便携式Li-K分析仪的研制及其在锂辉石中锂的分析应用

我国锂钾主要矿产资源大多分布在西部偏远地区,其勘查找矿或综合利用迫切需要现场快速分析技术的支持。本文介绍了自行开发的便携式Li-K分析仪的主要性能及其在锂辉石中锂的分析应用。Li-K分析仪是一种基于大气压的液体阴极辉光放电光谱仪,以待测液体为放电阴极,实现了样品中Li、K等元素的原子化和激发。该仪器以光纤传导CCD光谱仪作为检测器,其波长范围为345~1015 nm,分辨率3 nm;以Li 670.78 nm和K 769.90 nm分析谱线,在仪器最佳工作条件下测定Li、K的精密度(RSD,n=14)均低于2%,检出限为0.03μg/m L,检测范围0.1~10μg/m L。研究表明,不同酸度和酸的类型对谱线强度影响较大,且存在显著的样品基体效应,标准曲线法分析锂辉石中Li的结果偏差高达267%;而标准加入法可克服基体效应的影响,获得与ICP-OES一致性较好的分析结果,为现场开展固体样品中Li的测定奠定了基础。     

Study on the Global Carbon Assimilation System Based on Multisource Remote Sensing Data

The Paris agreement signed in April, 2016 aims to balance global anthropogenic carbon emissions and terrestrial carbon sinks by the middle of the 21^st century. To fulfill this goal, it is necessary to calculate carbon fluxes of different regions reliably. The global carbon assimilation system is an effective technique for achieving this goal. The Ministry of Science and Technology of China supports the project entitled as study on the global carbon assimilation system based on multisource remote sensing data through the national key research and development programs for global change and adaptation during the thirteen-five period. This project will develop synergic inversion techniques for retrieving key parameters of biological and atmospheric cycles and for assimilating multisource remote sensing and ground based data. Then, the high resolution global carbon assimilation system coupled with an ecological model will be constructed. This system is able to assimilate jointly multisource observation data and to optimize key model parameters, photosynthesis and respiration carbon fluxes of global terrestrial ecosystems, and anthropogenic carbon emission fluxes of key regions. This system will be used to study quantitatively the spatial and temporal patterns of carbon fluxes of global terrestrial ecosystems and anthropogenic carbon emission fluxes of key regions and to identify the mechanisms driving the global terrestrial carbon sinks and sources. The outputs of this study will be helpful for the fulfillment of the key research and development programs for global change and adaptation and provide valuable data and technical support for the decision-making in China.     

动力学模型预测深海鲣鱼(Katsuwonus pelamis)调理食品常温下的货架期

为了预测鲣鱼(Katsuwonus pelamis)调理食品的货架期,将鲣鱼调理食品贮藏在25°C、30°C、35°C温度条件下,通过测定在贮藏期间菌落总数、挥发性盐基氮、过氧化值三个指标的变化,分别对这三个指标与贮藏时间、温度建立一级动力学模型,来预测鲣鱼调理食品的货架期。经计算得出,菌落总数预测模型中的活化能(Ea)及指前因子(k0)分别为30.96 k J/mol和2.06×103,挥发性盐基氮预测模型中的的活化能及指前因子分别为24.35 k J/mol和75.1,过氧化值预测模型中的活化能及指前因子分别为48.75 k J/mol和2.92×106。在32°C和37°C条件下验证动力学模型,结果表明相对误差分别为–5.52%和–6.45%,准确性较好。进一步推算得出,在18°C和23°C常温下贮藏鲣鱼调理食品,产品的货架期为209d和172d。     

Driving forces and their interactions of built-up land expansion based on the geographical detector – a case study of Beijing,China

Scientific interpretation of the driving forces of built-up land expansion is essential to urban planning and policy-making. In general, built-up land expansion results from the interactions of different factors, and thus, understanding the combined impacts of built-up land expansion is beneficial. However, previous studies have primarily been concerned with the separate effect of each driver, rather than the interactions between the drivers. Using the built-up land expansion in Beijing from 2000 to 2010 as a study case, this research aims to fill this gap. A spatial statistical method, named the geographical detector, was used to investigate the effects of physical and socioeconomic factors. The effects of policy factors were also explored using physical and socioeconomic factors as proxies. The results showed that the modifiable areal unit problem existed in the geographical detector, and 4000 m might be the optimal scale for the classification performed in this study. At this scale, the interactions between most factors enhanced each other, which indicated that the interactions had greater effects on the built-up land expansion than any single factor. In addition, two pairs of nonlinear enhancement, the greatest enhancement type, were found between the distance to rivers and two socioeconomic factors: the total investment in fixed assets and GDP. Moreover, it was found that the urban plans, environmental protection policies and major events had a great impact on built-up land expansion. The findings of this study verify that the geographical detector is applicable in analysing the driving forces of built-up land expansion. This study also offers a new perspective in researching the interactions between different drivers.     

