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The X-ray absorption spectra of the transition metal L3,2-edges of the dichalcogenides FeS2 (pyrite), FeSe2, FeTe2, CoS2, CoSe2, CoTe2, NiS2, NiSe2 and NiTe2 have been studied. These spectra are compared with theoretical simulations make using the atomic multiplet approach assuming on octahedral site for the metal atoms. The Ni spectra can be closely simulated using this approach but the Fe and Co spectra show less good fits to the experimental data. The reasons for this and its implications for the use of L-edge spectra in the study of such minerals are discussed in terms of the covalency and the ground states of the compounds; these results indicate the mixing of the ground states increases in the order Ni<Co<Fe.  相似文献   
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A difficulty in the interpretation of mechanical and thermo-mechanical tests on specimens drawn from large argillaceous formations is the strong inhomogeneity of void ratio, clay minerals and carbonates content.

In this paper a relationship is developed to link strength and the maximum preconsolidation stress to the initial void ratio and carbonate content. Compressibility is also correlated to carbonates.

Thermal strains in drained and undrained conditions for a Spanish, a belgian and an Italian natural clay are compared. In the elastic state strains are comparable, while in the plastic range thermal strains are highest for the Belgian clay, lower in the Spanish cemented clay and lowest in the Italian clay, very stiff and cemented.  相似文献   

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The discovery of Mercury's magnetosphere by Mariner 10 was surprising since the conventional view of regenerative planetary dynamos had been that the spin requirement would likely have been in excess of the observed spin rate of Mercury. Also internal fluid motions were not expected to be sufficiently large. This paper explores the alternative model of the formation of Mercury's magnetosphere via electromagnetic induction forced by the solar wind. It is shown, however, that the constraints are so severe as to limit severely the applicability of such a model. Although induction is easily observed on the Moon, the modification of the magnetic boundary condition associated with a plasma magnetosphere on Mercury rules out its formation via induction except for interplanetary driving fields which are decreasing in amplitude. That model is explored but retains the difficulty that induced magnetospheres tend to be of small radial and temporal extent compared to that inferred by Ness et al. for Mercury.  相似文献   
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We found extensive evidence that the vertical ground accelerations produced during the largest shock (M = 6.0) of the 1997 Umbria-Marche earthquake sequence exceeded 1g in two areas close to the heavily-damaged villages of Annifo and Colle Croce. This evidence comes from the striking observation of thousands of freshly fractured and broken rocks and stones in these areas. Some of the broken stones lie isolated on soft detritic soil while others had been previously piled up, probably a long time agoto clear the fields for farming. The freshness of the cuts and fractures and the consistency of the observations for thousands of rocks and stones in these areas indicate that these rocks were thrown upwards during the earthquake, with breakage occurring at the time of impact. Ground motion calculations consistent with the static deformation inferred from GPS and interferometry data, show that the broken stones and rocks are found in the zone where the strongest shaking took place during the earthquake and that most of the shaking there was vertical.  相似文献   
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