The M/V Cosco Busan spill: source identification and short-term fate

Understanding the fate of heavy fuel oils (HFOs) in the environment is critical for sound decisions regarding its usage and spill cleanup. To study weathering of HFOs, we examined the M/V CoscoBusan spill (November 2007; San Francisco Bay, CA, USA). In this baseline report, we identified which ruptured tank (port tank 3 or 4) was the source of the spilled oil and characterized changes in the oil composition across location and time. Samples from three impacted shorelines, collected within 80 days of the spill, were analyzed using one- and two-dimensional gas chromatography (GC and GC × GC, respectively). Weathering varied across sites, but compounds with GC retention times less than n-C₁₆ were generally lost by evaporation and dissolution. Changes in n-C₁₈/phytane and benz[a]anthracene/chrysene ratios indicated some biodegradation and photodegradation, respectively.     

Overshooting and semiconvection: structural changes and asteroseismic signatures

Overshooting and semiconvection are two poorly known mechanisms which affect the extent and the efficiency of chemical mixing outside classical convection zones in stars. We discuss the uncertainties and the inferences of those processes in main sequence stars burning hydrogen in a convective core. We then focus on the asteroseismic signatures of partially or fully mixed zones surrounding the convective core, through the detailed shape of the induced chemical composition profile. We emphasize the potential power of asteroseismology to determine the internal structure of stars and thus to help us understand the physical processes at work inside the stars.     

2D solar modeling

Understanding the reasons of the cyclic variation of the total solar irradiance is one of the most challenging targets of modern astrophysics. These studies prove to be essential also for a more climatologic issue, associated to the global warming. Any attempt to determine the solar components of this phenomenon must include the effects of the magnetic field, whose strength and shape in the solar interior are far from being completely known. Modeling the presence and the effects of a magnetic field requires a 2D approach, since the assumption of radial symmetry is too limiting for this topic. We present the structure of a 2D evolution code that was purposely designed for this scope; rotation, magnetic field and turbulence can be taken into account. Some preliminary results are presented and commented.     

Single-crystal polarized FTIR spectroscopy and neutron diffraction refinement of cancrinite

We relate a single-crystal FTIR (Fourier transform infrared) and neutron diffraction study of two natural cancrinites. The structural refinements show that the oxygen site of the H₂O molecule lies off the triad axis. The water molecule is almost symmetric and slightly tilted from the (0001) plane. It is involved in bifurcated hydrogen bridges, with Ow···O donor–acceptor distances >2.7 Å. The FTIR spectra show two main absorptions. The first at 3,602 cm^?1 is polarized for E ⊥ c and is assigned to the ν₃ mode. The second, at 3,531 cm^?1, is also polarized for E ⊥ c and is assigned to ν₁ mode. A weak component at 4,108 cm^?1 could possibly indicate the presence of additional OH groups in the structure of cancrinite. Several overlapping bands in the 1,300–1,500 cm^?1 range are strongly polarized for E ⊥ c, and are assigned to the vibrations of the CO₃ group.     

Organizing earth observation data inside a spatial data infrastructure

Scientists as well public institutions dealing with geospatial data often work with a large amount of heterogeneous data deriving from different sources. Without a well-defined, organized structure they face problems in finding and reusing existing data, and as consequence this may cause data inconsistency and storage problems. A catalog system based on the metadata of spatial data facilitates the management of large amount of data and offers service to retrieve, discover and exchange geographic data in an quick and easy fashion. Currently, most online catalogs are more focusing on the geographic data and there has been only few interests in catalogizing Earth observation data, in which in addition the acquisition information matters. This article presents an automatic metadata extraction approach that creates from different optical data deriving from various satellite missions of scientific interest (i.e. MODIS, LANDSAT, RapidEye, Suomi-NPP VIIRS, Sentinel-1A, Sentinel-2A) metadata information, based on an extended model of the standard ISO 19115. The XML schema ISO 19139-2 with the support of gridded and imagery information defined in ISO 19115-2 was examined, and based on the requirements of experts working in the research field of Earth observation the schema was extended. The XML schema ISO 19139-2 and its extension has been deployed as a new schema plugin in the spatial catalog Geonetwork Open Source in order to store all relevant metadata information about satellite data and the appropriate acquisition and processing information in an online catalog. A real-world scenario that is productively used in the EURAC research group institute for Applied Remote Sensing illustrates a workflow management for Earth observation data including data processing, metadata extraction, generation and distribution.     

Lake Redó ecosystem response to an increasing warming the Pyrenees during the twentieth century

The ecosystem response of Lake Redó (Central Pyrenees) to fluctuations in seasonal air temperature during the last two centuries was investigated by comparison of reconstructed air temperatures with the sediment record. Fine slicing allowed a resolution of 3–6 years according to the ²¹⁰Pb dating, although it was still difficult to easily investigate the response to air temperature forcing, since extreme fluctuations in temperature occur on interannual time-scales. However, the resolution was sufficient to show responses on decadal and century scales. An overall tendency to warming in mean annual temperature in the Central Pyrenees has been caused by summer and in particular by autumn increases. Many of the measured sediment variables apparently responded to these long term trends, but the significance of the relationships was highly conditioned by the structure of the data. The variables responding most on the finer time scales were the microfossils. For diatoms, chironomids and chrysophytes the main variability correlated to summer and to autumn temperatures. For two planktonic species, Fragilaria nanana and Cyclotella pseudostelligera, we found a link of their variability with temperature fluctuations in their growing months (September and October, respectively). This relationship appeared at a certain point during a general warming trend, indicating a threshold in the response. On the other hand, no significant changes in the dominant species could be linked to temperature, nor in any significant subgroup of the 180 diatom species present in the core. In contrast, for most chironomids (particularly Paratanytarsus austriacus, Heterotrissocladius marcidus and Micropsectra radialis) a negative relationship with summer temperature extended throughout the studied period. This response of the whole group gives chironomids a more robust role as indicators for recording temperature changes on long time-scales (e.g., through the Holocene) and for lake signal inter-comparison. Finally, our results indicated that, in all cases, there was a significant resilience to high frequency changes and hysteresis despite extreme fluctuations. Although we were dealing with organisms with one or many generations per year, their populations seemed to follow the decadal trends in air temperature.     

