Retention of arsenic and phosphorus in iron-rich concretions of Tagus salt marshes

Iron-rich concretions are frequently found around plant roots in Tagus estuary (Portugal) where radial delivery of O₂ takes place. Salt marsh sediments exhibit cracks that are an additional feature to introduce O₂ and other solutes in the upper sediments. Metal concentrations in salt marsh sediments are clearly above the background levels reflecting the anthropogenic sources from a large city with 2.5 million inhabitants, and several industrial centres. In order to evaluate how both oxidised structures influences the redistribution of redox sensitive elements in salt marsh sediments, concretions were collected from roots of Halimione portucaloides below the oxygenated zone. These tubular cylindrical structures were analysed for Fe, Al, Mn, As, and P along 1-cm radial transect in a millimetre scale from the inner part to the adjacent anoxic sediment. In addition, oxidised cracks were analysed for the same spatial resolution, from the sediment–water interface to anoxic layers (2-cm transept). The parallelism between Fe, As, and P concentrations at this microscale is the most noticeable aspect. Iron and As presented very high concentrations in the 4-mm concretions (3.4 mmol g⁻¹ and 3.1 μmol g⁻¹, respectively) and decreased sharply to the host sediment. Oxygen released from roots oxidise the solid sulphides, and the reduced Fe and As are transported towards the root by both diffusion and pore water flow associated with the root water uptake. Subsequently, Fe(III) precipitates and As is retained by sorption and/or coprecipitation. These elements are also enriched in the first 2-mm of oxidised cracks, but in lower concentrations (50% and 30%, respectively). Manganese concentrations in concretions were low (11.8 μmol g⁻¹), indicating that Fe dominates the sediment chemistry. Phosphorus and iron concentrations in the ascorbate fraction were higher in the oxidising surfaces of concretions (10.7 μmol g⁻¹ and 1.6 mmol g⁻¹, respectively) and of cracks (5.1 μmol g⁻¹ and 0.47 mmol g⁻¹). The parallelism of Fe and As distributions includes not only their similar redox chemistries, but also that to phosphate, including control by coprecipitation of the host iron phases. The mechanisms involved in the mobilisation of As and P are however different, whereas As comes from the oxidation of iron sulphides; dissolved P derives from reduction of ferri-hydroxide phases.     

Short-Term Benthic Recolonization after Dredging in the Harbour of Ceuta, North Africa

Abstract. The benthic recovery after dredging (area: 2625 m²) was studied in a polluted and enclosed area of the harbour of Ceuta, in which the recolonization through the water column (larvae and adult bedload transport) could be limited by the lack of renewal. The benthos was sampled at two sites (control and dredged) using a van Veen grab and adopting a BACI (Before, After, Control, Impacted) approach. Five samplings were conducted after dredging (3, 15, 30, 90, 180 days). The proportion of gravel in the sediment of the dredged site increased after dredging, while the organic matter decreased. The impact on the community was estimated at species level, using both univariate and multivariate analyses. The maximum negative effect on benthic macrofauna was a reduction by 65% for species richness (15 days after dredging) and by 75% for abundance (3 days after dredging). Between 15 and 30 days after dredging, the abundance of some species such as the molluscs Parvicardium exiguum and Retusa obtusa and the polychaete Pseudomalacoceros tridentata increased considerably in the dredged site, while typical ‘opportunistic’ species such as Capitella capitata were disfavoured by the disturbance. For this small‐scale dredging, about 6 months are required for the disturbed area to re‐establish a sediment structure and a macrobenthic community similar to the undisturbed area. Small‐patch dredging operations are proposed in harbour management whenever possible, since they allow a quick re‐adjustment of the initial sediment structure and benthic communities.     

