sur carottes, se comportent de la même façon. Dans les agrégats, comme les graviers et les sols, où les particules possèdent une porosité propre, seule la teneur en eau intergranulaire, et non l'eau de l'intérieur des particules, contribue à la valeur du coefficient de diffusion et à la conductivité hydraulique, dans des conditions non saturées, bien que l'eau intragranulaire joue un rôle très important quant au retard et aux autres effets chimiques. Les Valeurs de K(‹) déterminées expérimentalement montrent un bon accord avec les relations de van Genuchten/Mualem calculées à partir des teneurs en eau de rétention, déterminées au laboratoire en fonction du potentiel matriciel obtenu sur les mêmes sols. Les valeurs expérimentales de K(‹) pour des roches consolidées semblent valider la théorie du faisceau capillaire.     

The effect of species on lacustrine δ18Odiatom and its implications for palaeoenvironmental reconstructions

The oxygen isotope composition of diatom silica (δ¹⁸O_diatom) is increasingly being used to reconstruct climate from marine and lacustrine sedimentary archives. Although diatoms are assumed to precipitate their frustule in isotopic equilibrium with their surrounding water, it is unclear whether internal processes of a given species affect the fractionation of oxygen between the water and the diatom. We present δ¹⁸O_diatom data from two diatom size fractions (3–38 and >38 µm) characterized by different species in a sediment core from Heart Lake, Alaska. Differences in δ¹⁸O_diatom between the two size fractions varies from 0 to 1.2‰, with a mean offset of 0.01‰ (n = 20). Fourier transform infrared spectroscopy confirms our samples consist of pure biogenic silica (SiO₂) and δ¹⁸O_diatom trends are not driven by contamination. The maximum offset is outside the range of error, but the mean is within analytical error of the technique (± 1.06‰), demonstrating no discernible species‐dependent fractionation in δ¹⁸O_diatom. We conclude that lacustrine δ¹⁸O_diatom measurements offer a reliable and valuable method for reconstructing δ¹⁸O_water. Considering the presence of small offsets in our two records, we advise interpreting shifts in δ¹⁸O_diatom only where the magnitude of change is greater than the combined analytical error.     

Environmental conditions inferred from multi-element concentrations in sediments off Cauvery delta,Southeast India

We present multi-element concentrations in the surface sediments from the offshore of Cauvery delta of southeast India to evaluate the impact of coastal pollution on the geochemical behaviour of surface deposits. For this study, 16 surface sediment samples were collected from the offshore of Cauvery delta of southeast India and were analysed using traditional XRF for various major (SiO₂, Al₂O₃, MgO, Fe₂O₃, MnO, Na₂O, K₂O, CaO, P₂O₅, TiO₂) and trace elements (Rb, Sr, Ba, Y, Zr, Nb, V, Cr, Co, Ni, Cu, Zn, Th, Pb) after powdering it to ASTM 230 (<63 μm). The main objectives of this study were to understand the geochemical behaviour of the coastal surface sediments and its performance and relation with the pollution indices and statistical analysis. To meet out the objective, pollution indices such as enrichment factor (EF), contamination factor (CF) and Geoaccumulation Index (I _geo) were calculated and statistical analyses were performed to understand the relationship between the geochemical parameters. Both EF and I _geo show the enrichment of Cu, Cr and Zr, whereas CF shows enrichment of Cu and Cr. Statistical analyses exhibit poor correlation between these elements and fine fraction indicating the insignificant role played by both grain size and organic matter. Strong positive association between Cu and Zn with CaCO₃ exhibits the role of carbonates in precipitating these metals from the overlying water column possibly related to agricultural pollution. Distribution and association of other elements suggest the influence of mineralogy in geochemical composition of surface sediments. Based on this study, we suggest that environmental indices alone should not be considered for evaluating environmental conditions and a prior geogenic characterisation of the sediments is necessary.     

Contamination of saltmarsh sediments and biota by CCA treated wood walkways

Sediments, marsh grasses, and ribbed mussels were collected under two CCA wood walkways (15 and 3 years old) and 1, 3, and 10 m out, in the high, middle and low marshes. These sediments, and samples from reference sites, were analyzed for Cu, Cr, and As by atomic absorption spectrophotometry. Metal concentrations were highly elevated under the walkways and up to 10 m away. Dispersal of contaminants near the old walkway was greatest in the low marsh, less in the middle, and least in the high marsh, corresponding to periods of tidal inundation. Accumulation under the walkway was generally greatest in the low marsh. Contamination was much higher in sediments under the new walkway than the old one, but metals had not dispersed as far. Accumulation patterns in plants were similar, but the contamination did not disperse as far and was not greater under the new vs the old walkway, despite differences in sediment concentrations. In mussels, bioaccumulation was seldom statistically significant, due largely to small sample sizes.     

