Lithium and lithium isotope profiles through the upper oceanic crust: a study of seawater-basalt exchange at ODP Sites 504B and 896A

Ocean Drilling Program (ODP) Hole 504B near the Costa Rica Rift is the deepest hole drilled in the ocean crust, penetrating a volcanic section, a transition zone and a sheeted dike complex. The distribution of Li and its isotopes through this 1.8-km section of oceanic crust reflects the varying conditions of seawater alteration with depth. The upper volcanic rocks, altered at low temperatures, are enriched in Li (5.6-27.3 ppm) and have heavier isotopic compositions (δ⁷Li=6.6-20.8‰) relative to fresh mid-ocean ridge basalt (MORB) due to uptake of seawater Li into alteration clays. The Li content and isotopic compositions of the deeper volcanic rocks are similar to MORB, reflecting restricted seawater circulation in this section. The transition zone is a region of mixing of seawater with upwelling hydrothermal fluids and sulfide mineralization. Li enrichment in this zone is accompanied by relatively light isotopic compositions (−0.8-2.1‰) which signify influence of basalt-derived Li during mineralization and alteration. Li decreases with depth to 0.6 ppm in the sheeted dike complex as a result of increasing hydrothermal extraction in the high-temperature reaction zone. Rocks in the dike complex have variable isotopic values that range from −1.7 to 7.9‰, depending on the extent of hydrothermal recrystallization and off-axis low-temperature alteration. Hydrothermally altered rocks are isotopically light because ⁶Li is preferentially retained in greenschist and amphibolite facies minerals. The δ⁷Li values of the highly altered rocks of the dike complex are complementary to those of high-temperature mid-ocean ridge vent fluids and compatible to equilibrium control by the alteration mineral assemblage. The inventory of Li in basement rocks permits a reevaluation of the role of oceanic crust in the budget of Li in the ocean. On balance, the upper 1.8 km of oceanic crusts remains a sink for oceanic Li. The observations at 504B and an estimated flux from the underlying 0.5 km of gabbro suggest that the global hydrothermal flux is at most 8×10⁹ mol/yr, compatible with geophysical thermal models. This work defines the distribution of Li and its isotopes in the upper ocean crust and provides a basis to interpret the contribution of subducted lithosphere to arc magmas and cycling of crustal material in the deep mantle.     

中国农村剩余劳动力转移的趋向和措施

在对中国农村剩余劳动力现状描述的基础上 ,对剩余劳动力形成的原因进行了分析与阐述 ;结合目前形势 ,指出未来农村剩余劳动力的转移前景不容乐观 ;并在此基础上阐述了中国剩余劳动力转移途径和主要措施     

Fluxes of Sr into the headwaters of the Ganges

Himalayan weathering is recognized as an important agent in modifying sea water chemistry, but there are significant uncertainties in our understanding of Himalayan riverine fluxes. This paper examines causes of the variability, including that of the seasons, by analysis of downstream variations in Sr, ⁸⁷Sr, and major ions in the mainstream, in relation to the composition of tributary streams from subcatchments with differing geologic substrates.Water samples were collected over four periods spanning the premonsoon, monsoon, and postmonsoon seasons. Uncertainties in the relative fluxes have been estimated, using Monte Carlo techniques, from the short-term variability of mainstream chemistry and the scatter of tributary compositions. The results show marked seasonal variations in the relative inputs related to high monsoon rainfall in the High and Lesser Himalaya, contrasting with the major contribution from glacial melt waters from the Tibetan Sedimentary Series (TSS) at times of low rainfall. Much of the spread in previously published estimates of the sources of Sr in Himalayan rivers may result from these seasonal variations in Sr fluxes.The annual fluxes of Sr into the headwaters of the Ganges are derived from the three main tectonic units in the proportions 35 ± 1% from the TSS, 27 ± 3% from the High Himalayan Crystalline Series (HHCS), and 38 ± 8% from the Lesser Himalaya. The particularly elevated ⁸⁷Sr/⁸⁶Sr ratios characteristic of the HHCS and the Lesser Himalaya enhance their influence on seawater Sr-isotope composition. The TSS contributes 13 ± 1%, the HHCS 30 ± 3%, and the Lesser Himalaya 57 ± 11% of the ⁸⁷Sr flux in excess of the seawater ⁸⁷Sr/⁸⁶Sr ratio of 0.709.     