Non-Gaussian distribution and clustering of hot and cold pixels in the five-year WMAP sky

We present measurements of the clustering of hot and cold patches in the microwave background sky as measured from the Wilkinson Microwave Anisotropy Probe 5-year data. These measurements are compared with theoretical predictions which assume that the cosmological signal obeys Gaussian statistics. We find significant differences from the simplest Gaussian-based prediction. However, the measurements are sensitive to the fact that the noise is spatially inhomogeneous (e.g. because different parts of the sky were observed for different lengths of time). We show how to account for this spatial inhomogeneity when making predictions. Differences from the Gaussian-based expectation remain even after this more careful accounting of the noise. In particular, we note that hot and cold pixels cluster differently within the same temperature thresholds at few-degree scales. While these findings may indicate primordial non-Gaussianity, we discuss other plausible explanations for these discrepancies. In addition, we find some deviations from Gaussianity at sub-degree scales, especially in the W band, whose origin may be associated with extragalactic dust emission.     

Adding the missing third and fourth dimensions to trajectory analysis in carbonate systems

We developed a seismic geomorphology-based procedure to enhance traditional trajectory analysis with the ability to visualize and quantify lateral variability along carbonate prograding-margin types (ramps and rimmed shelves) in 3D and 4D. This quantitative approach analysed the shelf break geometric evolution of the Oligo-Miocene carbonate clinoform system in the Browse Basin and delineated the feedback between antecedent topography and carbonate system response as controlling factor on shelf break rugosity. Our geometrical analysis identified a systematic shift in the large-scale average shelf break strike direction over a transect of 10 km from 62° to 55° in the Oligo-Miocene interval of the Browse Basin, which is likely controlled by far-field allogenic forcing from the Timor Trough collision zone. Plotting of 3D shelf break trajectories represents a convenient way to visualize the lateral variability in shelf break evolution. Shelf break trajectories that indicate contemporaneous along-strike progradation and retrogradation correlate with phases of autogenic slope system re-organization and may be a proxy for morphological stability of the shelf break. Shelf break rugosity and shelf break trajectory rugosity are not inherited parameters and antecedent topography does not dictate long-term differential movement of the shelf margin through successive depositional sequences. The autogenic carbonate system response to antecedent topography smooths high-rugosity areas by filling accommodation and maintains a relatively constant shelf break rugosity of ~150 m. Color-coding of the vertical component in the shelf break trajectory captures the creation and filling of accommodation, and highlights areas of the transect that are likely to yield inconsistent 2D sequence stratigraphic interpretations.     

时间延迟对劈裂试验条件下岩石凯塞效应的影响

验证了粗晶花岗岩在劈裂试验条件下凯塞效应的存在性。进行了循环加卸载时间间隔分别为2、15d和45d时岩石的声发射试验,讨论了时间延迟对花岗岩凯塞效应的影响。研究结果表明,前期荷载越接近极限强度,岩石的凯塞效应越不明显;凯塞效应随再次加载时间延迟的增加而削弱,在对花岗岩的声发射试验中观察到15d以后岩石的凯塞效应仍然很显著,45d后凯塞效应基本消失。文中同时对试件与加载设备之间的接触状态对声发射试验结果的影响作了初步的定性分析。     

利用遥感技术建立墨西哥热带地上生物量模型(英文)

Spatially-explicit estimation of aboveground biomass(AGB) plays an important role to generate action policies focused in climate change mitigation,since carbon(C) retained in the biomass is vital for regulating Earth’s temperature.This work estimates AGB using both chlorophyll(red,near infrared) and moisture(middle infrared) based normalized vegetation indices constructed with MCD43A4 MODerate-resolution Imaging Spectroradiometer(MODIS) and MOD44B vegetation continuous fields(VCF) data.The study area is located in San Luis Potosí,Mexico,a region that comprises a part of the upper limit of the intertropical zone.AGB estimations were made using both individual tree data from the National Forest Inventory of Mexico and allometric equations reported in scientific literature.Linear and nonlinear(expo-nential) models were fitted to find their predictive potential when using satellite spectral data as explanatory variables.Highly-significant correlations(p = 0.01) were found between all the explaining variables tested.NDVI62,linked to chlorophyll content and moisture stress,showed the highest correlation.The best model(nonlinear) showed an index of fit(Pseudo-r2) equal to 0.77 and a root mean square error equal to 26.00 Mg/ha using NDVI62 and VCF as explanatory variables.Validation correlation coefficients were similar for both models:lin-ear(r = 0.87**) and nonlinear(r = 0.86**).     