Small-scale,patchy distributions of infauna in hydrodynamically mobile continental shelf sands: Do ripple crests and troughs support different communities?

Spatial variability of infauna with respect to distribution of topographic habitat features was examined in hydrodynamically mobile sandy sediments on the inner continental shelf off New Jersey, USA (39° 27.69′ N, 74° 15.81′W). Sediment cores for infauna were taken by SCUBA divers at multiple spatial scales over time at 12-m depth in the LEO-15 research area on Beach Haven Ridge. Crests, troughs and less consistently flanks of sand ripples 5–15-cm in height, were characterized by different infaunal community patterns at spatial scales of centimeters to kilometers on several sampling dates. Overall, infaunal community differences among ripple crests, troughs, and/or flanks within areas <1-m² were greater than those found for each of these habitats (i.e., either crests, troughs, or flanks) that were separated by distances of 2 m–4 km. Infaunal density and species richness were consistently higher in troughs compared to crests. Indirect measures of food resources such as particulate organic carbon, chl a, and pheophytin were associated with ripple crests and troughs. Troughs contained significantly higher levels of particulate organic carbon (~1.2 times higher) associated with finer sediments, compared with crests and flanks. Various combinations of taxa had higher densities in either crests or troughs of sand ripples depending on date, and the relative abundances of three taxa, the deposit-feeding polychaete Polygordius jouinae, the suspension-feeding surfclam Spisula solidissima, and predatory nemerteans were important in distinguishing between crests and troughs on most dates. Thus, a priori knowledge of whether a benthic sample comes from a crest or trough helped to explain small-scale infaunal patchiness in relatively homogeneous, subtidal sandy sediments. Consideration of such topographic features in sampling designs can help in explaining variation in species’ distributions at several spatial and temporal scales.     

Flood-duration-integrated stream power and frequency magnitude of >50-year-long sediment discharge out of a hyperarid watershed

Determining sediment discharge out of watersheds is a global, long-term challenge. In the vast, usually data-poor, hyperarid regions of the world, this is a greater challenge. Here, we present a unique, decades-long dataset of individual floods and their respective sediment discharge out of Nahal Yael, an experimental, well-instrumented, hyperarid (~25–30 mm year⁻¹) watershed in southern Israel. The high correlation between directly measured sediment yield by discrete individual floods and their respective total energy, represented by flood-integrated stream power (FISP), serves here as a rating curve. Using this rating curve, the 51-year-long series of FISP in Nahal Yael, calculated from the detailed individual flood hydrographs, was converted into a series of sediment yield by these floods. This, in turn, allows determining the long-term frequency-magnitude of sediment exported out of this hyperarid basin. This can assist in landscape evolution modeling, in testing impacts of flood frequency changes enforced by altered regional climatology, and hint at changes needed in forming the observed alluvial fans. We conclude that, at the decadal scale, moderate floods are the most effective in terms of total sediment transport. However, the recurrence intervals of these moderate hyperarid floods are longer than in temperate regions and reach 5–10 years.     

The effects of using wood treated with chromated copper arsenate in shallow-water environments: A review

Studies published over the past several years have documented that copper, chromium, and arsenic leach from pressure-treated wood placed in estuaries, and that these toxic metals accumulate in nearby sediments and biota. We have found bioaccumulation and deleterious effects in the epibiotic (“fouling”) community, particularly in poorly flushed areas and on new wood. The epibiota showed reduced species richness, diversity, and biomass. Barnacles and encrusting bryozoa that settled on new treated wood grew more slowly than those that settled on untreated wood or plastic substrate. In laboratory studies, trophic transfer of the contaminants from epibiota to their consumers has also been demonstrated. We have also found accumulation of the treatment metals in the fine-grained fraction of nearby sediments and in the benthic infauna. Infauna also had reduced species richness and diversity in sediments adjacent to treated-wood structures. While standard toxicity tests with amphipods did not demonstrate acute toxicity of these sandy sediments, sublethal effects on development were seen in juvenile mysids. Overall, the extent and severity of effects of pressure-treated wood in an estuary depends on the amount and age of the wood and the degree of dilution by water movements.