An investigation of the SO2 content of the venusian mesosphere using SPICAV-UV in nadir mode

Using the SPICAV-UV spectrometer aboard Venus Express in nadir mode, we were able to derive spectral radiance factors in the middle atmosphere of Venus in the 170-320 nm range at a spectral resolution of R ? 200 during 2006 and 2007 in the northern hemisphere. By comparison with a radiative transfer model of the upper atmosphere of Venus, we could derive column abundance above the visible cloud top for SO₂ using its spectral absorption bands near 280 and 220 nm. SO₂ column densities show large temporal and spatial variations on a horizontal scale of a few hundred kilometers. Typical SO₂ column densities at low latitudes (up to 50°N) were found between 5 and 50 μm-atm, whereas in the northern polar region SO₂ content was usually below 5 μm-atm. The observed latitudinal variations follow closely the cloud top altitude derived by SPICAV-IR and are thought to be of dynamical origin. Also, a sudden increase of SO₂ column density in the whole northern hemisphere has been observed in early 2007, possibly related to a convective episode advecting some deep SO₂ into the upper atmosphere.     

Tidal exposure or microhabitats: what determines sandy‐beach nematode zonation? a case study of a macrotidal ridge‐and‐runnel sandy beach in Belgium

Lately, across‐shore zonation has been found to be more important in structuring the nematode community of a tropical macrotidal sandy beach than microhabitat heterogeneity. To evaluate whether this zonation pattern applies to a temperate beach, a macrotidal ridge‐and‐runnels sandy beach in the North Sea was studied. We investigated whether a similar zonation occurs in sandbar and runnel microhabitats, and whether the runnels harbour a different community from the subtidal. Our results indicate that nematode communities from runnel and sandbar habitats are significantly different. In addition, horizontal zonation patterns for nematode communities differ between both habitats. Nematode assemblages from sandbars are divided to lower, middle and upper beach while upper and middle runnels cluster together. The subtidal and upper runnels showed dissimilar nematode assemblages, although runnels showed the same dominant species (Daptonema normandicum), which increases its abundance towards the upper runnels. This study illustrates the importance of microhabitat heterogeneity, which resulted in different zonation patterns across the sandy beach examined. The divergent zonation between sandbars and runnels in the macrotidal temperate sandy beach, compared with the pattern observed for a subtropical sandy beach with similar morphodynamics, indicates that generalizations about nematode distribution patterns should be made with caution.     

Groundwater biofilm dynamics grown in situ along a nutrient gradient

This paper describes the in situ response of groundwater biofilms in an alluvial gravel aquifer system on the Canterbury Plains, New Zealand. Biofilms were developed on aquifer gravel, encased in fine mesh bags and suspended in protective columns in monitoring wells for at least 20 weeks. Four sites were selected in the same groundwater system where previous analyses indicated a gradient of increasing nitrate down the hydraulic gradient from Sites 1 to 4. Measurements during the current study classified the groundwater as oligotrophic. Biofilm responses to the nutrient gradients were assessed using bioassays, with biomass determined using protein and cellular and nucleic acid staining and biofilm activity using enzyme assays for lipid, carbohydrate, phosphate metabolism, and cell viability. In general, biofilm activity decreased as nitrate levels increased from Sites 1 to 4, with the opposite relationship for carbon and phosphorus concentrations. These results showed that the groundwater system supported biofilm growth and that the upper catchment supported efficient and productive biofilms (high ratio of activity per unit biomass).     

Fluoride Biomonitoring around a Large Aluminium Smelter Using Foliage from Different Tree Species

In order to study the pollution gradient in the vicinity of a large aluminium production facility in Patagonia (Argentina), a passive biomonitoring was performed employing foliage from three tree species. Primary scope was to identify pollution gradients and to select suitable tree species which can be used as biomonitor plants in the study area. Therefore, leaves of Eucalyptus rostrata, Populus hybridus and different needle ages of Pinus radiata were collected at different distances from the industry and the fluoride concentration was analysed in washed and unwashed samples in order to determine the amount of external fluoride. Washing reduced the F‐concentrations by 24, 39 and 51% on average in E. rostrata, P. hybridus and P. radiata, respectively, indicating that species‐specific characteristics determine the accumulation and wash‐off of dust‐associated fluorine. F‐concentrations varied from 6 to 3652 ppm F in unwashed samples indicating a steep pollution gradient in the study area. The influence of F‐emissions was discernible in all samples up to a distance of 3500 m from the smelter. E. rostrata accumulated more fluorine than the other species at equal distance from the emission source. The present study confirms that aluminium smelting results in high F deposition in the study area. Establishing a biomonitor network around large emitters is suitable and feasible to evaluate the efficiency of air control measures.     

Greening international shipping through private governance: A case study of the Clean Shipping Project

This article aims to generate insights into both private governance and partnerships within the shipping industry, but also tries to improve understanding of the complex process of institutionalisation.This is achieved through a case study of the Clean Shipping Project, a public/private partnership that aims to promote sustainability in the shipping industry. A set of enabling and constraining factors are examined that shape the institutionalisation process and determine to what extent the Clean Shipping Project can establish and expand authority as an industry norm.Overall, the Clean Shipping Project cannot yet be considered a full-fledged private governance institution, because of an insufficient level of collaborative advantage mainly due to weak system robustness and unfavourable market characteristics and conditions. However, institutionalisation is an ongoing process and the future outlook for the Clean Shipping Project remains promising. The Clean Shipping Project is certainly a relevant supplement to existing regulations and there is a basic level of commitment and cohesion within the partnership, so it is not unlikely that in the future this initiative may help to uncouple growth in shipping activities from environmental harm.     

Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite

For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different ¹⁸O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ₄₇ which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ¹⁸O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ¹⁸O and Δ₄₇ signatures reveal exchange with the aqueous fluid, whereas δ¹³C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments.     

Peat Accretion Histories During the Past 6,000 Years in Marshes of the Sacramento–San Joaquin Delta,CA, USA

The purpose of this study was to determine how vertical accretion rates in marshes vary through the millennia. Peat cores were collected in remnant and drained marshes in the Sacramento–San Joaquin Delta of California. Cubic smooth spline regression models were used to construct age–depth models and accretion histories for three remnant marshes. Estimated vertical accretion rates at these sites range from 0.03 to 0.49 cm year⁻¹. The mean contribution of organic matter to soil volume at the remnant marsh sites is generally stable (4.73% to 6.94%), whereas the mean contribution of inorganic matter to soil volume has greater temporal variability (1.40% to 7.92%). The hydrogeomorphic position of each marsh largely determines the inorganic content of peat. Currently, the remnant marshes are keeping pace with sea level rise, but this balance may shift for at least one of the sites under future sea level rise scenarios.