一次强烈发展西南低涡的中尺度结构分析

2021年8月7—8日,四川盆地中东部出现大暴雨、局地特大暴雨,是重庆2021年度社会影响最大的一次暴雨过程。采用多源观测及ERA5再分析资料,对此次大暴雨过程进行诊断分析。结果表明：大暴雨发生在低槽移入四川盆地诱发暖性西南低涡背景下,具有显著的阶段性、跳跃性和极端性特征。大暴雨先后形成于西南低涡中心东南部、西南低涡东侧和西南低涡南侧暖湿的边界层辐合线附近。各阶段大暴雨均由移动缓慢、维持时间达3~6 h的β中尺度对流系统影响形成,暖湿不稳定和弱垂直风切变为β中尺度对流系统的形成提供了有利的环境条件。涡度分析表明,西南低涡的发展主要源于低空辐合及垂直涡度输送效应,但暴雨区的正涡度发展与西南低涡并不完全相同,水平涡度倾侧效应较为显著。第一阶段暴雨区正涡度主要源于对流层中低层西南低涡中心附近显著的低空辐合、涡度垂直输送及水平涡度倾侧效应;第二阶段和第三阶段暴雨区正涡度主要源于边界层辐合及边界层以上的水平涡度倾侧效应,边界层辐合触发暖湿大气中的中尺度对流活动促进了第二阶段和第三阶段大暴雨的形成。

     

Loss of preferred habitat and pollen limitation threatens reproduction in a rare mountain <Emphasis Type="Italic">Paeonia delavayi</Emphasis>

Paeonia delavayi is a wild tree peony species endemic to high-altitude regions in southwestern China. Recent agricultural land expansion, however, not only causes its dwindling population size, but also poses a severe threat to its long-term persistence. Since our knowledge of the reproductive biology of P. delavayi is very limited, and some management misconceptions have further exacerbated the already worrisome situation, the aim of the present study is to provide some scientific evidence regarding habitat preference and breeding system of P. delavayi, and to help correct some management misconceptions. Specifically, morphological traits of P. delavayi populations growing in two different habitats (i.e., the open area versus forest understory), including basal stem diameter, plant height and flower numbers per plant, were measured and compared with each other. A range of floral manipulation experiments was further conducted to study the extent of self-compatibility and pollen limitation. The results showed that P. delavayi preferred the open habitat over forest understory as it generally grew bigger with thicker stems, and produced a higher number of flowers in the former habitat. Therefore, the open habitat should receive immediate priority for conservation action instead of being converted to agricultural land; also, P. delavayi is pollen limited, as evidenced by the fact that experimental flowers receiving supplemental non-self pollen generally displayed elevated seed production than flowers subjected to other treatments (e.g., non-supplemental self pollen, non-supplemental non-self pollen and supplemental self pollen), which is consistent with reported observations that alpine plants are more likely to be pollen-limited than lowland plants. We suggest that human intervention might be necessary to guarantee the long-term persistence of P. delavayi as harsh alpine environment, intense competition for pollinators and different anthropogenic perturbations co-limit its reproductive success.     

基于Google Earth的遥感影像数据资料归档系统

将Google Earth应用于遥感影像数据资料归档系统中,是一种新的遥感资料归档方法,能将归档的成果文件整合,克服了传统归档方式不能快速查看数据效果、位置、属性信息的缺点,很好地适应了信息化工作程序对图像数据库的快速响应的要求.ARCGIS补充了Google Earth薄弱的空间分析功能.系统再联合EXCLE表件,方...