孟加拉湾季风爆发对南海季风爆发的影响Ⅰ:个例分析

利用南海季风试验分析场和NCAR向外长波辐射通量(OLR)资料研究了1998年孟加拉湾季风和南海季风爆发期间副热带环流的大尺度和天气尺度特征,探讨了孟加拉湾季风爆发与南海季风爆发之间的物理联系及孟加拉湾季风气旋的对流凝结潜热释放对副热带高压“撤出”南海的影响。结果表明,1998年5月爆发的东亚季风展现出典型的从孟加拉湾地区东传发展到南海地区的过程。随着孟加拉湾季风爆发和对流活动增强、北移,南海北部出现了低层西风和对流活动,领先于副热带高压在南海地区减弱和撤退。结果还显示南海北部地区的对流凝结加热有助于该地区经向温度梯度的反转,在热成风关系的制约下南海上空副热带高压脊面的垂直倾斜由冬季型转向夏季型,季风爆发。     

A hybrid method for size characterization of coarse subsurface fluvial sediments

This paper introduces and evaluates a novel method for ascertaining the grain‐size distribution of subsurface sediments that involves profoundly less sampling effort than standard methods. It is based on hybrid sampling principles previously applied to the construction of synthetic surface grain‐size distributions. The method is developed from an empirical demonstration of the approximate similarity of surface and subsurface grain‐size distributions when compared over a common range of sizes. Subsurface hybrid models are found to provide good facsimiles of grain‐size distributions de?ned using standard criteria and to yield distribution percentiles with millimetre accuracy. The technique is presented as an expedient alternative to standard methods for large, perennial gravel‐bed rivers. As this is a new technique, prudent application is advised in lieu of further investigation. Copyright © 2004 John Wiley & Sons, Ltd.     

High-pressure experimental growth of diamond using C–K2CO3–KCl as an analogue for Cl-bearing carbonate fluid

High-pressure, high-temperature diamond growth experiments have been conducted in the system C–K₂CO₃–KCl at 1050–1420 °C, 7.0–7.7 GPa. KCl is of interest because of the strong effect of halogens on the phase relations of carbonate-rich systems [Geophys. Res. Lett. 30 (2003) 1022] and because of the occurrence of KCl coexisting with alkali silicate–carbonate fluids in natural-coated diamond [Geochim. Cosmochim. Acta 64 (2000) 717]. We have used system C–K₂CO₃–KCl as an analogue for these mantle fluids in diamond growth experiments. The presence of KCl reduces the potassium carbonate liquidus to ≤1000 °C at 7.7 GPa, allowing it to act as a solvent catalyst for diamond growth at temperatures below the continental geotherm. This is a reduction on the minimum diamond growth temperature reported in the alkali-carbonate–C–O–H system [Lithos 60 (2002) 145]. Diamond growth using carbonate solvent catalysts is characterised by a relatively long induction period. However, the addition of KCl also reduced the period for diamond growth in carbonate to 5 min; no such induction period appears to be necessary. It is suggested that KCl destabilises carbonate, allowing greater solubility and diffusion of carbon.     

Li/Ca in multiple species of benthic and planktonic foraminifera: thermocline, latitudinal, and glacial-interglacial variation