Recent activity of Nisyros volcano (Greece) inferred from structural, geochemical and seismological data

This study summarizes the results of structural, geochemical and seismological surveys carried out at Nisyros volcano (Aegean Sea, Greece) during 1999–2001. Field mapping and mesostructural measurements at the summit caldera (Lakki plain) indicate that faults follow two main strikes: NE-SW and N-S. The N-S striking fault depicts extensional features accommodating the left-lateral component of motion of the NE-SW- striking main faults. The NE-SW preferred strike of the Lakki faults and of the mineral-filled veins as well as the distribution and NE-SW elongation of the hydrothermal craters indicate that tectonics plays a major role in controlling the fluid pathway in the Nisyros caldera. The same NE-SW trend is depicted by CO₂ anomalies revealed through detailed soil CO₂ flux surveys, thus indicating a structural control on the pattern of the hydrothermal degassing. Degassing processes account for a thermal energy release of about 43 MW, most of which occurs at Lofos dome, an area that was affected by hydrothermal eruptions in historical times. The seismic study was conducted in June 2001, using a deployment specifically aimed at detecting signals of magmatic-hydrothermal origin. Our instruments recorded local and regional earthquakes, a few local long-period events (LP), and bursts of monochromatic tremor. Local earthquake activity is concentrated beneath the caldera, at depths generally shallower than 6 km. Plane-wave decomposition of tremor signal indicates a shallow (<200 m) source located in the eastern part of the caldera. Conversely, LP events depict a source located beneath the central part of the caldera, in the area of Lofos dome, at depths in the 1–2-km range. In agreement with geochemical and structural measurements, these data suggest that both the deeper and shallower part of the hydrothermal system are subjected to instability in the fluid flow regimes, probably consequent to transient pressurization of the reservoir. These instabilities may be related to input of hot fluids from the deeper magmatic system, as suggested by the variations in geochemical parameters observed after the 1997–1999 unrest episode. The significance of seismological and geochemical indicators as precursors of hydrothermal explosive activity at Nisyros is discussed.Editorial responsibility: H. Shinohara     

Silicic magma entering a basaltic magma chamber: eruptive dynamics and magma mixing — an example from Salina (Aeolian islands,Southern Tyrrhenian Sea)

The Pollara tuff-ring resulted from two explosive eruptions whose deposits are separated by a paleosol 13 Ka old. The oldest deposits (LPP, about 0.2 km³) consist of three main fall units (A, B, C) deposited from a subplinian column whose height (7–14 km) increased with time from A to C, as a consequence of the increased magma discharge rate during the eruption (1–8x10⁶ kg/s). A highly variable juvenile population characterizes the eruption. Black, dense, highly porphyritic, mafic ejecta (SiO₂=50–55%) almost exclusively form A deposits, whereas grey, mildly vesiculated, mildly porphyritic pumice (SiO₂=56–67%) and white, highly vesiculated, nearly aphyric pumice (SiO₂=66–71%) predominate in B and C respectively. Mafic cumulates are abundant in A, while crystalline lithic ejecta first appear in B and increase upward. The LPP result from the emptying of an unusual and unstable, compositionally zoned, shallow magma chamber in which high density mafic melts capped low density salic ones. Evidence of the existence of a short crystal fractionation series is found in the mafic rocks; the andesitic pumice results from complete blending between rhyolitic and variously fractionated mafic melts (salic component up to 60 wt%), whereas bulk dacitic compositions mainly result from the presence of mafic xenocrysts within rhyolitic glasses. Viscosity and composition-mixing diagrams show that blended liquids formed when the visosities of the two end members had close values. The following model is suggested: 1. A rhyolitic magma rising through the metamorphic basement enterrd a mafic magma chamber whose souter portions were occupied by a highly viscous, mafic crystal mush. 2. Under the pressure of the rhyolitic body the nearly rigid mush was pushed upwards and mafic melts were squeezed against the walls of the chamber, beginning roof fracturing and mingling with silicic melts. 3. When the equilibrium temperature was reached between mafic and silicic melts, blended liquids rapidly formed. 4. When fractures reached the surface, the eruption began by the ejection of the mafic melts and crystal mush (A), followed by the emission of variously mingled and blended magmas (B) and ended by the ejection of nearly unmixed rhyolitic magma (C).     

Efficient analysis of dynamic response of linear systems

After reviewing briefly a recently proposed procedure for evaluating the dynamic transient response of a classically damped linear system from its corresponding steady-state response, a modified procedure is presented which also appears to be highly efficient for non-classically damped systems of the type encountered in studies of soil-structure interaction. The concepts involved are developed by reference to viscously damped single-degree-of-freedom systems, and numerical solutions are included to illustrate the accuracy and efficiency of the proposed procedure and its superiority over the classical Discrete Fourier Transform approach.