Thermal effects on the growth and fatty acid composition of four harmful algal bloom species: Possible implications for ichthyotoxicity

Little is known regarding how harmful algal bloom species respond to different temperatures in terms of fatty acid production. This study examined the effects of temperature on the growth rates, cell volumes, and fatty acid concentrations and compositions of four harmful algal bloom species (HABs), Akashiwo sanguinea, Alexandrium tamarense, Chattonella ovata, and Prorocentrum minimum. The HABs species were cultured at 15, 20, 25, and 30°C in a nutrient-enriched medium. Three of the species maintained optimal growth rates over a wide range of temperatures, but A. tamarense did not. The cell volumes of each species showed little change over the temperature range. The total fatty acid concentrations in A. sanguinea, A. tamarense and C. ovata decreased as the temperature increased, but P. minimum showed no trend in this respect. Polyunsaturated fatty acids (PUFAs), the key biochemical components that maintain cell membrane fluidity and which are associated with toxicity, decreased in both concentration and proportion of total fatty acids as temperature increased, except in A. sanguinea, in which the proportion of PUFAs to the total fatty acids increased. These reductions in PUFA concentration and proportion could reduce cell membrane fluidity and toxicity in HABs; however, enhanced growth and/or ruptured cells, which are considered more toxic than intact cells, could compensate for the reduced per-cell toxicity. This phenomenon might impact on the marine ecosystem and aquaculture industry.     

Recognition of Strong Earthquake Prone Areas in the Altai–Sayan–Baikal Region

The locations of areas prone to strong earthquakes (M ≥ 6.0) in the Altai–Sayan–Baikal region are determined. Based on a scheme of morphostructural zoning of the region and by using the CORA-3 pattern recognition algorithm, all intersections of morphostructural lineaments are separated into two classes: the highly seismic intersections in the vicinities of which strong earthquakes can occur and low seismic in the vicinities of which only earthquakes with M < 6.0 are possible. Recognition was performed for the vectors the components of which were measured values of the geological–geophysical characteristics describing the respective intersection. The result obtained allows the zones of high seismic hazard to be identified more reliably in the region.

     

Effects of mechanical layering on hydraulic fracturing in shale gas reservoirs based on numerical models

Generally, induced hydraulic fractures are generated by fluid overpressure and are used to increase reservoir permeability through forming interconnected fracture systems. However, in heterogeneous and anisotropic rocks, many hydraulic fractures may become arrested or offset at layer contacts under certain conditions and do not form vertically connected fracture networks. Mechanical layering is an important factor causing anisotropy in sedimentary layers. Hence, in this study, with a shale gas reservoir case study in the Longmaxi Formation in the southeastern Chongqing region, Sichuan Basin, we present results from several numerical models to gain quantitative insights into the effects of mechanical layering on hydraulic fracturing. Results showed that the fractured area caused by hydraulic fracturing indicated a linear relationship with the neighboring layer’s Young’s modulus. An increase of the neighboring layer’s Young’s modulus resulted in better hydraulic fracturing effects. In addition, the contact between two neighboring layers is regarded as a zone with thickness and mechanical properties, which also influences the effects of hydraulic fracturing in reservoirs. The initial hydraulic fracture was unable to propagate into neighboring layers under a relatively low contact’s Young’s modulus. When associated local tensile stresses exceeded the rock strength, hydraulic fractures propagated into neighboring layers. Moreover, with the contact’s Young’s modulus becoming higher, the fractured area increased rapidly first, then slowly and finally became stable.     

An experimental investigation into the compaction characteristic of granulated gangue backfilling materials modified with binders

Solid backfill mining has apparent technical advantages in extracting coal resource under sensitive surface structures such as buildings and roads; meanwhile, as an effective method of disposing mining wastes, it works well in solving some environmental problems caused by mining activities. In addition, the controlling effect of solid backfill mining is directly related to the compaction characteristic of backfilling materials. The present study aims to modify the backfilling materials by assessing the effect of binders (cement, fly ash, and lime) on the compaction characteristic of granulated gangue backfilling materials. The compaction test was performed with rock mechanic test system equipped with a self-made circular cylinder apparatus. From the results obtained, cement is not the suitable binder for modifying the gangues backfilling materials, while fly ash or lime, when the dosage is up to 20 wt%, is beneficial to the compaction characteristic of backfilling materials. The relationship between strain behavior and micro-structure of backfilling materials was investigated by SEM and the effect of fly ash or lime on the strain behavior of backfilling materials could be associated with its cementation and gap-filling effect.     

Movement process analysis of the high-speed long-runout Shuicheng landslide over 3-D complex terrain using a depth-averaged numerical model

Landslides - Flow-like landslide is one of the most catastrophic types of natural hazards due to its high velocity and long travel distance. In 2019, a large catastrophic landslide was triggered by...     

青海黄南地区近54年蒸发量变化特征及其影响因子

利用青海省黄南地区近54a(1960—2013年)蒸发量、气温、降水量、日照时数、水汽压等资料,应用地理信息系统、数理统计、线性回归和Mann-Kendall检验等方法分析了黄南地区蒸发量的空间及时间变化趋势,并对黄南地区蒸发量变化特征及其影响因子进行了诊断研究。结果表明:黄南地区年平均蒸发量呈明显的下降趋势,20世纪60—70年代为蒸发量偏多阶段,80年代及后为偏少阶段;黄南地区蒸发量最大的季节是春季和夏季,各季蒸发量均呈减少趋势;黄南地区年蒸发量在1973年发生了由多到少的突变,春、夏、秋、冬季分别发在1973、1975、1976和1974年;分析影响蒸发量的相关因子,蒸发量与日照时数呈显著的正相关关系,与水汽压和降水量呈显著的负相关关系,日照时数的减小是蒸发量减少的主要影响因子。