Li/Ca ratios were measured in planktonic and benthic foraminifera from a variety of hydrographic settings to investigate the factors influencing lithium incorporation into foraminiferal tests including temperature, dissolution, pressure, and interspecies differences. Down-core measurements of planktonic (Orbulina universa, Globigerinoides ruber, and Globigerinoides sacculifer) and benthic foraminifera (calcitic Cibicides wuellerstorfi and aragonitic Hoeglandina elegans) show a systematic variation in Li/Ca with δ¹⁸O through the last glacial-interglacial transition. All species examined exhibit an increase in Li/Ca between 14 to 50% from the Holocene to the last glacial maximum. Li/Ca generally increases with decreasing temperature as seen in a latitudinal transect of planktonic O. universa and down-slope benthic species along the Bahama Bank margins. Postdepositional dissolution possibly causes a decrease in planktonic foraminiferal Li/Ca along the Sierra Leone Rise, and increased water depth causes a decrease in benthic foraminiferal Li/Ca in the deep Caribbean. However, none of these effects are sufficient to account for the observed glacial-interglacial changes. Physiological factors such as calcification rate may affect the Li/Ca content of foraminiferal calcite. The calcification rate in turn may be a function of carbonate ion concentration of ambient ocean water. This work shows that incorporation of lithium by foraminifera appears to be influenced by factors other than seawater composition and does not appear to be dominated by changes in temperature, dissolution, or pressure. We hypothesize that the consistent increase in foraminiferal Li/Ca during the last glacial maximum may be linked to changes in seawater carbonate ion concentration. Important parameters to be tested include calcification rate and foraminiferal test size and weight. If foraminiferal Li/Ca is dominantly controlled by calcification rate as a function of seawater carbonate ion concentration, then Li/Ca may act as a proxy of past atmospheric CO₂.     

Assessing natural and cultural influence on soil in remnant tropical woodlands

Rural Hong Kong contains culturally protected enclaves of remnant woodlands that provide sanctuary for vegetation, wildlife and soil. This study focuses on the influence of natural and cultural factors on soil properties in woodlands with different human activities. At each of the nine selected sites, two pits were dug to collect soil samples for analysis of 24 physical and chemical properties. Analyses of variance between soil attributes and site factors suggest the prominence of woodland size, and important contribution of topography, aspect and parent material. Soil indicators of human impacts and the tenacity of woodland soil towards anthropogenic disturbance were demonstrated.     

南京市日最高气温对支气管和心血管类疾病就诊人数的影响

融合应用分布滞后非线性模型(Distributed Lag Mon-linear Model,DLNM)与广义相加模型(Generalized Additive Model,GAM),在控制新冠疫情影响、节假日效应、星期效应、长期趋势以及大气污染因子等因素基础上,探究了2018—2020年南京市日最高气温与当地支气管类、心血管类疾病就诊人数的暴露反应关系,包括滞后效应和累积效应。结果表明:对于支气管类疾病,冬季为高风险期,低温的即时效应和累积效应显著;中短期累积作用下,气温越低危险性越大;长期累积作用下,10 ℃左右的危险性最大;高温累积效应不显著,30 ℃左右滞后效应显著。对于心血管类疾病,低温的即时效应和累积效应显著,11~12 ℃左右影响的累积效应和持续性最强;高温的滞后效应显著,温度越高,滞后效应越明显;长期暴露于高温环境的患病风险会快速增加,日最高气温32 ℃左右的暴露累积风险最大。针对这两类疾病,当日最高气温在22~24 ℃范围内,属于人体最舒适温度。     

What does the occurrence of Sporormiella (Preussia) spores mean in Australian fossil sequences?

Understanding the loss of the final few species of Australian megafauna is beset by a paucity of data on human arrival, well‐provenanced megafauna, human/megafauna population range and distribution (coexistence and interaction), and the range, scale and impact of environmental changes spanning the human–megafauna period. To overcome these shortcomings, the occurrence and decline of coprophilous fungal spores of Sporormiella in sediments have been used as a proxy for extinct megaherbivores. The Sporormiella evidence is presented as the key indicator of extinction timing and these reports are often from locations where there is no known archaeological record or megafauna remains. However, interpreting fungal spore occurrence is not straightforward, as demonstrated by studies investigating taphonomy, taxonomy and the types of animal dung where Sporormiella occurs. No detailed studies on these problems exist for Australia and no evidence supporting the use of Sporormiella as a valid proxy has been reported. Here we examine the occurrence of Sporormiella spores from Cuddie Springs in south‐eastern Australia. Despite a well‐preserved suite of megafauna fossils, Sporormiella occurrence is sporadic and frequencies are low. We conclude that using Sporormiella alone as an indicator for the presence of megafauna is premature for the Australian context.